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CONCEPT MAP:
Sulphuric Acid
Contact process
Haber process
Glass
MANUFACTURED
Type Ceramics SUBSTANCES IN Ammonia
INDUSTRY
Composite Uses
Composition
Materials
Uses
Alloys Polymers
Type Of Alloys
Natural Synthetic
Polymers Polymers
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characteristics composition
Sulphuric Acids
c) Potassium Sulphate:
It is manufactured by the neutralisation of sulphuric acid and potassium hydroxide.
2KOH (aq) + H2SO4 (aq) K2SO4 (aq) + 2H2O (l)
4. Initially, sulphuric acid is produced by the reaction between sulphuric acid and
hydrocarbon compounds.
5. Sulphonic acid then reacts with sodium hydroxide to form sodium alkyl sulphonate which
is a detergent.
6. Accumulators need an electrolyte to carry charges ad to react with the positive need
negative plates during the charging and discharging processes.
7. In the acid accumulator, sulphuric acid acts as the electrolyte.
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Uses of
sulphuric Example
acid
Drying agent Concentrated sulphuric acid is generally used to dry gas in laboratory.
However it is not suitable to dry alkaline gases such as ammonia.
Oxidising Concentrated sulphuric Oxidises copper to form copper(II) sulphate.
agent 2H2SO4 (l) + CU(s) CuSO4(aq) +2H2O(l) + SO2(g) However dilute
sulphuric acid does not react with copper.
Dehydrating When concentrated sulpuric acid is added to sugar, a violent reaction
agent occurs.The water contain the sugar is extracted by the acid and the sugar
become carbon.
C6H12O6 (l) 6H2O(l) + 6C(s)
Strong acid It react with salt of the weak acid such as sodium ethanoate to form a weak
acid.
2CH3COONa(s) + H2SO4(l) 2CH3COOH(aq) + Na2SO4(aq)
1. Today sulphuric acid is made from sulphuric dioxide, by the contact process. There three
stages for the production of sulphuric acid by the contact process.
Stage 1:
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b) In the contact process, sulphur powder is sprayed inside a furnace at a temperature of
◦
100 C. Here sulphur is converted to sulphur dioxide.
c) Sulphhur dioxide can also be produced by heating metal sulphides such as zink sulphide
2ZnS(s) + 3O2(g) 2ZnO(s) + 2SO2(g)
Stage 2:
a) Sulphur dioxide and air are passed over a catalyst called vanadium(v) oxide, (V2O5).
◦
b) The temperature used here is about (450-500) C. If the temperature is less this range ,
the vanadium(V) oxide may not be able to catalyse.
c) The reacting pressure is about 2 to 3 atmosphere.
Stage 3:
1. Sulphur dioxide is present to some extent in the natural unpolluted atmosphere. The
sulphur dioxide sources are form:
a) Bacterial decay of organic matter.
b) Volcanic gases.
c) Forest fires
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However, their concentrations are low and they are normally considered as non polluting
2.
(a) Sulphur is found in coal and petroleum. When this fossil fuels burn they produce
sulphur dioxide.
(b) When this gas is release to the atmosphere, they pollute the air. In fact the burning of
coal and oil is the major source of sulphur dioxide pollution in our environment
(c) This gas considered as the most serious health hazard among the pollutant.
3. When SO2 desolving in water or rain , they form sulphurous acid H2SO3
4. Atmospheric SO2 can be oxidised to SO3 also. When SO3 dissolve in water it form
sulphuric acid H2SO4 .
SO3(g) + H2O(l) H2SO4(aq) both type of acid will cause acid rain.
5. Acid rain are affects marin and forest ecology. In an acidic environment less fish will
brred in polluted lake. More tress will die in the forest.
6. Sulphur dioxide is harmful to human health and property many of the environmental
effect are actually due to the reaction of sulphuric and sulphurous acid.
7. Acid react with metal and carbonates. Thus, acid is corresive both to metal and to
building material made of carbonates. For example, marble buildings and marble statures
will be corroded by acid rain. This will make them less beautiful.
8. The release of SO2 gas to the atmosphere can be reduce by reacting gas with :
a) Calcium carbonate
SO2(g) + CaCO3(s) CaSO3(s) + CO2(g)
b) Calcium oxide
CaCO(S) + SO2(g) CaSO3 (S)
9. Some gases release from industries also contain sulphur dioxide. These gases are mainly
produced from the burning of fossil fuel.They are also produced during the manufacture
of sulphuric acid.
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Reducing Acid Rain
1. The acidity in the soil can be reduced with the following chemicals.
a) Calcium oxide
CaO(s) + 2H+(aq) Ca2+(aq) + H2O(l)
b) Calcium hydroxide
Ca(OH)2(s) + 2H+(aq) Ca2+(aq) + 2H2O(l)
c) Calcium carbonate
CaCO3(s) + 2H+(aq) Ca2+(aq) + H2O(l) + CO2(g)
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Ammonia And Its Salts
Uses Of Ammonia
1. Most of the ammonia produced are used to produce nitrogen fertilisers and nitric acid.
2. Ammonia is used to produce nitric acid as shown in the following series of reaction.
4NH3(g) + 5O2(g) Platinum/rhodium 4NO(g) + 6H2O(g)
2NO(g) + O2(g) catalyst 850◦ 2NO2(g)
4NO2(g) + 2H2O(l) + O2(g) 4HNO3(aq)
3. Ammonia is an alkaline solution. It dissolves grease. Thus it used in the manufacture of
household cleaning agent.
