PART-A SINGLE CORRECT CHOICE TYPE Q.1 to Q.

7 has four choices (A), (B), (C), (D) out of which ONLY ONE is correct. 1. In a textile mill, a double - effect evaporator system concentrates a weak liquor containing 4% (by mass) caustic soda to produce a lye containing 25% solids (by mass). The mass of water evaporated per 100 kg feed in the evaporator is : 1) 16 kg 2) 75 kg 3) 84 kg 4) 79 kg 2. Assume that the atomic mass of oxygen is 7. A sample of 11 gm of an oxide of uranium contains 10 gm of uranium. Which of the following combination of formula of the oxide and the atomic mass of uranium is compatible with the data? 1) Uranium oxide is UO and the atomic mass of uranium is 70. 2) Uranium oxide is U3 O8 and the atomic mass of uranium is 240. 3) Uranium oxide is UO2 and the atomic mass of uranium is 105. 4) Uranium oxide is U2 O3 and the atomic mass of uranium is 105. 3. The gas which can not be absorbed in lime water is : 1) CO 2) CO2 3) Cl2 4) SO2 4. The minimum mass of water that is needed to slake 1.12 kg of quick lime, assuming no loss by evaporation, is 1) 760 gm 2) 1480 gm 3) 180 gm 4) 360 g 5. Pure FeS2 is burnt with 60% excess air (O2 = 20%, N2 = 80%, by volume). What is the percentage of N2, by volume, in the gaseous mixture, after the reaction ? Assume that the reaction occurs at constant pressure and temperature condition. The balanced chemical reaction is : 4FeS2 + 11O2 2Fe2 O3 + 8SO3 1) 84.62 2) 91.43 3) 89.8 4) 82.82 6. A gaseous alkane is exploded with oxygen. The volume of O2 needed for complete combustion and the volume of CO2 formed (measured at the same pressure and temperature) is in the ratio of 7 : 4. The molecular formula of

alkane is : 1) CH4 2) C3H8 3) C2H6 4) C4H10 7. 10 gm of acetic acid is dissolved in 100 gm of each of the following solvents. In which solvent, the molality of solution is maximum ? Assume no dissociation or association of acetic acid in the solvent. 1) water 2) enthanol 3) benzene 4) same in all solvents PART-B PARAGRAPH TYPE Q.8 to Q.10 has four choices (A), (B), (C), (D) out of which ONLY ONE is correct. Directions for question 8 to 10:Paragraph for next three questions Figure shows a scheme for concentrating dilute solution of NaOH.

8. How much water evaporated per hour? 1) 5000 kg 2) 500 kg 3) 19500 kg 4) 20000 kg 9. How much concentrated solution obtained per hour? 1) 5000 kg 2) 500 kg

3) 19500 kg 4) 20000 kg 10. How much slurry obtained per hour? 1) 5000 kg 2) 500 kg 3) 19500 kg 4) 20000 kg PART-C REASONING TYPE Q.11 to Q.13 has four choices (A), (B), (C), (D) out of which ONLY ONE is correct. 11. Statement-1 : A solution is homogeneous mixture of two or more pure substances. Statement-2 : The properties of solution are entirely different than the properties of its constituents. 1) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1. 2) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1. 3) Statement-1 is true, statement-2 is false. 4) Statement-1 is false, statement-2 is true. 12. Statement-1 : The mass ratio of reactants remain unchanged during the reaction, if they are taken in thier stoichiometric amounts. Statement-2 : The mass ratio of products formed (in case of more than one products) is always independent from the relative masses of reactants taken. 1) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1. 2) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1. 3) Statement-1 is true, statement-2 is false. 4) Statement-1 is false, statement-2 is true. 13. Statement-1 : The number of atoms in 2 gm hydrogen and 28 gm nitrogen is same. Statement-2 : The number of atoms in the gm-molecular mass of each substance is always same. 1) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1. 2) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1. 3) Statement-1 is true, statement-2 is false. 4) Statement-1 is false, statement-2 is true. PART-D MULTIPLE CORRECT CHOICE TYPE Q.14 to Q.16 has four choices (A), (B), (C), (D) out of which ONE OR MORE may be

