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Air is a gas. Gases have various properties that we can observe with our senses, including the gas
pressure, temperature (T), mass, and the volume (V) that contains the gas. Careful, scientific
observation has determined that these variables are related to one another and that the values of
these properties determine the state of the gas.
The relationship between temperature and volume, at a constant number of moles and pressure,
is called? ??
??in honor of the two French scientists who first
investigated this relationship. Charles did the original work, which was verified by Gay-Lussac.
They observed that if the pressure is held constant, the volume is equal to a constant times the
temperature
V = constant * T
In a scientific manner, we can fix any two of the four primary properties and study the nature of
the relationship between the other two by varying one and observing the variation of the other.
This slide shows a schematic "gas lab" in which we can illustrate the variation of the gas
properties. In the lab a theoretical gas is confined in a blue container. The volume of the gas is
shown in yellow and is determined by the position of a red piston. The volume can be changed
by moving the red piston using the red screw at the top of the piston. The number of moles of the
gas is indicated by the number of small black "molecules" in the volume. The number of moles
can be changed by injecting or withdrawing molecules using the pump at the left. There are two
probes inserted into the bottom of the container to measure the pressure and the temperature. The
pressure can be changed by adding or removing green weights from the top of the red piston, and
the temperature can be changed by heating the container with the "torch" at the bottom.
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In 1900 Max Planck made a profound discovery in modern physics / Quantum Theory. He
showed (from purely formal / mathematical foundations) that light must be emitted and absorbed
in discrete amounts if it was to correctly describe observed phenomena (i.e. ·lackbody
radiation).
Prior to then light had been considered as a continuous electromagnetic wave, thus the discrete
nature of light was completely unexpected, as Albert Einstein explains;
About fifteen years ago [1899] nobody had yet doubted that a
correct account of the electrical, optical, and thermal properties
of matter was possible on the basis of Galileo-Newtonian
mechanics applied to molecular motion and of Maxwell's theory
of the electromagnetic field. (/*?("", 1915)
In the year nineteen hundred, in the course of purely theoretical (mathematical) investigation,
Max Planck made a very remarkable discovery: the law of radiation of bodies as a function of
temperature could not be derived solely from the Laws of Maxwellian electrodynamics. To
arrive at results consistent with the relevant experiments, radiation of a given frequency f had to
be treated as though it consisted of energy atoms (photons) of the individual energy hf, where h
is Planck's universal constant. During the years following, it was shown that light was
everywhere produced and absorbed in such energy quanta. In particular, Niels ·ohr was able to
largely understand the structure of the atom, on the assumption that the atoms can only have
discrete energy values, and that the discontinuous transitions between them are connected with
the emission or absorption of energy quantum. This threw some light on the fact that in their
gaseous state elements and their compounds radiate and absorb only light of certain sharply
defined frequencies. (/*?("", on Quantum Theory,
1940)
We can now finally solve these problems by understanding the reason for these discrete energy
states, which are due to the fact that standing waves only exist at discrete frequencies, like notes
on the string of a guitar, thus while the correct Spherical Standing Wave Structure of Matter
predicts that energy exchanges will be discrete, as observed, the continuous e-m wave does not
anticipate this.
Thus the Spherical Standing Wave Structure of Matter explains Max Planck's (1900) discovery
that there are only certain allowed discrete energy states for electrons in molecules and atoms,
and further, that light is only ever emitted and absorbed by electrons in discrete or 'quantum'
amounts, as the electrons move from one stable standing wave pattern to another.
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Akibatnya, hanya masih ada satu kesimpulan, bahwa teori elektron sebelumnya
menderita dari ketidaklengkapan penting yang menuntut modifikasi, tapi seberapa dalam
modifikasi ini harus pergi ke dalam struktur teori adalah sebuah pertanyaan atas mana pandangan
masih sangat beragam. JJ Thompson condong ke tampilan yang paling radikal, seperti halnya J.
Larmor, A. Einstein, dan dengan dia I. Stark yang bahkan percaya bahwa propagasi gelombang
elektromagnetik dalam ruang hampa murni tidak terjadi tepat sesuai dengan persamaan medan
Maxwellian, tetapi dalam hv energi kuanta yang pasti. Saya berpendapat, di sisi lain, bahwa saat
ini tidak perlu untuk melanjutkan dalam begitu revolusioner rupa, dan yang satu mungkin datang
berhasil melalui dengan mencari makna dari hv kuanta energi hanya dalam aksi bersama dengan
yang resonator mempengaruhi satu sama lain. Sebuah keputusan yang pasti mengenai
pertanyaan-pertanyaan ini penting hanya bisa dibawa sebagai hasil dari pengalaman lebih. (Max
Planck, Columbia Kuliah tentang Teori Quantum)
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Sekitar lima belas tahun lalu [1899] ada yang belum meragukan bahwa account yang benar dari
sifat listrik, optik, dan termal materi dimungkinkan atas dasar mekanika Newtonian Galileo-
diterapkan pada gerakan molekul dan teori Maxwell tentang medan elektromagnetik. (Albert
Einstein, 1915)
Kemudian Planck menunjukkan bahwa untuk membangun hukum radiasi panas (Infra
gelombang cahaya merah) konsonan dengan pengalaman, hal itu perlu menggunakan metode
perhitungan yang ketidaksesuaian dengan prinsip-prinsip fisika klasik menjadi lebih jelas dan
lebih jelas. Untuk dengan metode ini perhitungan, Planck diperkenalkan ke dalam fisika kuantum
hipotesis, yang sejak menerima konfirmasi brilian. (Albert Einstein, pada Teori Quantum, 1914)
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