IIT-JEE – 2010 (Code-5)

Answer Keys
(Paper–II)
Chemistry Mathematics Physics
1. C 20. B 39. B
2. A 21. C 40. A
3. D 22. D 41. B
4. B 23. D 42. D
5. C 24. A 43. C
6. D 25. B 44. D
7. 2 26. 1 45. 3
8. 6 27. 3 46. 4
9. 2 28. 4 47. 8
10. 3 29. 3 48. 2
11. 7 30. 0 49. 6
12. B 31. D 50. D
13. C 32. C 51. B
14. B 33. A 52. C
15. B 34. C 53. A
16. A 35. A 54. C
17. D 36. B 55. C
18. A - p,s 37. A-t 56. A - r,s,t
B - p,q,r,t B - p,r B - q,r,s,t
C - p,q C - q,s C - p,q
D - p,q D-r D - q,r,s,t
19. A - r,s 38. A-q 57. A - p,r
B-t B-p B - q,s,t
C - p,q C - p,s,t C - p,r,t
D-r D - q,r,s,t D - q,s

IIT-JEE–2010/Paper – II/Solution IIT-JEE Page 1

Test Prep
 Chemistry 7. 2 F always show –1 oxidation state. Na always show
+1 oxidation state.
1. C
8. 6 H2SO4, H3PO3, H2CO3, H2S2O7, H2CrO4, H2CO3 are biprotic
1. NaOH/Br2
H3C acid.
CONH2 H3C NH2
Hoffmann
bromamide rxn
9. 2 w S  (4  1.5)  (1 1)  (0.75  0.25)  8.875
COCl 5.5
2
wD   dV  4.6
V
0.5
H3C NH CO
wD
2
wS
2. A If Hund’s rule violated then electrnic configuration is
10. 3
1s2,  * 1s2, 2s2,  * 2s2, 2px 2 H3N CO H3N PPh3
16  41
B.O.  1 Rh
2 Rh
Bond order is 1 and diamagnetic.
Cl PPh3 Cl CO

H3N
PPh3
3. D S (Pyramidal)
Rh
O F
F CO Cl

4. B mass 108  3
11. 7 Density  
2+
Ni = volume 6.023  1023  4r 3

2–
[NiCl4] = 108  3
r3   4.08  10 24 cm3
23
6.023  10  4  3.14  10.5
[NiCl4]2– has two unpaired e– so
  n(n  2)  2(2  2)  8  2.82 B.M. r  1.4  1010 m

Area of one atom  6.15  10 20

5. C In P, —OH group is activating and o-, p-directing but —
COOH is deactivating. 1012
In Q, —OCH3 is more activating and o-, p- directing Number of atoms in 10–12 m2 area 
than —CH3. 6.15  10 20
In S, —CO— is deactivating and —O— is activating.
 1.6  107
Area occupied by atoms 12. B S1 has one radial node and spherically symmetrical 1s
6. D Packing Efficiency  l=0.
Total area of unit cell
Radial node = (n – l –1)
From unit cell, or n –0 – 1 = 1 or n = 2
L Therefore, S1 = 2s
4r  L 2  r  ; where r is the radius of atom.
2 2
Z2 9
13. C En  13.6   13.6 
2r 2
2L 2
  n2 4
PE    %PE   100  78.54 = 2.25 times to the energy of H atom in ground state.
L2 8L2 4 4

Page 2 IIT-JEE IIT-JEE–2010/Paper – II/Solution

Test Prep
14. B S2 has one radial node and energy is equal to ground Mathematics
state energy of H atom.
20. B x = 0, f(0) = 2
Z2
So 13.6  13.6  2  n  3
n e  x f (x)  e  x f(x)  1  x 4
Now radial nodes (n – l –1) = 1 f (0)  2  1 f (0)  3
or l = 1
f 1  f  x    x
Solution of Qs 15, 16, 17
f 1  f  x   f   x   1

