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Froth Flotation
1
Introduction
Froth flotation is a surface-chemistry based process of separation of fine solids that takes
often naturally wettable by water and termed hydrophilic. A surface that is non-wettable
typically air attracting, termed aerophilic, and is strongly attracted to an air interface,
which readily displaces water at the solid’s surface. In froth flotation, separation of a
solid particles to gas bubbles (typically air). The other hydrophilic solid particles remain
in the liquid (typically water). The difference in the density between the air bubbles and
water provides buoyancy that preferentially lifts the hydrophobic solid particles to the
surface where they remain entrained in a froth which can be drained off or mechanically
Froth flotation is often used to separate solids of similar densities and sizes, which
prevent other types of separations based upon gravity that might otherwise be employed.
It is especially useful for particle sizes below 100ìm (150 mesh), which are typically too
small for gravity separation using jigging and tabling. The lower-size limit for flotation
been separated. At these small particle sizes, it may be difficult to take advantage of
particles greater than 200 ìm (65 mesh) tend to be readily sheared from the bubble
surfaces by collision with other particles or vessel walls. However, relatively low-density
Froth Flotation
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materials, such as coal, may be successfully separated up to 1600 ìm (10 mesh) in some
systems.
Froth flotation has been used in the minerals processing industry since the mid-1800’s
between 1900 and 1925. Today, at least 100 different minerals, including almost all of
the world’s copper, lead, zinc, nickel, silver, molybdenum, manganese, chromium,
cobalt, tungsten, and titanium, are processed using froth flotation. In 1997, the estimated
worldwide mineral production, using froth flotation, was two billion tons. Another major
usage of froth flotation is by the coal industry for desulferization and the recovery of fine
coal, once discarded as waste. Since the 1950's, flotation has also been applied in many
and chemical, plastics, and food processing. The development of froth flotation
continues today with the need to recover minerals from increasingly poorer grades of ore,
There are several different types of froth flotation systems in use today including the
mechanical type, of which there are many subtypes, and the flotation column. The type
mechanical type shown in Figure 1. While this is a laboratory scale unit capable of
handling up to 5 L (5 x 10-6 m3), the same equipment type and principals are used at the
industrial level up to 7,000 ft3 (200 m3). A photograph of a 1000 ft3 unit is shown on the
Froth Flotation
3
Rotating Shaft
Air
Froth
Layer
Frothing
Tank Froth Effluent
Hydrophobic Particle
Hydrophilic Particle
Agitator Air Bubble
The froth-flotation apparatus to be used consists of a frothing tank containing the solution
recirculatory mixing of the solids and solution. Air is introduced through the shaft and
exits into the solution at the bottom of the agitator (sub-aerated). The introduction of air
creates bubbles that are stabilized by an added frothing agent. The hydrophobic particles,
activated by an added collector agent, adhere to the air bubbles (frothers and collectors
will be discussed in subsequent sections). Due to the density differences, the air bubbles
rise to the surface of the solution where they collect as a froth layer (the concentrate
stream) which spills over into a froth-collection tray. The froth may also be mechanically
skimmed off. The hydrophilic particles remain in solution, which is eventually decanted
off as waste (the tailing stream). Typically, the concentrating stream contains the desired,
Froth Flotation
4
Objectives
The purpose of this experiment is to investigate the various aspects of the froth-flotation
including the types and concentrations of collectors, frothers, and modifiers (depressants,
activators, and pH regulators). The conditioning times; solids loading and weight
fractions; agitator speed; aeration rate; particle densities, sizes, and shapes; and the
temperature may be varied. Data analyses will include determination of the grade and
recoveries of the more desired material with respect to the effect of the experimental
concerning possible behavior of the system with respect to the quantitative results. Based
upon the experimental results, the different separation outcomes should be compared and
contrasted and optimal parameter ranges should be postulated for the separations. Scale-
up considerations of these laboratory results to larger flotation systems and their use with
methodology to achieve viable separations, data, and analyses. It will be easy to identify
activated carbon. Characterize your feed by composition and by particle size of each
Froth Flotation
5
Background
Wettability
Froth flotation involves three phases – solid, liquid, and gas – and the corresponding
characterizes wettability is the contact angle at the three-phase interface (Figure 2). The
contact angle, è, is related to the respective interfacial surface tensions, ãSG, ãSL, and ãLG,
Air
spreads over the solid, the solid is hydrophilic – characterized by a contact angle of 0o < è
< 90o between the water drop and the solid surface at P. At these angles, air bubbles do
not readily adhere to hydrophilic solids in water. Conversely, when the solids are not
Froth Flotation
6
readily wetted by water, the solids adhere to the air bubbles and the characteristic contact
angle is 90o < è < 180o, and these solids are said to be hydrophobic (or aerophylic). An
intermediate regime, è = 90o, may exist where the solid does not exhibit either strong
The hydrophilic or hydrophobic character of the solid expressed by the contact angle is
necessary to actually obtain a hydrophobic solid as defined by a è > 90o. Contact angles
in flotation systems typically do not exceed 100o. What is more important is that the
system is operated in such a manner that one of the solid components has a greater –
preferably a substantially greater – hydrophobicity than the other solids from which it is
to be separated. It has been found that a è of at least 20o is necessary for bubble
attachment and successful flotation, and è’s > 20o are desirable for effective separation.
