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• Secondary Bonding
Three types of dipole-dipole bonds
Charges:
Electrons and protons have negative and positive charges
of the same magnitude, 1.6 × 10-19 Coulombs.
Neutrons are electrically neutral.
Masses:
Protons and Neutrons have the same mass, 1.67 × 10-27 kg.
Mass of an electron is much smaller, 9.11 × 10-31 kg and
can be neglected in calculation of atomic mass.
n = Nav × d / M
accept 2e-
accept 1e-
give up 3e-
H He
Li Be O F Ne
Na Mg S Cl Ar
K Ca Sc Se Br Kr
Rb Sr Y Te I Xe
Cs Ba Po At Rn
Fr Ra
Electropositive elements: Electronegative elements:
Readily give up electrons Readily acquire electrons
to become + ions. to become - ions.
0: Inert gases (He, Ne, Ar...) have filled subshells: chem. inactive
IA: Alkali metals (Li, Na, K…) have one electron in outermost
occupied s subshell - eager to give up electron – chem. active
VIIA: Halogens (F, Br, Cl...) missing one electron in outermost
occupied p shell - want to gain electron - chem. active
repulsion
Potential Energy, U
Interatomic distance r
0
attraction
equilibrium
0.005
Energy, eV, Force, eV/Å
Force F2
-0.005
Energy U
repulsion attraction
-0.01
2 4 6 8
Distance between atoms, rij, Å
r r
r r dU(r 12 ) F2 2 1 F1
F1 = − F2 = -
dr12 r r
r12 = r1 − r2
MSE 2090: Introduction to Materials Science Chapter 2, Bonding 14
The electron volt (eV) – energy unit convenient for
description of atomic bonding
Electron volt - the energy lost / gained by an electron
when it is taken through a potential difference of one
volt.
E=q×V
for q = 1.6 x 10-19 Coulombs and V = 1 volt
1 eV = 1.6 x 10-19 J
Types of Bonding
e-
Na Cl Na+ Cl-
Repulsive energy UR
Potential Energy, U
Interatomic distance r
Net energy U
U0
Attractive energy UA
ethylene molecule:
polyethylene molecule:
ethylene mer
diamond:
(each C atom has four
covalent bonds with four
other carbon atoms)
_ _
+ +
H H
-
+ +
Dipole