Professional Documents
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Song Wang
9%
Repairment Cost
$32 billion
2
Introduction
3
Introduction
4
5
Introduction
Fiber-Reinforced Polymer (FRP)
Confined Concrete Column !!!
Confinement
Protection
Durability
6
Self-consolidating concrete (SCC)
7
Introduction
ACI 440.2R
8
Research Significance
▪ Polyester-based FRP
▪ HC-FCS
9
Research Plan
Poly. Epoxy
3 UV Chamber
Envr. Chamber
w/ Water
2
Epoxy
Seawater CFFT
Immersion
4
Poly.
CFFT
Poly.
HC-FCS
Envr. Chamber
1 Poly.
CFFT
Poly.
HC-FCS
10
1.1. Specimen preparation
Test matrix for all the specimens (Both CFFT and HC-FCS)
12 3
Unconditioned
No No
Unloaded (UU)
9 1
12 in. height:
Compression
12 3
Conditioned Unloaded
Yes No
(CU) 9 in. height: Split-disk
9 1
tensile, SEM, EDX,
FTIR, and DSC
12 3
Conditioned Loaded
Yes Yes
(CL)
9 1
11
▪ Epoxy coating
load cell
hydraulic jack
nut
top triangle plate
HC-FCS CFFT
nut
12 3
NLNW No No
9 1 12 in. high -
compression test
12 3
NLW No Yes
9 1 9 in. high - split-disk
Environmental tensile, SEM, EDX,
12 3 Chamber and FTIR tests
LNW Yes No
9 1
12 3
LW Yes Yes
9 1
14
2.2. Load frame setups
LNW
NLW
NLNW
LW
LW
15
1.3. Environmental Exposure Regime (72 days)
Condition Type Freeze/Thaw Heating/Cooling 1st Wet/Dry 2nd Wet/Dry 3rd Wet/Dry
-20°C 20°C 60% RH 60% RH 60% RH
Temperature/
to 10°C to 45°C to 95% RH to 95% RH to 95% RH
RH Range
@ 40% RH @ 40% RH @ 20°C @ 25°C @ 40°C 16
Seawater Immersion
▪ HC-FCS: 51 specimens
▪ CFFT: 51 specimens
17
4.1. Tank setup
5.5
nut 20.0 20.0
anchor plate
6.75 HSS 6.0 8.0 6.0 3.0 6.0 8.0 6.0
load cell steel plate hole for Dywidag bar
Dywidag
18.0
bar hydraulic jack 2.5
2.5
anchor plate
5.5 nut Top View
Front View 18
19
20
Task 1: Envr. Chamber (Phase I)
140% 280
120% 240
Target load 200 kN
Load Retention 100% 200
60% 120
40% 80
20% 40
0% 0
0 5 10 15 20 25
Time (days)
Epoxy
▪ Epoxy yellowing
▪ Lost of gloss
Polyester
▪ Nothing
24
1.4. Compression test setup
LVDT-3
SG-3
Concrete FRP tube
SG-4 SG-2
LVDT-1 LVDT-2
SG-1
25
1.5. Split-disk tensile test setup
groove
sections
strain
gauge
strain strain
gauge gauge
26
1.6. Scanning Electron Microscopy (SEM)
and Energy Dispersive X-ray (EDX)
27
1.7. Fourier Transform Infrared (FTIR) Spectroscopy
& Differential Scanning Calorimetry (DSC)
FTIR transmission 28
UU CU
Concrete
75 um
Concrete 73 um
FRP
FRP
CL
FRP
Concrete
34 um
29
T1P2
30
T2P2
fiber/resin
interphase
debonding
31
T3P2
fiber cracks
resin cracks
32
T1P4
resin cracks
fiber crack
fiber/resin
interphase
debonding
fiber/resin interphase
debonding
33
T2P4
resin cracks
34
T3P4
resin cracks
fiber/resin
interphase
debonding
fiber cracks
35
1.10. EDX results
▪ Possible reaction for glass fibers at the outer surface (leaching)
Si-O-Na + H 2O → Si-OH + Na + OH + -
2+
Ca
Mg 2+
3+
Al
36
MFR outer fiber UU outer fiber
C 2.99% C 12.49%
O 34.11% O 35.36%
Si 32.48% Si 25.23%
Na 0.58% Na 1.19%
Mg 1.38% Mg 1.84%
Al 9.55% Al 7.72%