Many materials, such as minerals, are nonpolar and are more naturally hydrophilic than
hydrophobic in water. However, there are also many exceptions such as coal with a
natural è = 45-60o and talc with a natural è = 88o (see the bottom of Table 1 in next
section).
necessary to selectively enhance the hydrophobicity of one of the solid components that
collectors.
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Collectors
are typically heteropolar organic substances – they contain both nonpolar and polar
chemical groups. The nonpolar end is almost always a long-chain or cyclic hydrocarbon
group that is hydrophobic. The collector must be able to attach to the solid, and it does so
through its polar end, which is typically an ionic group termed the solidophil group.
When the solidophil group of a suitable collector contacts a mineral at a surface site that
can chemically interact with the solidophil group, the collector bonds to the surface of the
mineral via chemisorption or ionic bonding. The nonpolar end of the collector then
orients outward from the solid surface forming a nonpolar chemical envelope
hydrophilic solid surface. The solid particle can then more readily attach to an air bubble
Froth Flotation
8
hydrophilicity of the nondesirable material. It should also be noted that the strength of
the induced hydrophobicity of the mineral via the collector is directly relatable to the
length of the hydrocarbon group while the strength and selectivity of the collector’s ionic
There are many different types of collectors, and they are classified as to the type of ion
(anionic or cationic) that is formed upon their dissociation in aqueous solutions. For
which is hydrophobic and a polar carboxyl group, [COONa], which is the solidophil
R C
This anionic carboxyl group will bond with minerals that contain alkali-earth metal
cations such as Ca, Ba, and Mg, as well as carbonate, oxide, and sulfate minerals.
Other widely employed anionic collectors include the xanthates, containing bivalent
sulfur, that are highly selective collectors in the separation of sulfide minerals. The
xanthate anion is
R O C
S
Froth Flotation
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Other types of collectors are used in froth flotation including dithiophosphates and alkyl
sulfuric salts that are also anionic collectors. The later include sodium dodecyl sulfate and
sodium lauryl sulfate, used in detergents. The later have the sulfo-solidophil group
O O
R O O
Cationic collectors are less widely used. The most common types contain amine groups,
such as aniline and pyridine, but cation attachment to most minerals is typically weak.
They are also typically water insoluble and require the presence of acids to induce
solubility. However, cation collectors are used for silicates and other oxides, including
related to the contact angle, è. Examples of contact angles modified by various collectors
for various minerals are indicated in Table 1, as well as those for naturally hydrophobic
Froth Flotation
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Table 1. Contact Angles for Various Solids and Collectors
(adapted from Encyclopedia of Chemical Technology 4th Edition, Vol. 11 (1997) p. 88.
Frothers
presence of frothers. Once its surface is rendered hydrophobic, a solid particle must be
able to attach to an air bubble. While it may be possible to initially obtain solid particle
attachment to air bubbles in an agitated liquid under aeration alone, these air bubbles are
unstable and quickly break down due to collisions with other bubbles, solid particles, and
the vessel walls. In addition, the bubble size may not be sufficient to effectively carry a
solid particle to the surface of the liquid. Consequently, additional materials, termed
frothers, are added to promote the formation of stable air bubbles under aeration.
Frothers, like collectors, are typically comprised of both a polar and nonpolar end. The
nonpolar hydrophobic ends orient themselves into the air phase. Bubble wall strength is
surface tension.