O 1
O O f 1(2) 
aq. K2CO3 C H 3
H3C CH C H + H C H H3C C CH2OH
21. C OG refers to signal being green originally.
CH3 CH3
GR green received
(P) (R)
(Q) RR red received
HCN
 OG  P  OG  GR 
P 
OH  GR  P  GR 
OH OH
H3C O 4 3 3 4 1 1 1 3 1 1 1 3
 CH COOH CH CN P  GR             
H3C 5 4 4 5 4 4 5 4 4 5 4 4
H3C C CH2OH H3C C CH2OH
O H3O
+

CH3 CH 3 46
P(GR) 
(S) 80

4 3 3 4 1 1
P  OG  GR       
5 4 4 5 4 4
15. B
40
P  OG  GR  
16. A 80

OG  40
17. D  P  
 GR  46
18. (A  p,s); (B  p,q,r,t); (C  p,q); (D  p,q)

19. (A  r,s); (B  t); (C  p,q); (D  r) 22. D No. of required subsets will be 41

23. D A r  10 Cr , Br  20 Cr , Cr  30Cr
10

 10
Cr  20
C10 20Cr  30 C10 10Cr 
r 1

10 10
20 10 20
 C10  Cr Cr  30C10  10
Cr 10Cr
r 1 r 1

20
 C10 (30 C10  1)  30C10 (20 C10  1)

 30C10  20C10

 C10  B10

IIT-JEE–2010/Paper – II/Solution IIT-JEE Page 3

Test Prep
 (1,–2,1) 27. 3
x 1 y  2 y 1
24. A    /2k
1 2 2 (1,2,–2)
   1,2  2,1  2  2
2 2
x  2y  2z    0 /k
1 4  2   2
distance 5 
1 4  4
 
  5  15 2cos  2cos  3  1
2k k
  10   3 1
 cos  cos  
   1  2  2  2  2 1  2   10  0 k 2k 2 2
 1  3  
15 5  cos  or cos   
9  15  0   , k 2 2k 2 k 3
9 3 k3
5 5 5 28. 4
  1,2  2,1  
3 3 3
adjA   I | A |
8 4 7
 , ,  adj  | A |n1  | A |2
3 3 3
| A |2  | B |2  106
25. B
2k  1 2 x 2 k
A 2i+10j+11k B
A  2 k 1 2k , B 0
 2 k 2x 1
–i+2j+2k


A   2k  1 1  4k 2  2 k 2 k  4k k   
D D C

2 k 2 k  2k   2 k 
2  1  10  (2)  11(2)
cos  90    
2 2 2

A  8k 3  12k 2  6k  1 = (2k + 1)3 
22  102  112  1   2    2 3
 2k  1  10 6
 2k  1  10
40 2k  10

153 9
k
8 2
 sin   [k] = 4
9
29. 3
17
cos   A
9

26. 1 =15 3
10
2
f (x)  2010  x  2009  x  2010   x  200 

1 B 6 C D
f (x)  .g(x) g(x)  ef( x )
g(x)   15 3
g(x)  g(x) f (x)  e f( x) f (x) g(x)  0 if f (x)  0 1
Area of triangle   AD  BC
2
+ – + 1
2009 2010  15 3   AD  6
2
 AD  5 3

Page 4 IIT-JEE IIT-JEE–2010/Paper – II/Solution

Test Prep
 32. C Equation of line through B and perpendicular to PA is
Further AC2  CD2  AD 2  CD  5
8
2 y as AP is parallel to y-axis
2
 AB  5 3   2
 11  196  AB  40 5
As orthocentre (G) lies on the above line, let us assume
 s  15 and   15 3  r  3 , r 2  3
 8
G as  x1, 
30. 0  5

a1  15 mPG.mAB  1

further 2ak 1  ak  ak  2  ak  2,ak 1,ak are in A.P. 8  8 

 5  4  5  0  11
 a1, a2, a3…,a111 are in A.P.     1 x1 
 x1  3    9  3  5
a12  a22    a11
2
  5 
as  90
11  11 8 
orthocentre M  , 
Assume a6 = 15 – 5d, where d is the common difference  5 5
of A.P.
2 2 2 2
  a 6  5d    a6  4d     a6      a6  4d   9 8
33. A P(3, 4), A(3, 0), B   ,  let point be C(h, k)
2  5 5
  a6  5d   990
2 2