Ca 18.20% Ca 16.17%
37
0.5
0.4
Absorbance
0.3
OH CH
0.2 OH/CH
MFR 1.01 MFR outer resin
UU 0.99 UU outer resin
0.1
CU 1.02 CU outer resin
CL 1.00 CL outer resin
0
4000 3700 3400 3100 2800 2500
Wavenumbers (cm-1)
38
1.12. DSC Results
-1.6 -1.4
UU CU
-1.65 -1.45
Heat Flow (W/g)
-1.75 -1.55
1st Run Tg=133.2°C 1st Run Tg=132.9°C
2nd Run Tg=134.2°C 2nd Run Tg=133.7°C
-1.8 -1.6
100 110 120 130 140 150 160 170 100 110 120 130 140 150 160 170
Exo Up Temperature ( C) Exo Up Temperature ( C)
-2.7
CL
-2.75 Tg (°C)
Sample
Heat Flow (W/g)
-2.8
1st Run 2nd Run
-2.85
UU 133.2 134.2
-2.9
CL
▪ Concrete: one major crack relatively high compressive strength (8 ksi)
▪ Conditioned specimens: abrupt and larger acoustic emission at the time
of failure freeze/thaw cycles embrittled FRP tubes 40
140%
Norm. Max Stress
120% Max Axial Strain
Max Hoop Strain
100%
Retention
80%
60%
40%
20%
0%
UU CU CL 41
1.14. Split-disk tensile test results
140%
Max Stress
120%
Max Strain
Retention 100%
80%
60%
40%
20%
0%
UU CU CL
42
2.3. FTIR test results
43
Specimen OH CH OH/CH
UC 1.057 1.007 1.050
NLNW 0.944 0.921 1.025
LNW 1.041 1.014 1.027
NLW 0.767 0.633 1.212
LW 0.602 0.437 1.378
▪ Lamina delamination, compared to abrupt rupture, provides CFFT extra strain capacity
45
Max f'cc f'c Max normalized stress Max axial strain
Specimen
(ksi) (ksi) (f'cc/f'c) (%)
Average 1.107 2.652
UC COV 10.241 9.254 5% 6%
Retention 100% 100%
Average 1.058 2.622
NLNW COV 10.604 10.022 2% 7%
Retention 96% 99%
Average 1.044 2.604
LNW COV 10.467 10.022 3% 10%
Retention 94% 98%
Average 1.020 2.484
NLW COV 10.477 10.268 6% 4%
Retention 92% 94%
Average 1.004 2.439
LW COV 10.309 10.268 7% 10%
Retention 91% 92%
Before UV After UV
47
Task 3: UV Chamber
Polyester
Before UV After UV
48
3.4. Split-disk tensile results
UC
50
51
Local buckling Elephant footing
52
110%
Normalized Strength
100%
90%
Retention
80%
90%
Retention
80%
70%
Tank 1 (73 F)
60% Tank 2 (95 F)
Tank 3 (140 F)
50%
0 100 200 300 400 500
Time (days)
54
4.4. Long-term performance prediction
Arrhenius model
1
▪ conditioned 0.95
in an aqueous environment with at least three
HC-FCS
1.2
San Francisco (55 F)
1.0
Strength Retention
0.8
0.6
0.2
0.0
0 50 100 150 200
Time (years)
x=50 y=0.59
x=100 y=0.55
56
Task 3: Seawater Immersion
CFFT
1.1
San Francisco (55 F)
1.0
Strength Retention
0.9
0.8
y = -0.02ln(x) + 0.9532
0.7
0.6
0 500 1000 1500 2000 2500
Time (years)
x=50 y=0.88
x=100 y=0.86
57
4.6. Conclusions
▪ Seawater immersion did not affect the GFRP tube chemically. However, the
absorbed moisture caused micro-cracks in the resin and debonding between
fiber/resin interphase due to swelling stresses
▪ As seawater immersion time passed, the maximum normalized strength and
maximum axial strain capacity of the CFFT and HC-FCS cylinders were degraded
continuously. The elevated temperature increased the moisture absorption rate of
the GFRP and cracks and debondings appeared earlier in the GFRP tube.