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Frothers are generally classified by their polar groups with the most common being the
hydroxyl (–OH), carboxyl (–COOH), carbonyl (=C=O), amino (–NH3), and sulfo (–
OSO2OH and–SO2OH) groups. Table 2 lists some common frothers according to their
chemical grouping. Effective frothers typically contain at least five or six carbon atoms
in their straight-chain, nonpolar group to obtain sufficient and stable interaction with the
air phase. For branched-chain hydrocarbons, the number of carbon atoms in the nonpolar
group may range up to sixteen. However, a frother must be at least slightly soluble in the
maximum of eight, e.g., octyl alcohol) will eventually lead to too low of a solubility for
effective frothing. Thus, a suitable frother must provide a balance between sufficient
nonpolar interaction with air and solubility in water. With respect to the polar groups,
one or two are usually sufficient to interact at the liquid-air interface to provide sufficient
Most of the frothers in Table 2 are hydroxyl-group-type frothers, and, thus, have little
collector can also serve as a frother in some systems. This is true of the carboxyl-type
frother, sodium oleate, and the sulfo-solidophil fatty acids. Certain collector/frother
combinations may also exhibit a synergistic separation effect. However, one designs a
flotation system based upon a collector specific to the modification of the surface
properties of the solids required for separation. The type of frothing agent is a secondary
consideration that is chosen after the collector to provide suitable frothing conditions and
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Table 2. Examples of Frothers.
Frother Formula
Aliphatic Alcohols CH3(CH2)nCH2OH, n = 3–5
MIBC (4-methyl-2-pentanol) CH3CH(CH3)CH2CH(OH)CH3
di-acetone alcohol (CH3)2(OH)CH2COCH3
2-ethyl 3-hexanol CH3(CH2)3CH(C2H5)CH2OH
Cyclic Alcohols
pine oil (terpineol) C10H17OH
eucalyptus oil (cineole) C10H16O
Phenols
cresol CH3C6H4OH
xylenol (e.g., xylitol) HOCH(CHOH)3CH2OH
Alkoxyparaffins
1,1,3-triethoxybutane CH3CH2CH(OC2H5)CH(OC2H5)2
Polyglycols
poly(propylene glycol) monalkyl ethers R(OC3H6)nOH, n = 2–5, R = CH3, C4H9
poly(ethylene glycol)s R(OC2H4)nOC2H4OH, n = 2-5
Other
sulfo-cetyl alcohol CH3(CH2)14CH2OSO2OH
Modifiers
“resurface” the solid to increase the interaction with collectors that are otherwise
ineffective alone. Depressants form a polar chemical envelope around the solid particle
that enhances hydrophilicity or selectively prevents interaction with collectors that may
so that single particles interact with the collectors and air bubbles. Regulators are
commonly used to control the pH since the hydrophobicity of systems is often optimal
within a certain pH range. Frothers also often need a certain pH range in order to form
stable bubbles. The presence of reducing agents may also serve to prevent the presence
of soluble ions due to oxidation that may undesirably activate certain minerals.
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Separation Kinetics
It should be emphasized that the overall dynamics and kinetics of froth flotation
surrounding the solid particles and its hydrophobic nature. While one must still consider
the particle size and mass of the material since these affect the ability of the bubbles to
successfully transport the solid particle, the type of material that lies beneath the
Consequently, if enough conditioning time has been provided for collector action to
selectively render the desired solid particles hydrophobic, the remaining overall
separation is essentially dependent only upon the efficiency of the bubble and solid-
particle interactions (assuming the particle size and density are within a suitable range).
The overall flotation efficiency, EF, of the separation system may be defined by
EF = EC • EA • ES (Eq. 2)
where EC is the collision efficiency, EA is the attachment efficiency, and ES is the stability
dC
rs = − = k C n (Eq. 3)
dt
the frothing tank; t is time; n is the order of the process, n = 0, 1, 2,…; and k is the
flotation rate constant. This approach to flotation rate modeling is analogous to that used
in chemical-reaction kinetics. It must be re-stressed that this rate expression is for the
overall separation process and not the reaction of the collector at the solids surface.
Froth Flotation
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In kinetic modeling, one often assumes a reaction order and subsequently determines the
accuracy of that assumption based upon the experimental data. However, in practice for
all but the simplest processes, there are often undeterminable or unknown system
compare systems. This is often termed a pseudo-first-order assumption, and Eq. 3 with n
= 1 has been found to adequately model most flotation systems comprised of a single
rate expression
Ct − Co = e − kt (Eq. 4)
or
C
ln t = − k t (Eq. 5)
Co
the frothing tank at time t and Co is the concentration of the desired component at t = 0,
the beginning of the separation. Note that the ratio Ct/Co is the fraction of the desired
Based upon bubble-particle capture modeling, the flotation rate constant may be
expressed by
3 G EF h
k= (Eq. 6)
2 db V
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where G is the gas flow rate; db is the average bubble diameter; and V and h are the
volume and depth, respectively, of the particle suspension. If k is known, then the
flotation efficiency, EF, can be estimated from Eq. 6 for a given system with known db.