2 2
PC  h  3   k  4 
 a6  10d  90
line AB  8x  24y  2y  0
2 2
 15  5d  10d  90 8x  24y  24 x  3y  3
Distance of C from AB  
9 27 640 10
 d = – 3,  , only d = –3 is applicable as a2 <
7 2 2 2 2
 x  3y  3   10   x  3    y  4  
 
a1  a 2    a11
Hence a6 = 0 and 0 2
x 2  9  y  1  6x  y  1  10x 2  60x  90  10y 2
11
160y  160
31. D x 2  9y 2  18y  9  6xy  6x  10x 2  10y 2  60x
P(3,4) 160y  160
9x2  y 2  6xy  54x  62y  241  0

34. C f  x   4  3  3x 2  2x  1
(x1y1)B
A f (x)  12x 2  6x  2  0  x  R
(3,0)
f     

f     

f  0  0
x y
Equation of tangent from (3, 4)  1
3 4  1
f   0
2
 4
–1–3/4 –1/2 –1/4
x2 1  3  x  
Solving with the curve  4 1
9 4   3    1
f   0
 2
9 y  0, 8  3
solving we get x  3,  , f   0
5 5  4
 9 8 f  1  0
A  3,0  ,B   , 
 5 5
 3 1 
real root lies in   , 
 4 2

IIT-JEE–2010/Paper – II/Solution IIT-JEE Page 5

Test Prep
 1/ 2 3/ 4
I1  f(x)dx, I2  f(x) dx 3
35. A 
0 
0
(B) tan1  x  3   tan1  x  3   sin1
5
1/ 2
 x  x2  x3  x4 x3x3 3
0
tan1  sin1
3/4 1  x2  9 5
I2  x  x 2  x 3  x 4
0
6 3 3
tan1  sin1  tan1
15 525 x2  8 5 4
I1  , I2 
16 256
6 3
 
x2  8 4
36. B
x2  8  8
37. (A  t), (B  p,r), (C  q,s), (D  r)
(A) Equation of plane passing through origin will be x 2  16 x  4.
A(x – 0) + B(x – 0) + C(z – 0) = 0   
(C) a.b  0  a  b
   
If this plane contain line1
x  2 y 1 z 1
  ,
 
ba . bc 0 
1 2 1
 2    
the following c onditions must be true  b  b.c  a.c …(ii)
   
A ×1 + B × –2 + C × 1 = 0 …(i) 2 bc  ba
(direction ratio of normal to the plane are A,B,C)
and 2 2  2
A(2) + B(1) + C(–1) = 0 …(ii) 3 b  4 c  8b.c  a …(iii)
(point (2, 1, –1) lies on the plane)   
Solving (i) and (ii) we get  a  b  4c
2  2 2  
A = 3B and C = + 5B  a  2 b  16 c  8 b .c
Hence equation of the plane passing through origin
and containing line 1 will be
x + 3y + 5z = 0 
Similarly we can find equation of plane passing through  
 3  2 b2  12c2  8    1 b.c
origin and containing line 2 as
3x + y – 5z = 0   
The equation of line which intersect line 1 and line 2 Further, b2   4b.c and 4c 2  a.c b.c
will be  
x + 3y + 5z = 0 = 3x + y – 5z 4c2  b2  b.c  b.c
  
Direction ratios of this line will be in ratio of 5, –5, 2
Hence the equation of the desired line will be
 
