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SULTAN IDIUS EDUCATION UNIVERSITY

UNIVERSITI PENOIOIKAN SULTAN lORIS

FINAL EXAMINATION
SEMESTER 2 SESSION 2015/2016
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• CODE: SKF1013 COURSE: INTRODUCTION TO PHYSICAL

CHEMISTRY

DATE: o 1 MAR 2016 DURATION: 2 HOURS

INSTRUCTIONS

1. Answer ALL questions in the examination booklet. DO NOT use pencil.

2. SHOW YOUR WORK. Marks may be deducted for incomplete work.
3. Scientific calculator may be used in this examination.
4. This question paper will be collected at the end of the examination.

This question paper contains 2 pages including the cover page

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NAME:

YEAR: LECTURE GROUP: A

REGISTRATION NO. :
I I I I I I I I I' I I I I
IDENTITY CARD NO:
I I I I I I I I I I I I I
LECTURER : DR AISYAH MOHAMAD SHARIF
MRS ROZITA YAHAYA

DO NOT OPEN THIS QUESTION PAPER UNTIL YOU ARE TOLD TO DO SO

CONFIDENTIAL
 SKF1013 Introduction to Physical Chemistry 2

Answer ALL questions [50 Marks]

monoatomic ideal gas: Cv = 1.5 R

PV" = constant; VTCV/nR =

constant; rr pi-y =
constant

1. By using suitable diagram or equation, describe the following thermodynamic terms:

(a) Zeroth law of thermodynamics

(b) Heat (q)
(c) Internal energy (U)
(d) Irreversible proses

(e) Heat capacity (C)

[20 Marks]

2. Two moles of hydrogen gas behaves ideally and initially at 30.0 atm and 500 K. The

system is allowed to expand adiabatically against constant external pressure of 10.0

atm until equilibrium with final temperature of 350 K. [Assume Cp,m =

30 J rnolK"].
Calculate;

(a) MI

(b) AU
(c) q

(d) w

[15 Marks]

3. One mol of an ideal gas is expanded isothermally reversible from 4 L to 26 L at 300 K.

Calculate;

(a) AU
(b) MI
(c) AS
(d) M
(e) Predict the spontaneity of reaction
[15 Marks]

END OF QUESTIONS