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IN ANY survey of stainless steel applications it is soon apparent instantaneously re-form to give continuous protection, provided
that in the vast majority of cases it is the corrosion resistance of a source of oxygen is available. In practice, a source of oxygen
the material which is the deciding factor in its selection. can mean atmospheric air or an oxidising solution such as nitric
Appearance, non-toxicity, retention of strength at high and low acid.
temperatures, and ease of fabrication are all important in varying
degrees, but the widespread applications of stainless steel—
a material which celebrated its first half-century only a few
Applications in an atmospheric environment
years ago—follow principally from its inherent 'stainless' It is generally accepted that the marine/industrial atmosphere of
properties which confer a remarkable degree of resistance to the United Kingdom can be exceptionally aggressive to building
attack in a wide variety of environments. materials. This is particularly the case in the large industrial
During the past 50 years a number of different stainless steels cities where high sulphur and chloride pollution occurs following
with varying compositions have been developed. These can be the large-scale combustion of fossil fuels. Nevertheless, stainless
classified in three main groups, namely martensitic, ferritic and steel has been used satisfactorily by the building industry for
austenitic. All stainless steels contain large amounts of chro- over 35 years for internal and external applications. Early uses
mium, while the austenitic steels have nickel as well as chromium related mainly to shop-front sections and decorative façades—
and sometimes additional elements such as molybdenum,
titanium and niobium.
The martensitic steels, which generally contain not less than
11% chromium, can be strengthened and hardened by quench-
ing and tempering. Like carbon steel, they are magnetic and
are used chiefly for cutlery and in the manufacture of tools and
steam turbine blading—applications which normally do not
demand the very highest degree of corrosion resistance.
Ferritic steels also contain chromium as the only important
alloying element. They, too, are magnetic but they are not
hardened by heat treatment. Their chromium contents com-
monly vary from 17-20% and their corrosion resistance, which
is moderate compared with that of the austenitic steels, is
adequate for applications such as motor-car trim, bumpers and
items of kitchenware.
The most important group of stainless steels is that having
an austenitic structure at ambient temperatures. The fully
austenitic structure is very soft and ductile and there is no
sharply defined yield point. Austenitic steels work harden
rapidly, to give high tensile strengths while maintaining good
elongation values. They are particularly amenable to cold
forming and this advantage, together with their excellent
corrosion resistance at ambient and elevated temperatures, and
ease of forming has led to their widespread usage in many
branches of industry.
Corrosion-resistant applications
When Brearley noted the phenomenon of non-rusting chro-
mium steels in 1913 he was recording for the first time an
example of the corrosion resistance which is a feature of all
types of stainless steel. This immunity to attack is due to the
chromium-rich oxide film which is always present on the
metal's surface. The film is transparent and extremely thin—
less than 130Å thick—but it is inert and very tightly adherent
to the metal. Most important of all, it is self-repairing, which
means if the surface is scratched or abraded the film will
July 1969 ANTI-CORROSION 11
Chemical engineering
The chemical and petrochemical industries are among the
growth sectors of the economy. The range of materials handled
and the diversity of the end-products are rapidly increasing.
In all but a few branches of chemical engineering, stainless steel
is regarded as one of the principal materials of construction.
The corrosion resistance and ductility of the austenitic steels
permit them to be used for agitators, distillation and evaporation
plant, filtration units, separators, mixers and many ancillary
items, such as tanks, pumps, valves, pipework and fasteners.
Stainless steel is also closely concerned in the transport of
chemicals by road, rail and water. The first stainless steel road
tanker was built in 1931—the forerunner of thousands of similar
vehicles, some with capacities in excess of 6,000gal. The
carrying of chemicals by sea is a fairly recent development.
Compared with the giant supertankers used for oil, chemical
carriers are small but, nevertheless, several hundred tons of
stainless steel plate may be required for the cargo tanks of one
such vessel.
Information regarding the effect of various chemicals on
different stainless steels can be obtained from the Stainless
Steel Development Assn., or from companies within the
steel industry who have carried out extensive laboratory tests
on this subject. In general, it can be said that mineral acids
which are oxidising by nature, such as nitric acid, can be
handled safely in stainless steel at most concentrations and
temperatures. There is, in fact, extensive use of chromium-
nickel stainless steels for the plant used in the manufacture of
nitric acid, particularly by the ammonia oxidation process.
Phosphoric acid also has little effect on molybdenum-bearing
July 1969 ANTI-CORROSION 15