 3  2 b2  3b2  3b.c  3b.c  8   1 b.c

x

y z
 ..... line 3
 
 2 b2  5    1 b.c
5 5 2
 
    b2 2
 5    1    b2
To find out P , we will solve line 1 and line 3.
 4
 42  52  5    0,5
x  2 y 1 z 1
let us assume   = r and
1 2 1

x y z
  = s
5 5 2
r+2 = 5s ; 1-2r = -5s ; r-1 = 2s
we get , r = 3 .
Hence , P = ( 5, -5 , 2)
Similarily by solving line 3 and line 2 , we get
Q = ( 10/3 , -10/3 , 4/3)
PQ2 = 6

Page 6 IIT-JEE IIT-JEE–2010/Paper – II/Solution

Test Prep
 9x x 2  16  8x  y 2  100  20
2
 y2
sin  x  4
(D) f(x)  2 it is an even function
x  x 2  16  8x  y 2
sin
2
2
9x 9x x 16x  100  20  x  4  y2
sin 2sin cos
2  4  2 dx  4  2 2 dx
  F(x)dx  
   0 sin x  0 2 sin x cos x 4x  25  5  x  4
2
 y2
2 2 2
4  sin5x sin4x  sin4x 16x 2  625  200x  25x  25x2  400  200x  25y2
  dx  dx  0
 0 sin x sin x  0 sin x 9x2  25y2  225
2
4x  / 2 sin5x x2 y 2
 dx
 0 sin x 
25 9
1
8  / 2 sin3x cos x  cos3x sin 2x
  dx
 0 sin x
(C) Let w  2  cos   isin  
8 /2
 0
 
3  4 sin2 x cos 2x  2cos3x cos x dx
1 1 1
zw  2 cos   isin     cos   i sin  
8 /2 w 2
3  2(1  cos 2x) cos2x  cos 4x  cos2x dx
 0
1
8 / 2  2  cos   i sin     cos   i sin  
cos 2x  1  cos 4x  cos 4x  cos2x dx 2
 0
3 5
/ 2  cos   isin 
8  2 sin 4x 2 sin2x  2 2
   x
  4 2 0 If z = x + iy
8   3 5
 0  0   0  4 x cos  y sin 
  2  2 2
2 2
38. (A  q), (B  p), (C  p,s,t), (D  q,r,s,t)  2x   2  2 2
    y   cos   sin 
(A) z = x + iy  3  5 

x  iy  i |  x  iy  |  x  iy  i x 2  y 2 x2 y2
 1
9 25
 
x  i y  x2  y2  x  i y  x2  y2   4 4

9 25
2 2
x  y  x  y  2y x  y 2 2 2 2

4

4

1  e2 
 x 2  y 2  x 2  y 2  2y x 2  y 2
9 4
4y x 2  y 2  0 e2  1  e 
25 5
 y=0
Im(z) = 0 (D) w 1

1
(B) z  4  z  4  10 Let w  cos   isin    cos   isin 
w
This condition for ellipse
ae = 4 2a = 10 1
4 zw  2cos 
e w
a=5
5
z  2cos 
Let z  x  iy
2 If z = x + iy, x  2cos , y  0
 x  4  iy   x  4   iy  10
Re  z   2 Im(z)  0
2 2
 x  4  y2  x  4  y 2  10

IIT-JEE–2010/Paper – II/Solution IIT-JEE Page 7

Test Prep
 Physics 16
42. D 1 MSD = 1mm, 1VSD   0.8 mm
39. B 20
FL=15cm  LC = 1 MSD – VSD = 0.2 mm

43. C Area under the F-t graph represents the change in

momentum
1
Area 
2
 4  3  2  1.5  4.5

 P  4.5kg  m / s  Pf  Pi  Pf as Pi  0
30cm 10cm 2
Pf2  4.5 
st
KEf    5.06
For the lens, as the object is at 2F the 1 image will be 2m 22
at 2F.
This image acts as an object (virtual) for the mirror 4 3
and hence it forms the 2nd image 20 cm in front of the 44. D r g  qE  6 rv
3
mirror, which, acts as a virtual object for the lens
place at 10 cm from the lens to its left in the direction of qE
 r  6 v
incident light.
1/ 2
1 1 1 
 63 23 v 3 3  
 For final image v  10  15 q 
2
 4E g 
v = 6 cm to the left of the lens.
 the image is 16 cm to the left of the mirror and is
real. 45. 3
1 1 1
 
