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Inner
electron
shell
Proton
Nucleus
Neutron
Outer
electron
shell
Relative scale model of an atom and the
solar system
On this scale, the nearest star would be a little over 10,000 miles
away
Nuclear notation
• Z = atomic number or proton number, is the
number of protons in the nucleus.
• N = neutron number, is the number of neutrons
in the nucleus.
• A = Z + N = mass number, is the number of
nucleons in the nucleus.
A
• In general, the notation is Z X N
• Tools
– First-order ordinary differential equations
Enrico Fermi
(1901-1954)
-------------------------------
Nuclei spontaneously
disintegrate for proton numbers
larger than 83.
ln(λN)–ln(λNo)
-1
Activity
λNo -2 slope = -1
2
λNo -3
e
-4
-5
0 t 1/2 τ 2τ 3τ 4τ 5τ 0 t 1/2 τ 2τ 3τ 4τ 5τ
time time
91
Example: 238U -> 234Th + 4He
234
90 Th Mass-energy budget:
23
238U 238.0508 amu
8
144 145 146
23
# neutrons s
7
2
on 234Th –234.0436
36
le
2
uc 4He
35
n –4.00260
23
#
4
87
38 Sr
Example: 87Rb -> 87Sr + e– + ν
37 87
Rb Mass-energy budget:
49 50 87Rb 86.909186 amu
88
# neutrons s
on
87
l e 87Sr –86.908882
uc
86
n
# mass defect 0.0003 amu
= 0.0003 x 931 = 0.28 MeV
The emission of the electron is from the nucleus
The nucleus contains protons and neutrons
The process occurs when a neutron is
transformed into a proton and an electron
Energy must be conserved
19 K 40
the atomic number decreases by 1.
40
18 Ar
21 22
41
s
Examples: 40K -> 40Ar + e+ + ν
# neutrons
on
4
cl
39
nu
#
In positron emission, most energy is
liberated by remote matter-antimatter
annihilation. In electron capture, a gamma
ray carries off the excess energy.
0.01
You can see why some of the isotopes people
worry about in nuclear fallout are 91Sr and 137Cs.
( )
Q = ( ∆m ) c 2 = m7 Li + m 4 He − m10 B − mn c 2 = −2.79MeV
Processes of Nuclear Energy
• Fission
– A nucleus of large mass number splits into
two smaller nuclei
• Fusion
– Two light nuclei fuse to form a heavier
nucleus
• Large amounts of energy are released in
either case
Nuclear Fission
• A heavy nucleus splits into two smaller nuclei
• The total mass of the products is less than the original
mass of the heavy nucleus
• First observed in 1939 by Otto Hahn and Fritz
Strassman following basic studies by Fermi
• Lisa Meitner and Otto Frisch soon explained what had
happened
• Fission of 235U by a slow (low energy) neutron
1
0 n+ 235
92 U→ 236
92 U* → X + Y + neutrons
–If uncontrolled, a
violent explosion can
occur
–The principle behind
the nuclear bomb, where
1 g of U can release
energy equal to about
20000 tons of TNT
Carbon dating is a variety of radioactive
dating which is applicable only to matter
which was once living and presumed to be in
equilibrium with the atmosphere, taking in
carbon dioxide from the air for photosynthesis.
Cosmic ray protons blast nuclei in the upper
atmosphere, producing neutrons which in turn
bombard nitrogen, the major constituent of
the atmosphere . This neutron bombardment
produces the radioactive isotope carbon-
carbon-14.
The radioactive carbon-
carbon-14 combines with
oxygen to form carbon dioxide and is
incorporated into the cycle of living things.
The carbon-
carbon-14 forms at a rate which appears to be constant, so that by
measuring the radioactive emissions from once-once-living matter and
comparing its activity with the equilibrium level of living things, a
measurement of the time elapsed can be made
made..
Radioactive Dating
Radioactive half
half--life of a given radioisotope is not affected
by temperature, physical or chemical state, or any other
influence of the environment outside the nucleus
nucleus..
E = 0.0046 x 931
= 4.3 MeV
-----------------------
Which particle
has the greater
kinetic energy?
Energy Distribution in Radioactive Decay
Conservation of
momentum:
Mv = mV (2)
Rearranging, we get
Ratio of kinetic energies: V/v = M/m (3)
KEm / KEM: (1/2 mV2) / (1/2 Mv2) Substitute (3) into (1):
A German tourist in
the Italian Alps
discovered the
remains of the
"Iceman" in the ice
of a glacier in 1991
Calculating the Iceman's Age
Phosphorus-30 does not occur in nature and is radioactive. This was the first artificial radioactive substance ever
prepared. Aside from the three natural types of radioactivity (α,β,γ), artificially made nuclei can undergo:
Both positron emission and electron capture tend to occur for radioactive isotopes that need to convert a proton into
a neutron. The Curie-Joliots were awarded the Nobel Prize in Chemistry in 1935 for discovering artificial
radioactivity.
Chemical Reaction Nuclear reaction
Atoms are rearranged by Elements (or isotopes of
the breaking and formation the same elements) are
of chemical bonds converted from one to
another
Only electrons in atomic Protons, neutrons,
orbitals are involved in the electrons and other
breaking and forming of elementary particles may
bonds be involved
Absorption or release of Absorption or release of
small amounts of energy tremendous amounts of
energy
Rates of reactions are Rates of reactions are NOT
affected by temperature, affected by temperature,
pressure, concentration pressure, concentration
and catalysts and catalysts
Producing Radioactive Isotopes:
238 234 4
92 U −− > 90 Th + He 2
n+ 14 N → 1 4C + p
7 6
4H e+ 14 N → 1 7O + 11 H
2 7 8
Every day, we ingest/inhale nuclides in our air we breath, in the food we eat
and the water we drink. Radioactivity is common in the rocks and soil that
makes up our planet, in the water and oceans, and even in our building
materials and homes. It is just everywhere. There is no where on Earth that you
can get away from Natural Radioactivity.
Radioactive elements are often called radioactive isotopes or radionuclides.
There are over 1,500 different radioactive nuclides
Natural Radioactivity in Food