The flotation rate constant, k, can be determined from a plot of ln [Ct/Co] vs. t (see Eq. 5)
from experimental data. If this plot is linear, then the assumption of overall first-order
separation kinetics is valid. However, in actual systems this plot often exhibits
hydrophobic strengths of the solids. The result is a distribution of flotation rate constant
values. The recovery rate is then represented by a sum of a series of exponential terms,
Froth Flotation
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Experimental Equipment
The principal experimental apparatus used for this lab is the D-12 Lab Flotation Machine
appears in Figure 4. Further details about this unit are provided in the manufacturer’s
equipment manual available in the lab. The apparatus provides recirculation and
agitators/mixer heads are supplied with the equipment; however, all experimentation
should be done with the installed agitator unless directed otherwise by the instructor.
Speed-Adjustment
Knob RPM Indicator
Motor
Aeration Valve
Agitator Shaft
Housing
Power Switch
Height-Adjustment
Handle
Height-Adjustment
Stop Knob Agitator Assembly
Base
Frothing Tank
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The vertical position of the agitator is adjusted by pulling out the stop knob on the left-
hand side of the unit and turning the lever on the right-hand side (Caution – the agitator
assembly is heavy). The rotation speed (rpm’s) of the agitator is varied by turning the
knob at the top of the motor at the back of the unit (Caution – only change the motor
speed with the motor running). An rpm tachometer is located at the top of the unit. To
change the agitator rpm’s, back off the lock ring (the knurled ring) and turn the top knob
clockwise to decrease the speed and counterclockwise to increase the speed. Retighten
the lock ring. Air, via a petcock valve located near the top of the agitator shaft, is
introduced through the shaft into the aqueous solution to promote frothing. This aeration
Flotation tanks are available in various sizes ranging from 1.5 to 5 L. The flotation tanks
are designed with an effluent lip to allow the froth to exit for collection in the froth-
collection trays. Both stainless-steel and acrylic tanks are available. The acrylic tank
may be used to qualitatively view the particle, bubble, and fluid behavior under agitation.
The 1.5 L stainless steel tanks (2 are available) should be used for all other
temperature using the 1.5 L tanks. Only distilled water (available in the lab) should be
used in the heating bath. The temperature set point is chosen via a dial located at the top
of the immersion heater. A temperature meter and thermocouple are used to monitor the
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A pH meter is available to measure the pH of the various flotation solutions before and
after the addition of various collectors, frothers, inhibitors, promoters, and pH regulators.
Other equipment required for the experiment includes appropriately sized sieves,
distilled- water wash bottles, weight balance, weighing pans or paper, graduated cylinder
of volumetric flask, hot plate, beakers, stirring rod, and filter paper (coffee filters work
well).
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General Methodology
The following procedures outline the general methodology for running most froth
flotation experiments with the equipment in the lab (see next section for specific
separations).
1.) For ambient temperature operation, choose the desired frothing-tank size and
place it under the agitator. A cutout under the frothing tank will center it. Lower
the agitator to the desired height (typically ½ to ¾”. from the frothin g-tank
floor). Caution – firmly grasp the adjusting handle before disengaging the stop
knob and ensure that the stop knob is fully engaged when finished.
2.) If using the heating bath for elevated temperature operation, only the 1.5 L
stainless-steel tanks can be used. Insert the frothing tank into the empty heating
bath, centering it on the standoff on the floor of the heating bath. The frothing-
tank effluent lip should nestle over the cutout along the top of the heating bath.
Place the 1 in. high tray support under the heating bath and position the heating
bath against the back of the flotation unit’s main-support column. Lower the
agitator to the desired height (typically ½ to ¾”. from the frothing -tank floor).
Adjust to center the agitator in the frothing tank. The frothing tank will first
need to be filled with water to enable it to settle in the heating bath. Thus, do the
following in conjunction with Step 3 – fill the heating bath with distilled water to
within 1 to 2” from the top of the heating bath. Place the froth diverter (a bent
aluminum panel) over the lip of the frothing tank with the bent, side supports
facing down.