4. Ammonia is important refrigerator in the refrigerator.
5. Ammonia is also used to make explosive chemicals such as TNT. This explosive is
produced when ammonia reacts with toluene.
6. In the industry ammonia is used to prevent coagulate in latex.
7. Ammonia is widely used in the manufacture of fertilizer.
Property Of Ammonia
Physical Property
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5. Its density is 0.68
Chemical Property
Decomposition Of Ammonia
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1. When the ammonia gas is passed over heated iron wool, some of the gas decomposes into
the elements nitrogen and hydrogen.
2NH3(g) N2(g) + 3H2(g)
2. This process actually is the reverse of Haber process.
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2. The % of nitrogen content can be calculated by using the following formula.
Mass of nitrogen
%
Molecular mass of fertiliser
Alloys
Meaning Of Alloy
1. Alloys are materials that contain more than one elements.
2. Usually alloys are mixtures of metallic elements
3. Pure aluminium is light but not strong enough to make aeroplane bodies. If a small
amount of manganese and magnesium are added then an alloy duralumin is formed. This
alloy is hard and strong for aeroplane frame.
4. Thus an alloy is mixture of metals made for a certain purpose.
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5. However, alloy are harder and stronger than the original constituent metals.
6. There are different ways of arranging the different atom alloys
a) Solution alloys are homogenous alloys in which the different atoms are distributed
uniformly throughout.
b) In heterogeneous alloys, the different atoms are not distributed uniformly.
7. Homogeneous alloys have definite properties and compositions.
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Synthetic Polymers
Meaning Of Polymers
1. most of the covalent molecules we have studied are small molecule.
2. However, some molecules are very big. They are called macromolecules.
3. Some macromolecules are formed when a large number of small molecules join together
to form a longer or bigger molecules. The small molecules are called monomers.
4. The big molecules formed are called polymers. Thus we define a polymers as the
following:
Polymers are large molecules made up of identical repeating sub-units of monomers
which are joined together by covalent bonds.
5. The process of forming polymers is called polymerization.
6. If the molecules simply join together then this type of polymerisation is called additional
polymerisation
7. There are two main group of polymers.
a) Man-made polymers or synthetic polymers
b) Natural polymers.
Natural Polymers
1. Rubber is an example of a natural polymer.
2. All these substances are large molecules made from smaller molecules that are joined
together. Thus, fat, carbohydrates and proteins are natural polymers.
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Natural Rubber Polymer
1. Natural rubber are natural polymer
2. Its monomer is called isoprene.
3. The joining of “n” molecules of isoprene will form the natural rubber polymer (C5H8)n.
The numerical values of “n” could be a few millions.
Fat Polymer
1. A molecules of fat is made by the combination of a glycerol molecule with carboxylic
acid molecules.
2. The carboxylic acid may be of the same type or different types. For example, two
molecules of stearic acid and one molecule of oleic acid have combined with one
molecule of glycerol to give one molecule of fat.
3. The glycerol part of the molecule form a bridge across the three carboxylic acid parts.
4. Other type of fat molecules may have structures with different carboxylic acid molecules.
Carbohydrate Polymers
1. Carbohydrate are polymers made up of small sugar molecules joined together.
2. Starch and cellulose are two types of carbohydrate polymers. In both cases the monomer
is glucose C6H12O6.
3. When the glucose monomer join together, they will form a polymer starch chain.
Protein Polymers
1. Protein polymer made up from monomer called amino acids.
2. They are many types of amino acids, but only twenty-four of them are found in nature.
3. These naturally occurring amino acids are used to make proteins.
4. The simplest amino acid is glycine H2N-CH2-COOH.
5. When the glycine and alanine join together they form a dipeptide protein.
Synthetic Polymer
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1. Synthetic polymer are widely use today.
2. Example of synthetic polymer are polythene, Perspex, polyvinyl chloride (PVC), and
nylon.
Synthetic Rubber
1. There are two main types of synthetic rubber:
a) SBR rubber or styrene-butadiene
b) Neoprene
2. SBR rubber or styrene-butadiene
a) This rubber is made by combining one part of styrene (IUPAC name: buta1,3-diena)
b) This type of polymerization is called copolymerization.
c) This polymer was developed during World War II and is used mainly to make tyres.
3. Neoprene
a) This rubber is made from monomer called chloroprene.
b) Its IUPAC name is 2-chloro-1,3-butadiena
c) The term diena means that this molecule contains two double bonds.
d) When these molecules polymerise they form the synthetic rubber polymer called
neoprene.
e) This type of polymerization is called additional polymerisation.