correct. 14. Which of the following statement(s) is/are correct? 1) 1g-atom of each element contains the same number of atoms. 2) 1 mole atom of each substance contains the same number of molecules. 3) 1g-molecule of each covalent compound contains the same number of molecules. 4) 1g-formula unit of each ionic compound contains the same number of ions. 15. When hydrocarbons (alkanes, alkenes or alkynes) are burnt completely in excess of oxygen, then 1) for the same number of carbon atoms, more oxygen is consumed for alkanes. 2) for the same number of hydrogen atoms, more oxygen is consumed for alkynes. 3) for the same number of carbon atoms, more water is formed from alkynes. 4) for the same number of hydrogen atoms, more carbon dioxide is formed from alkynes. 16. If the ratio of mole-fractions of solute and solvent is unity, then the mass percent of solute is (molar masses of solute and solvent are X and Y, respectively) : 1) 50% 2) 3) mass percent of solvent 4) mass percent of solvent PART-E MATRIX TYPE Q.17 has three statements (A, B, C) given in Column-I and four statements (P, Q, R, S) given in Column-II. Any given statement in Column-I can have correct matching with one or more statement(s) given in Column-II. 17. Column I Column II A 2 moles of C6 H12 O6 P 12 moles of C-atoms B 6 moles of C2 H5 OH Q 24 moles of H-atoms C 3 moles of C3 H8 R 6 moles of O-atoms S 9 moles of C-atoms 1) A-P 2) A-Q 3) A-R 4) A-S 5) B-P 6) B-Q 7) B-R 8) B-S 9) C-P

10) C-Q 11) C-R 12) C-S Marks: 8 PART-F INTEGER TYPE Q.18 to Q.21 are "Integer Type" questions. (The answer to each of the questions are upto 4 digits) 18. A gaseous mixture contains 40% H2 and 60% He, by volume. The total number of g-molecules of gases present in 9.6 gm of such mixture is : 1) 0001 2) 0002 3) 0003 4) 0004 19. The mass (in gm) of 80% pure NaOH sample needed for complete reaction with 21.3 gm chlorine in hot condition is (unbalanced reaction : NaOH + Cl2 NaCl + NaClO3 + H2 O) 1) 0028 2) 0029 3) 0030 4) 0031 20. A gaseous mixture of C2 H6, C2H2 and CH4 contains 40% CH4, by volume. The volume of CO2 gas produced (in ml) by complete combustion of 200 ml of this mixture is (all the volumes are measured at the same pressure and temperature) 1) 0310 2) 0320 3) 0330 4) 0335 21. What volume (in ml) of 0.25 M-NaCl solution should be mixed with 40 ml of 0.25 M-MgCl2 solution to get a solution having chloride ion concentration equal to 0.3 M? (Assume volume to be additive) 1) 0160 2) 0161 3) 0162 4) 0163 PART-A SINGLE CORRECT CHOICE TYPE Q.22 to Q.28 has four choices (A), (B), (C), (D) out of which ONLY ONE is correct. 22. If x1 and x2 are the values of x satisfying the equation x2 4x + 1 = 0 where x1 > x2

lt

24

25

26


l t

i t t i

23

ti l

ti

t lt

3) 220 4) 221 27. The number of solutions of the equation equal to 1) 0 2) 1 3) 2 4) 3 28. is equal to 1) tan 25 2) cos 20 3) tan 10 4) sec 10 PART-B PARAGRAPH TYPE Q.29 to Q.31 has four choices (A), (B), (C), (D) out of which ONLY ONE is correct. Directions for question 29 to 31:Paragraph for next three questions A denotes the product xyz where x, y and z satisfy log3 x = log5 log7 log5 y = log7 log3 log7 z = log3 log5 B denotes the sum of square of solution of the equation log2 (log2 x6 3) log2 (log2 x4 5) = log 2 3 C denotes characterstic of logarithm log2 (log2 3) log2 (log4 3) + log2 (log4 5) log2 (log65) + log2 (log6 7) log2 (log8 7) 29. Find value of A + B + C 1) 18 2) 34 3) 32 4) 24 30. Find log2 A + log2 B + log2C 1) 5 2) 6 3) 7 4) 4 31. Find | A B + C | is

1) 30 2) 32 3) 28 4) 30 PART-C REASONING TYPE Q.32 to Q.34 has four choices (A), (B), (C), (D) out of which ONLY ONE is correct. 32. Statement-1 : Statement-2 : . .

1) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1. 2) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1. 3) Statement-1 is true, statement-2 is false. 4) Statement-1 is false, statement-2 is true. 33. Statement-1 : If where 'a' and ' ' are natural numbers, then minimum value of 'a' is 5. Statement-2 : The minimum value of 'a' occurs when ' ' takes the least natural number which is 2. 1) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1. 2) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1. 3) Statement-1 is true, statement-2 is false. 4) Statement-1 is false, statement-2 is true. tan x + 1 = 0,

34. Statement-1 : If angle A and B satisfy the equation tan2 x + then triangle ABC is right angled, where R.

Statement-2 : In triangle ABC, 1) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1. 2) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1. 3) Statement-1 is true, statement-2 is false. 4) Statement-1 is false, statement-2 is true. PART-D MULTIPLE CORRECT CHOICE TYPE Q.35 to Q.37 has four choices (A), (B), (C), (D) out of which ONE OR MORE may be correct.

