REVIEW QUESTION

TOPIC : BUFFER TITRATION AND SOLUBILITY

1. The pH of a solution that contains 0.818 M acetic acid (Ka = 2.76 x 10-7) and 0.27 M sodium
acetate is__________.
2. In all these questions, Ka for ethanoic acid = 1.74 x 10-5 mol dm-3 .
a) Calculate the pH of a buffer solution containing 0.100 mol dm-3 ethanoic acid and 0.100 mol
dm-3 sodium ethanoate.
b) Calculate the pH of a buffer solution containing 0.500 mol dm-3 ethanoic acid and 0.250 mol
dm-3 sodium ethanoate.
c) In what proportions would you have to mix solutions of ethanoic acid and sodium ethanoate
of the same concentration in order to produce a buffer solution of pH 5.00?
3. Indicator is a solution which could have different color in acid and basic solution. When you
prepared by an indicator which has pKin = 8.4. What is the pH range of the indicator?
4.

You got a solution from your teacher. When you used several indicator above, Here are results:
Thymol blue : yellow
Litmus : red
Methyl orange : orange
Bromcresol green : yellow
What is the pH range of the solution given?
5. When 0.1 M acetic acid was titrated with 0.3 M of Sodium Hydroxide. What is the equivalence
point of the solution after neutralization?
6. A 0.1234-g sample of a diprotic acid neutralizes 8.4 mL of 0.065 M KOH solution. Calculate the
molar mass of the sample!
7. A 21 mL sample of 0.015 M KOH was titrated with a weak acid. It took 15.2 mL of the acid to
reach the equivalence point. What is the molarity of the acid?
8. In the titration of 10 mL of 0. 5 M HCOOH(Ka=1.8X10-5 ) with 0.1 M NaOH. What is the pKin of
an indicator which was suitable to this titration
9.

Which graph could be represented by titration which using indicator with Kin = 1.0 x 10-9

10.

How much water need to dissolve 10g of ammonium chloride at 50°C?

11. In a titration experiment, 2.5 mL of 0.15 M H3PO4 neutralize 5.0 mL of NaOH. What is the
concentration of the NaOH solution!(assuming all protons in phosphoric acid ionized in solution)
12. What is buffer solution used for? And describe how could a solution said to be a good buffer!
13. I have discovered a new chemical compound with the formula A2B3. If a saturated solution of
A2B3 has a concentration of 1.5 x 10-2 M, what is the solubility product constant for A2B3?
14. A solution made from pure barium hydroxide contained 1.74 g in exactly 50 cm3 of water. Using
phenolphthalein indicator, titration of 10.0 cm3 of this solution required 8.6 cm3 of a
hydrochloric acid solution for complete neutralization. [atomic masses: Ba = 137, O = 16, H = 1)
(a) write the equation for the titration reaction.
(b) calculate the molarity of the barium hydroxide solution.
(c) calculate the moles of barium hydroxide neutralized.
(d) calculate the moles of hydrochloric acid neutralized.
(e) calculate the molarity of the hydrochloric acid.
15. You were provided primary standard solution of potassium hydrogen phtalate (KHP). This
solution was used for doing standardization to sodium hydroxide which needed for titration
used. A 0.2 gram of KHP used to make standard solution. And sodium hydroxide used in this
standardization was 22.5mL. Standardized sodium hydroxide then used to titrate a 5mL sample
solution contain of acetic acid. For this titration, volume of sodium hydroxide used was 12 ml
a. Write the balanced equation for NaOH standardization
b. Write the balanced equation for titration reaction between sodium hydroxide and sample
c. Calculate the concentration of sodium hydroxide used
d. Calculate the concentration of sample
(Mr KHP = 204.22 gr/mol)
16. Order the following salts from lowest to highest solubility.
(a) SrSO4 (Ksp = 2.8 × 10-7 )
(b) Zn(OH)2 (Ksp = 4.5 × 10-17)
(c) PbI2 (Ksp = 8.7 × 10-9 )
(d) MnS (Ksp = 5 × 10-15)
17. PbCl2 is not very soluble in water with Ksp = 1.6 × 10-5 . The number of moles of PbCl2 that
dissolve in a litre of water is called the molar solubility.
(a) If x moles of PbCl2 dissolve in 1.00 L of water, what will be [Pb2+(aq)] and [Cl- (aq)] in terms of
x?
(b) Ksp of PbCl2 is 1.6 × 10-5 , work out [Pb2+(aq)] and [Cl- (aq)]
18. Determine the solubility in (i) in mol/L, and (ii) in gram/L of each of the following salts:
(a) AgCl, Ksp = 1.6 x 10-10
(b) AgBr, Ksp = 5.0 x 10-13
(c) Ag2CrO4, Ksp = 9.0 x 10-12
19. The solubility of calcium hydroxide, Ba(OH)2, in water at 35oC is 0.22 g/L.
a. Determine the solubility in mole/L
b. Calculate the solubility product constant (Ksp) for Barium hydroxide.
(Ar Ba=137, O=16, H=1)
20. A saturated solution of magnesium hydroxide, Mg(OH)2, has a pH = 8.4.
a. What is the solubility of Mg(OH)2 in gr/L?
b. Determine the Ksp of magnesium hydroxide.
(Ar Mg=24, O=16, H=1)