Importance Of Polymers
1. Polymer products play a very important part in our life. In fact, thousands of products we
use are made from polymer.
2. They are used in making household object such as toys,casing etc. Most textile materials
are mixture of synthetic fibres and natural fibres.
3. In fact, polymers have replaced many natural materials for several reasons.
a) They are relatively cheap
b) They are strong
c) They last for a long time
d) Easy to be moulded or shaped
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Environmental Pollution From Synthetic Polymers
1. Land pollution
a) The properties of polymers that make them useful causes problems. For example,
polymers are cheap. Thus, it often cheaper to throw away a polymer plate or cup then
to wash one to be used again.
Air Pollution
1. Burning plastics causes air pollution. When PVC is burnt, it gives off corrosive acidic
hydrogen chloride gas and poisonous chlorine gas. These two gases will produce acid
rain
2. Plastic material contain carbon. When they are burnt, poisonous gases such as carbon
monoxide are produced.
3. Some plastic materials contain carbon and nitrogen. When they are burnt, highly
poisonous gas such as hydrogen cyanide is given off to the air.
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a) If you look at the bottom of a plastic container , you are likely to see a recycle symbol
b) Recycling can create new product from disposed plastics. For example, bottles,
synthetic clothing and parts for new cars can be made from discarded plastics.
c) A pile of empty soda bottles can be turned into synthetic wood.
d) By recycling, we can help to minimize environmental pollution due to the disposal of
synthetic polymers.
2. Using biodegradable plastis
a) By mixing plastics with biodegradable materials, plastic can be decomposed like any
other organic rubbish.
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d) Unlike copper wire, glass does not corrode. Therefore, communication by using
optical fibres are also clear
Photochromic Glass
1. Photochromic glasses are glasses that darken in response to very bright light.
2. This type of glass of glass is made by adding tiny silver chloride crystals into molten
glass.
3. The silver chloride crystal are trapped in the glass structure, as the glass solidifies. Some
silver bromide and copper(II) chloride are added too.
4. Silver chloride and silver bromide have the property of darkening when light passes
through them. This happens when light dissociates the silver chloride or silver bromide
into silver.
2AgCl(s) 2Ag(s) + Cl2(g)
2AgBr(s) 2Ag(s) + Br2(g)
5. If the light intensity decreases then the silver chloride will restore back to original colour.
Conducting Glass
1. Glass is not a conductor of electric. However, it will conduct electricity if it is coated
with a film of conducting materials.
2. This conducting film can be made of indium stannum(IV) oxide
3. This type of glass is called ITO glass and is commonly used in LCD display panels.
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3. They are:
a) Hard
b) Brittle
c) Non reactive to chemicals
d) Good heat insulator
e) Good electric insulators
4. Glass is easy to clean
5. They are not porous.
6. The colour of glass can be changed by adding coloured oxides of metals. Additional of
a) Iron(II) oxides will colour the glass green
b) Copper(II) oxide and cobalt oxide will colour it blue.
c) Colloidal gold will colour it a red colour.
7. Crystals glass has a high refractive index. They are very suitable to make lenses and
prisms.
Ceramics
1. Ceramics are made from clays, such as kaolin. It contain silicates such as aluminium
silicates.
2. Ceramic are hardened by heating them at high temperature.
3. Like glass, the main component of ceramics are based on silicates.
4. Glass can be melted and remelted as often as it is desired. However, once a ceramic has
been hardened, it is resistant to extreme temperature.
Composition Of Ceramics
1. The main composition of kaolin is aluminosilicate (Al2O3.2SiO2.2H2O)
2. This compound contains aluminium, silicon and oxygen.
3. Silicone is added into kaolin to harden it during the process of making porcelain.
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a) Roofing tiles
b) Bricks
c) Sewer pipes
3. Ceramic are used as insulator in light fixtures and in electric equipment such as plugs
and lamp holders.
4. Ceramic tiles are the only materials that can withstand the temperature of over 1600○C.
thus they are used:
a) As heat insulating tiles to protect space shuttle.
b) To line the wall of furnace or oven.
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c) It contain the mixture of yttrium oxide, barium oxide and copper(II) oxide.
d) Ceramic superconductor can be used to make lighter but stronger magnets than
conventional magnets.
2. Engine block
a) Additional of magnesium oxide into ceramics can be used to make engine blocks that
can withstand very high temperatures.
b) In this type of engine, the fuel can burn at higher temperature. This increases the
efficiency of engines.
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a) Iron is a good material to use in construction industry. However iron rust easily.
b) Common plastics are long lasting. However, most of them melt or soften if heated.
2. New materials are needed today to supply the high demand for the new industries.
3. With the knowledge of science on materials, chemists are able to produce new composite
material for general and specific needs of technology development.
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Appreciating Synthetic Materials
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Justify The Importance Of Synthetic Materials In Daily Life
1. Society’s need increase from day to day. Our present needs are more complex as
compared to the old days. Thus, it is important for us to do research and development
continuously.
2. Research and development that are carried out can create new materials and products for
us to use.
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