35. 1) tan = 1 2) 3) tan = 1 4)

36. If N = (log2 125 + 1) (2 + log 4 625 ) (log2 25) (log4 (15625) + 4) then N is equal to 1) prime number 2) irrational number 3) rational number which is not natural number 4) natural number which is coprime with 5 37.

, then which of the following statements is/are true? 1) 3A + C = B 2) A + B + C = 0 3) A + C = B 4) B 2A = 4C PART-E MATRIX TYPE Q.38 has three/four statements (A, B, C/A, B, C, D) given in Column-I and four/five statements (P, Q, R, S/P, Q, R, S, T) given in Column-II. Any given statement in Column-I can have correct matching with one or more statement(s) given in Column-II. 38 Column I Column II . A P 4 If is coprime with If maximum and minimum value of 2 sin2 + 4 cos ( + ) sin B sin + cos 2 ( + ) is a & b respectively then (a + b) is less Q 3 than The number of values of x satisfying the equation C R 2 is equal to S 1 1) A-P 2) A-Q 3) A-R 4) A-S

5) B-P 6) B-Q 7) B-R 8) B-S 9) C-P 10) C-Q 11) C-R 12) C-S Marks: 8 PART-F INTEGER TYPE Q.39 to Q.42 are "Integer Type" questions. (The answer to each of the questions are upto 4 digits) 39. Find the number of integral solution of the equation . 1) 0001 2) 0002 3) 0003 4) 0004 40. If and P(tan ) = 2, P(tan ) = 2 , P(cot ) = 4, where , , are acute angles and sum of all possible distinct values of , and is given by where m & n are coprimes then find the value of (m + n). 1) 0008 2) 0007 3) 0009 4) 0005 41. Suppose that x, y R satisfying 7x2 9xy + 7y2 = 9. If a is the maximum value and b is the minimum value of x2 + y2 then find the number of digits in 210a + 23b ? 1) 0015 2) 0016 3) 0017 4) 0018 42. then find value of 'n'. 1) 0060 2) 0065

3) 0070 4) 0080 PART-A SINGLE CORRECT CHOICE TYPE Q.43 to Q.49 has four choices (A), (B), (C), (D) out of which ONLY ONE is correct. 43. Given that ln where p is pressure, z is distance, KB is Boltzmann constant and is temperature, the dimensions of are (useful formula Energy = K B temperature) 1) L0M0T0 2) L1M1T2 3) L2M0T0 4) L1M1T2 44. Rotational kinetic energy 'E' of a body is given by where is the angular velocity (radian/second) and I is the moment of inertia of the body. Dimensional formula of I on the basis of this equation is 1) [M0L2T1] 2) [M1L2T0] 3) [M2L2T0] 4) [M1L2T0] 45. A boat is moving in direction 4 + 3 with a speed of 10 m/s. Velocity vector of boat in unit vector rotation can be expressed as : 1) 40 + 30 2) 8 + 6 3) 4) 6 + 8 46. Given two vectors, Calculate the angle between 1) 60 2) 90 3) 30 4) 45 47. A particle is thrown with a speed of 12 m/s at an angle of 60 to the horizontal. After what time does its speed becomes 10 m/s 1) 1.2 sec 2) , given by

3) 4) 48. Two particles are at (5, 3) and (7, 3) moving with constant velocity 2 + 3 and x + y respectively. After 2sec. they collide. What are the values of x and y respectively? 1) 2, 2 2) 1, 3 3) 3, 2 4) 1, 1 49. A ball is thrown vertically upwards from a cliff. after which it strikes the ground below. Choose correct statement. 1) The speed at the time of hitting the ground is less than the initial speed. 2) The speed at the time of hitting the ground is greater than the initial speed. 3) The acceleration just before hitting the ground is more than the initial acceleration. 4) The acceleration just before hitting the ground is less than the initial acceleration. PART-B PARAGRAPH TYPE Q.50 to Q.52 has four choices (A), (B), (C), (D) out of which ONLY ONE is correct. Directions for question 50 to 52:Paragraph for next three questions Romeo lives at the foot of a hill and Juliet lives at the top of the hill which is shaped like a right circular cone of half angle 60 and slant length 180 m. Take horizontal direction as x-axis and vertically up as y-axis.