3.) Measure out a suitable amount of distilled water and fill the frothing tank with
the agitator in place. For a 1.5 L tank, this amount is ~1.3 L of distilled water
yielding a liquid height approximately ½”below the effluent lip of the frothing
tank.
4.) Place a froth-collection tray (3 or 4 plastic ones are available) under the effluent
lip of the frothing tank. Position several other froth-collection trays nearby so
that they can be readily replaced during a run.
5.) Turn on the agitator and set the desired agitator speed using the set knob and
rpm-indicator dial. Caution – change the agitator speed only with the motor
running and always retighten the lock ring when finished with the adjustment.
6.) Open the aeration petcock valve at the top of the agitator shaft and the ball valve
on the rotameter-inlet line, and set the airflow to the desired setpoint using the
needle valve on the rotameter inlet line. Calibrate and record the airflow.
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7.) Adjust the liquid height in the frothing tank if excessive spillage occurs at a
given speed and airflow. Record the new volume.
8.) Turn off the aeration at the ball valve on the rotameter-inlet line. Leave the
aeration petcock valve open.
9.) Pre-sieve the desirable-component and gangue solids to obtain particle sizes that
enable subsequent separation by sieving and quantitative weight analyses after
flotation. Record all sizes.
10.) Weigh out the desirable-component and gangue solids to obtain the desired
weight fraction. If a pre-mixed solids sample is used, determine the weight
fraction. Record all weights.
11.) Weigh out the desired amounts of collector, frother, depressant, promoter, etc. If
liquid, measure out using a graduated cylinder or volumetric flask. Record all
values.
12.) Record the temperature of the frothing tank using the thermocouple. If using the
heating bath, set the heating bath to the desired temperature using the immersion
heater set-point dial (calibrated in oF). Maximum operating temperature should
not exceed 75oC. Monitor the heated-bath and frothing-tank temperatures until
the desired temperature is obtained.
13.) Calibrate the pH meter using suitable calibration solutions (see the instructor).
Record the pH in the frothing tank.
14.) Pour the solids mixture to be separated into the frothing tank and allow mixing.
15.) With the aeration still off, separately add any promoters, inhibitors, pH
modifiers, collectors, and frothers and record the time, temperature, and pH after
each addition. A conditioning time (~typically 1 to 2 min. although it may be an
im) should follow each addition, and the sequence of the additions and their
conditioning times recorded. Note any qualitative observations of the frothing
tank solution such as dispersion or coalescence of solids, bubble formation, etc.
16.) To begin froth-flotation separation, turn on the ball valve at the rotameter-inlet
line and record the time. Froth should build and begin to elute over the effluent
lip of the frothing tank and into the froth-collection tray. A plastic spatula may
be used to sweep the froth off the top of the frothing tank and into the froth-
collection tray, especially if it tends to froth over the sides of the frothing tank.
Depending upon the amount of froth, the froth-collection tray may need to be
switched over time. Record the times for froth-collection-tray switches to obtain
time-based, separation information. Note any qualitative observations during the
separation with time including froth amounts, discernable presence of solids in
the froth, bubble-size distribution, bubble stability, etc.
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17.) When frothing ceases, shut off the aeration at the ball valve on the rotameter-
inlet line and record the time. Record any final qualitative observations.
18.) Separately wash out each froth-collection tray with distilled water into filter
paper (coffee filters work well) placed in a suitably fine sieve to prevent any
solids loss.
19.) Raise the agitator and rinse any remaining froth and solids back into the frothing
tank using distilled water. Remove the frothing tank.
20.) Separately wash out the frothing tank with distilled water into filter paper (coffee
filters work well) placed in a suitably fine sieve to prevent any solids loss.
21.) Remove the filter paper from the sieve, seal with tape, and label accordingly.
22.) Dry the samples in the filter paper in a drying oven at 75–100 oC. Record the
drying time and temperature.
23.) When dry, re-sieve each sample based upon the initial sieve-size distribution to
obtain separation of the solids. Alternatively, if one of the solids is magnetic,
use a magnetic plunger or magnetic separator to separate.
24.) Weigh each separated sample and calculate recovery and grade (purity) obtained
in the separation. Note any total sample loss.
25.) Empty the water bath at the end of the experimental period, and return all
samples, reagents, and equipment to their proper place.
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Suggested Separations
Fluid Phase
Water (do not use other liquids)
Frothing Agents
Dowfroth
MIBC
Others that you identify (have the technician or instructor order them if necessary)
Hydrophilic Particles
Each group has the responsibility of selecting a hydrophilic particle. Use the sieves to
characterize the size of the particles (dry).