▪ CFFT bridge columns built in marine environment at San Francisco, USA, are
estimated to be degraded by 12% and 14% at 50-year and 100-year, respectively, in
normalized strength. The HC-FCS cylinders built in the same area are degraded by
41% and 45% for 50 and 100 years, respectively.
58
2.5. Conclusions
▪ Combined freeze/thaw, wet/dry and heating/cooling cycles barely degrade the
strength and axial strain of the epoxy-based CFFT.
▪ Both water immersion and sustained load further deteriorate stress and strain
capacities of epoxy-based CFFTs slightly.
▪ The conditioned CFFTs dissipate more energy than the unconditioned ones under
cyclic compression, due to the repeated opening and closing of the micro-cracks
among the epoxy of the GFRP tubes.
▪ In consideration of cost and especially when the CFFT is used in a regular non-
seismic area where high ductility and energy dissipation capacity are not
necessarily desired, the polyester-based GFRP tube could be a better option.
59
3.5. Conclusions
▪ Epoxy resin are more vulnerable to UV exposure than polyester resin, causing
yellowing and chalking.
▪ UV exposure barely affect the mechanical properties of both epoxy-based and
polyester-based GFRP
60
Thank you!
61
Fiber Matrix General View
62
Task 1: Literature Review
➢ Aramid fiber
▪ Susceptible to moisture absorption
➢ Carbon Fiber
▪ Inert to chemical solutions and do not absorb water
63
Task 1: Literature Review
▪ Moisture
• plasticization reduced modulus (reversible)
• reduce glass transition temperature (Tg)
• induce swelling stress upon moisture sorption micro-cracks
▪ Temperature
• Large differences in coefficients of thermal expansion (CTEs)
upon temperature change induce residual stress micro-
cracks
• High temperature reduced modulus
• Sub-zero temperature stiffer but brittle
64
Task 1: Literature Review
➢ Vinylester
▪ Less vulnerable to hydrolysis due to fewer ester groups and covered
with methyl functional groups, which do not react with water.
➢ Epoxy
▪ No hydrolysis since no ester group, but can adsorb up to 7%
moisture by weight due to large amount of hydrophilic hydroxyl
groups that attract water molecules plasticization (reversible)
65
Task 1: Literature Review
Fiber/Resin Interphase
▪ Inhomogeneous anisotropic region with thickness of one micron
▪ Bonding mechanisms:
• chemical bonds
• Van der Waals forces
• interdifussion
• residual stresses
• mechanical interlocking
67
Task 2: Environmental Chamber
68
Task 2: Environmental Chamber
2.2. Specimen Preparation
Specimen Preparation Matrix
12 in. high 3 3 3
CFFT
9 in. high 1 1 1
12 in. high 3 3 3
HC-FCS
9 in. high 1 1 1
▪ 12 in. high specimens: compression tests
▪ Three
2nd branch
1.2 1.2
piecewise 1.0
3rd branch
1.0
0.6 0.6
1st branch
CFFT_FT+S_1
significantly 0.0
-2.5 -2.0 -1.5 -1.0 -0.5 0.0 0.5 1.0 1.5 2.0
0.0
-2.5 -2.0 -1.5 -1.0 -0.5 0.0 0.5 1.0 1.5 2.0
Hoop Strain (%) Axial Strain (%) Hoop Strain (%) Axial Strain (%)
hoop direction
0.0 0.0
-2.5 -2.0 -1.5 -1.0 -0.5 0.0 0.5 1.0 1.5 2.0 -2.5 -2.0 -1.5 -1.0 -0.5 0.0 0.5 1.0 1.5 2.0
Hoop Strain (%) Axial Strain (%) Hoop Strain (%) Axial Strain (%)
70
Task 2: Environmental Chamber
2.9. Cyclic Compression and Energy Dissipation
1.4 1.4
was calculated as
CFFT_UC_3 CFFT_FT_3
value from every 0.2
CFFT_FT_3
0.2
CFFT_FT+S_2
taken accordingly
worst 0.2
CFFT_UC_3
1000
CFFT_UC_3
CFFT_FT_3
CFFT_FT+S_2 CFFT_FT+S_2
0.0 0
0.0 0.2 0.4 0.6 0.8 1.0 1.2 1.4 1.6 1.8 0.0 0.2 0.4 0.6 0.8 1.0 1.2 1.4 1.6
Axial Strain (%) Axial Strain (%)
71
Task 1: Envr. Chamber (Phase I)
1.4
2nd branch
1.2
0.6
1st branch
0.4
0.2
CFFT_UC
0.0
0.0 0.5 1.0 1.5 2.0
Axial Strain (%)
72
Task 3: Seawater Immersion
2.4
2.2
73
Background
Temp. &
FRP Low
High Temp. Moisture Moisture UV
Components Temp.