40. A Pressure at a point on a charged spherical shell due to v u f
25
   2 v1  m,sou1  50m
its own charge is P    2   2 3
 0 0
50
Thus, force on each hemi-spherical shell will be v2  m,sou2  25m
7
Displacement of object = 25 m
2
FE  P.A. 
20
R2  Time = 30 s
25 18
Hence, external force required to hold the shell is  speed  30  5  3 km / hr
proportional to
46. 4
2R2
FE  2/5
0 V 
T1V1 1  T2 V2 1 T1V11  T1  1 
 32 
2/5
41. B Length of pipe = 0.8 m     32  4
Length of string = 0.5 m
Tension = 50 N
47. 8
velocity of sound = 320 m/s
Vsound = Vstring dN dN
 N0 e t ln  ln  N0   t
4Lpipe = Lstring dt dt
320 1 50 Y  C  mx

4  0.8 0.5  1 1
m 
2 2
1 m 1
   50  0.5  50 N 1
  e t  e 2.08
N0 P
1 ln P = 2
 m  100 kg  10 gm or P = e2
P8

Page 8 IIT-JEE IIT-JEE–2010/Paper – II/Solution

Test Prep
48. 2
52. C I  r 2 [where  is the reduced mass r is the distance
Time constant of the circuit = ReqLeq
between C and O]
  4s
Instantaneous voltage  mm 
1.87  1046   1 2  r 2
 m1  m 2 
 
V  V0 1  e  t / 
on solving r = 1.3 × 10–10 m
4  10 1  e  t / 4

53. A Since force due to surface tension

e  t /   0.6 F = T.l [l is the length line in contact)
t 5  T.2r (given r << R)
 log    log5  log3
 3 Therefore answer is (A)
Hence t = 2s
54. C W hen drop detaches; total upward force = Total
49. 6 downward f orce
2rT  mg
R 4 3
 2rT  R g
3
ic 3rT
R3 
2g
R  2  103 m
8cm ic
55. C Surface energy  4R 2 T
 4   4  10 6  0.11
3  5.4  10 6 J
sinic 
5
56. (A  r,s,t), (B  q,r,s,t), (C  p,q), (D  q,r,s,t)
3 R
 tanic  4  8  R = 6 cm For circuit p
I = 0, V1 = 0, V2 = V
Since it is an L-C circuit connected to a D.C. source,
capacitor will cease the flow of current in steady
nh
50. D I  state.
2 For circuit q
nh It is an R-L circuit connected to a D.C. source, thus V1
  across the inductor will be zero and V2 is equal to V,
2I
I  0 and hence V2 > 0.
1 2 For circuit r
Therefore K.E.  I
2 It is an R-L circuit connected to an A.C. source where
2
XL = LW = 6 × 10–3 × 2  50 = 1.88 ohm. But, R is
1  nh 
  I  2 ohm. Therefore XL < R, hence I  0 , V1 < V2 and V2
2  2I 
is proportional to I.
n2h2 For circuit s
 It is an L-C circuit connected to an A.C. source, where
82I
XC > XL. Hence I  0 , V2 > V1 and V2 is proportional
to I.
51. B Change in rotational energy = h
For circuit t
h2 it is an R-C circuit connected to an A.C. source where
8 2I

22  12  h  XC < R. Hence I  0 .
V2 is proportional to I and V2 < V1
3h
 I  1.87  1046 kgm2
82  57. (A  p,r), (B  q,s,t), (C  p,r,t), (D  q,s)
Ray bonds towards the normal on entering denses
medium from rarer and away from the normal when
going from denser to rares.

IIT-JEE–2010/Paper – II/Solution IIT-JEE Page 9

Test Prep