50. The position vector (in meters) Juliet is 1) 90 + 90 2) 90 + 90 3) 90 4) 180 + 90 + 180

51. On the valentine's day, Romeo throws a red rose at an angle of 30 to the

sloping hill so that Juliet can catch it. What should be the initial speed of the rose ? 1) 30 m/s 2) 30 m/s 3) 10 m/s 4) 60 m/s 52. The hill is smooth due to snowfall. If Juliet slips down, in what time will she reach Romeo ? 1) 6 sec 2) 6 sec 3) 3 sec 4) 3 sec PART-C REASONING TYPE Q.53 to Q.55 has four choices (A), (B), (C), (D) out of which ONLY ONE is correct. 53. Statement-1 : It is not possible to have a vector whose magnitude is dimensionless. Statement-2 : A vector quantity has magnitude and direction both. 1) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1. 2) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1. 3) Statement-1 is true, statement-2 is false. 4) Statement-1 is false, statement-2 is true. 54. Statement-1 : Two stones were projected simultaneously from same point with same speed at different angles from horizontal as shown. They may collide at the point of intersection of their paths.

Statement-2 : For two particles to collide they must be at the same point in space simultaneously. 1) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1. 2) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1. 3) Statement-1 is true, statement-2 is false. 4) Statement-1 is false, statement-2 is true.

55. Two cars A and B are moving on a straight line at t = 0, as shown in figure.

Statement-1 : Cars A and B meet each other two times. Statement-2 : A car crosses another if its velocity is greater than another and has the same position. 1) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1. 2) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1. 3) Statement-1 is true, statement-2 is false. 4) Statement-1 is false, statement-2 is true. PART-D MULTIPLE CORRECT CHOICE TYPE Q.56 to Q.58 has four choices (A), (B), (C), (D) out of which ONE OR MORE may be correct. 56. The vector + x + 3 is rotated through an angle and doubled in magnitude, then it becomes 4 + (4x 2) + 2 . The values of x are 1) 2/3 2) 1/3 3) 2/3 4) 2 57. The velocity v of a particle depends upon time t according to the equation 1) the dimension of C is [LT1] 2) the dimension of d is [T] 3) the dimension of C is [L] 4) the dimension of d is [T1] 58. Which of the following graph(s) may represent the uniformly retarded motion. 1)

2)

3)

4) None of the above PART-E MATRIX TYPE Q.59 has three/four statements (A, B, C/A, B, C, D) given in Column-I and four/five statements (P, Q, R, S/P, Q, R, S, T) given in Column-II. Any given statement in Column-I can have correct matching with one or more statement(s) given in Column-II. 59 The equation of motion of the particle is described in column-I. At t = 0, particle is at . origin. Time t is in seconds. Match the statement in column-I with that in column-II. Column-I Column-II A x = (3t2 + 2t) m P Velocity of particle at t = 1 sec in B V = 8t m/s Q Particle moves with uniform accel 2 C a = 16t m/s and particle starts from rest. R Particle moves with variable accel S Particle will not turn back. 1) A-P 2) A-Q 3) A-R 4) A-S 5) B-P 6) B-Q 7) B-R 8) B-S 9) C-P 10) C-Q 11) C-R 12) C-S Marks: 8 PART-F INTEGER TYPE Q.60 to Q.63 are "Integer Type" questions. (The answer to each of the questions are upto 4 digits)

60. A flag attached to a ship points south when the ship sails east at a speed of 18 km/hr. When the ship sails south at the same speed, the flag points east. Find the speed of the wind (in km/hr) with respect to the Earth's surface. 1) 0035 2) 0036 3) 0037 4) 0038 61. A bird is flying at a constant altitude of 129.6 m above the ground. A boy throws a bullet at an angle of 45, such that it hits the bird when it is at its maximum height. What is the initial velocity of the bullet (in m/s). 1) 0070 2) 0071 3) 0072 4) 0073 62. An object is dropped from a height of 20 m and 1 sec later an identical object is thrown vertically downward with initial speed v0 from same point. If they hit the ground at the same time what is v0 (in m/s) ? 1) 0015 2) 0016 3) 0017 4) 0018 63. In a given system of unit standared measurment of mass is 100 gm, standerd measurement of length is 200 cm and standard measurement of time is 5 sec. 10 J energy in the given system of unit has value N, then value of N is. 1) 0625 2) 626 3) 0627 4) 0624