Hydrophobic Particles
An excellent hydrophobic particle is extremely fine activated carbon. Use the mortar and
pestal to crush the activated carbon, and use the sieves to characterize the size of the
particles (dry).
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Suggested Separation Experiments for Copper and Ilmenite
Sodium oleate, C17H33COONa, which is soluble in water serves as both a collector and
frother in a number of metal and mineral separations. It can be used in the separation of
copper metal from gangue, such as sand, and ilmenite from zircon in water. Table 3 lists
the various sample and reagent materials available in the lab (Caution – note the
warnings at the bottom of this table). Sodium oleic acid is used as the reagent to prepare
the sodium oleate solution. Please note that this reagent is relatively expensive.
Maximum molar concentrations up to 3 x 10-4 M (which is ~0.1g of oleic acid for the 1.5
L tank) should be used for each run, but less if possible (1.5 x 10-4 M usually works
well). Copper metal is available in two presized samples (–150 mesh and –40,+60 mesh).
Presized sand is available (–50,+70 mesh), as well as common beach sand which may be
sieved. Ilmenite and zircon are available both as a mixture (~22% by weight ilmenite)
and as separate samples, all unsized. Other reagents listed in Table 3 are potential
A total solids loading of 50 g of material is suggested for the 1.5 L cell using sodium
Froth Flotation
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Table 3. Materials for Froth Flotation of Cu/Sand and Ilmenite/Zircon
The following are suggested froth-flotation experiments using sodium oleate solution
(maximum of 3 x 10-4 M) for copper and ilmenite separation from sand and zircon,
respectively.
(NaOH), lime (CaO), or soda ash (Na2CO3) may be used. Note that it will be
necessary to first dissolve these reagents in water on a hot plate at ~75 oC before
addition to the frothing tank. Operation in the acidic range may also be investigated
using hydrochloric (HCL) or sulfuric (H2SO4) acids. These pH modifiers may also
Froth Flotation
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• Investigate the effect of depressants that may inhibit any hydrophobicity of the
• Investigate the effect of particle size on the separation – both the desired component
• Investigate the effect of conditioning time for various modifiers on the separation.
= 2-5 and R = CH3, C4H9] such as poly (propylene glycol) monobutyl ether and
short time intervals – the kinetic effects of particle size; aeration; solids loading;
collector, frother, and modifier types and concentrations; and temperature may be
Froth Flotation
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Data Analysis
The following are outlines of the types of analyses that may be performed. The
application of these analyses will be determined from the types of experiments chosen.
m
stream) from G = des ⋅ 100 where mdes is the weight of the desired component
mconc
(usually the more valuable mineral) in the concentrate stream and mtot is the total
weight of the concentrate stream. The % increase in % grade between the original
weight fraction of the desired component and the weight fraction in the concentrate
m
(the hydrophobic stream) from R = des ⋅100 where mdes is the weight of the
mfeed
desired component in the concentrate stream and mfeed was the weight of the desired
component in the feed stream before separation. Percent loss of the desired
component via the tailings stream (the hydrophilic stream) may also be reported.
• Create plots of grade and recovery vs. agitator speed, pH, temperature, and
were determined in the experiments. Similarly, create grade vs. recovery plots for
comparisons.
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• Compare the results of other mineral processes – e.g., tabling, mineral jigging,
cycloning, and centrifuging – often used in lieu of, or in conjunction, with that of
froth flotation, specifically with respect to particle size, efficiencies, grade and
• Apply scale-up design procedures to froth flotation based upon the experimental
results.
Additional Analyses
The following are additional analyses that require more extensive data collection.
• Determine the rate constant, k, of the separation process for a given set of conditions
dC
expression, rs = − = kC n , assuming a pseudo-first-order process (n = 1) where
dt
C
frothing tank and t is time. Create a normalized plot of ln t vs. t where Ct is the
Co
constant, k. If the process is not first order, investigate other possible rate
expressions.
Froth Flotation
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1
the gas constant. Create a plot of ln k vs. 1 . Determine A and Ea and relate these
T
General References
Kirk-Othmer Encyclopedia of Chemical Technology 4th Ed., Vol. 11 (1997) pp. 81-106.
Kirk-Othmer Encyclopedia of Chemical Technology 4th Ed., Vol. 23 (1997) pp. 478-536.
McKetta, John J., Encyclopedia of Chemical Processing and Design, Vol. 23 (1985) pp.
454-506.
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