Cycles
plasticization: absorb 7% chalking
Epoxy elastic modulus reduce elastic mositure by and
stiffer
reduced; modulus and Tg weight yellowing
Resin but micro-cracks
degraded if swelling: micro- hydrolysis
Poly- brittle high
exceed Tg cracks due to by hydroxyl
ester resistance
swelling stress (OH) ions
leaching, molecule weight
fiber
Glass Fiber NA NA loss and properties NA
blooming
degradation
debonding
due to
Fiber/Resin incompatible
NA NA osmotic cracks NA
Interphase deformation
between fiber
and resin
74
Task 4: Seawater Immersion
20 20
Tank 1 (73 F) Tank 2 (95 F)
UC UC
12 12
T1P1 T2P1
8 T1P2 8 T2P2
T1P3 T2P3
4 4
T1P4
T2P4
0 0
0.0 0.5 1.0 1.5 2.0 2.5 0.0 0.5 1.0 1.5 2.0 2.5
Axial Strain (%) Axial Strain (%)
20
Tank 3 (140 F)
UC
12
T3P1
8 T3P2
T3P3
4
T3P4
0
0.0 0.5 1.0 1.5 2.0 2.5
Axial Strain (%)
75
Task 4: Seawater Immersion
2.0
T1
B1
1.0
M2
0.5
B2
0.0
0.0 0.5 1.0 1.5 2.0 2.5
Cylinder Axial Strain (%)
76
Task 2: Envir. Chamber w/ Water
2.2. Temperature in Air and Water
Condition Type Freeze/Thaw Heating/Cooling 1st Wet/Dry 2nd Wet/Dry 3rd Wet/Dry
-20°C 20°C 60% RH 60% RH 60% RH
Temperature/
to 20°C to 45°C to 95% RH to 95% RH to 95% RH
RH Range
@ 40% RH @ 40% RH @ 20°C @ 25°C @ 40°C
25 50
20
Freeze/Thaw Air Heating/Cooling Air
Water 45 Water
15
Temperature (ºC)
Temperature (ºC)
10 40
5
35
0
-5 30
-10 25
-15
20
-20
-25 15
0 2 4 6 8 10 12 14 0 2 4 6 8 10 12 14
Time (hours) Time (hours)
HC-FCS - Nothing
78
1.15. Conclusions
▪ Combined freeze/thaw, wet/dry and heating/cooling cycles barely affect
the strengths and stiffnesses of CFFT and HC-FCS, and deteriorate the
axial and hoop strains insignificantly.
▪ The sustained axial load further deteriorate the strain capacities of
CFFT and HC-FCS, due to the micro-cracks generated among the
resin. However, the sustained axial load does not affect the strengths of
the cylinders significantly.
▪ Combined environmental conditions barely affect the FRP/Concrete
interface, but the sustained load on CFFT and HC-FCS help improve
the interface contact.
79
Conclusions