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XI I

CHEMI STRY
SAMPLE PAPER 4
Ti me: Thr ee Hour s Max . Mar k s: 70
Gener al I nst r uct i ons
1. All quest ions are compulsory.
2. Quest ion nos. 1 t o 8 are very short answer quest ions and carry 1 mark
each.
3. Quest ion nos. 9 t o 18 are short answer quest ions and carry 2 marks each.
4. Quest ion nos. 19 t o 27 are also short answer quest ions and carry 3 marks
each.
5. Quest ion nos. 28 t o 30 are long answer quest ions and carry 5 marks each
6. Use log t ables if necessary, use of calculat ors is not allowed.
1. Colloidal part icles show a zig - zag mot ion. What is t he name given t o
t his mot ion? ( 1)
2. Give I UPAC name of
a)
b)
( 1)
3. Give t he I UPAC name of [ Co ( NH
3
)
6
] Cl
3
( 1)
4. 2, 4, 6 Trinit rophenol is soluble in aqueous Na
2
CO
3
while phenol is not .
Why? ( 1)
5. What are elast omers? How are t hey different from fibres? ( 1)
6. To which class of ant imicrobials do t he following belong: Chloroxylenol,
Phenol , ) 0.2% ( 1)
7. Aliphat ic amines have a lower
b
pK value t han
3
NH . Why? ( 1)
8. What are anomers? Give an example. ( 1)
9. Account for t he following.
a) Si doped wit h P act s as a semi conduct or.
b) Glass obj ect s over a period of t ime st art appearing milky. ( 2)
10. St at e Henrys law. Give any one of it s applicat ion. ( 2)
11. Give reasons:
( a) Zn has lowest ent halpy of at omizat ion amongst first t ransit ion
series.
( b) Transit ion element s form coloured compounds. ( 2)
OR
Give reasons:
a) Transit ion element s exhibit variable oxidat ion st at es.
b) Cu
+
is not st able in aqueous solut ion. ( 2)
12. Calculat e t he emf of t he following cell at 298K :
2
2
F e ( s ) l F e ( 0 . 0 0 1 M ) l l H ( 1 M ) l H ( 1 a t m ) l P t ( s )
- -
2
F e lF e
E 0.44 V
-
u
= ( 2)
13. [ Co( NH
3
)
6
]
3+
is diamagnet ic while [ CoF
6
]
3-
is paramagnet ic. Why?
( At omic Number of Co = 27) ( 2)
14. Name t he cryst al syst em of t he compound wit h unit cell dimensions
o= |= 90, = 120 and a= 0. 387, b = 0.387 and c = 0.504 nm.
Give an example of a compound in which t his t ype of cryst al syst em is
present . ( 2)
15. Which of t he following undergoes S
N
1 fast er and why?
( a)
( b)
( 2)
16. Give t he names and st ruct ures of monomers of:
a) Dacron b) Buna N ( 2)
17. What is saccharin? What is t he purpose of using it ? ( 2)
18. a) Name t he react ion represent ed by following equat ions?
( i)
( ii)
b) Which of t hese has a higher boiling point and why? ( 2)
I odobenzene or Chlorobenzene.
19. Calculat e t he degree of dissociat ion of a decimolar solut ion of NaCl wit h
osmot ic pressure of 4. 6 at m at 300K. ( 3)
20. a) Corrosion is an elect rochemical process.
b) Give equat ion involved in recharging a lead st orage bat t ery. ( 3)
21. What happens when:
a) A freshly prepared
, )
3
F e OH is shaken wit h a lit t le amount of dilut e
solut ion of FeCl
3
.
b) Light is passed t hrough a colloidal solut ion.
c) Elect ric current is passed t hrough a colloid.
, ) 1 3 3 =
22. a) An alloy A finds applicat ion in making bullet s, shells et c. Name t he
alloy and give it s composit ion.
b) Which of t he t wo is more basic: La( OH)
3
or Lu( OH)
3
, and why?
c) Why does Zr ( Z= 40) and Hf ( Z = 72) have similar at omic radii?
, ) 1 3 3 =
23. Account for t he following:
a) Alcohols act as weak acids.
b) Phenols have smaller dipole moment t han alcohols
c) How can et hers be dist inguished from alcohol s? Give t he equat ion
involved.
, ) 1 3 3 =
24. Complet e t he following equat ions:
( a)
5
Sn PCl -
( b)
3 2 3 2
AgNO H O H PO - -
( c)
2
M nO HCl -
, ) 1 3 3 =
25. Writ e short not es on:
a. Gabriel pht halimide synt hesis
b. Hoffmann bromamide degradat ion met hod
( 3)
26. a) What happens wit h D - Glucose is made t o react wit h
2
Br wat er. Give
equat ion also
b) Why are carbohydrat es generally opt ically act ive?
c) Why cant vit amin C be st ored in t he body?
, ) 1 3 3 =
OR
a) St ruct urally different iat e bet ween insulin and myosin.
b) Two st rands of DNA are complement ary t o each ot her. Account for it ?
c) Why is sucrose known as invert sugar?
, ) 1 3 3 =
27. Account for t he following:
a) Zn is not ext ract ed from ZnO t hrough reduct ion using CO.
b) Copper mat t e is put in silica lined convert er
c) Graphit e is used in elect romet allurgy of Al. , ) 1 3 3 =
28. ( a) Convert :
( i) Et hanal t o Crot onaldehyde
( ii) Propanoic acid t o Lact ic acid
( b) Draw st ruct ure of met hyl hemiacet al of formaldehyde.
( c) How do carbonyl compounds react wit h sodium hydrogen sulphit e.
Explain giving react ion. ( 5)
OR
Complet e t he equat ions:
( a)
( b)
( c)
( d)
( e)
( 5)
29. Explain:
a) Perchloric acid is a st ronger acid t han sulphuric acid.
b) Noble gases are bigger in size t han halogens of respect ive per iod.
c) Solid PCl
5
exhibit s some ionic charact er.
d) Oxygen has lower elect ron gain ent halpy t han S.
e) Gaseous N
2
is used in food packaging. ( 5)
OR
a) What is aqua regia? Where is it used?
b) Draw t he shape of XeO
3
. What is t he hybridizat ion of Xe in XeO
3
?
c) Can PCl
5
act as bot h oxidizing and reducing agent ? Give reason t o
support your answer.
30.
a) The decomposit ion of
, ) , ) , )
2 5 2 5 2 2
N O , 2N O g 4NO g O g -

is a
first order react ion. Aft er 30 min from st art of decomposit ion in closed
vessel, t ot al pressure developed is found t o be 284. 5 mm Hg. And on
complet e decomposit ion, t ot al pressure is 584.5 mm Hg. Calculat e rat e
const ant of t he react ion.
b) Rat e of a part icular react ion quadruples when t emperat ure changes
from 293 K t o 313 K. Calculat e act ivat ion energy for t he react ion. ( 5)
OR
a)
90
Sr has half life of 28. 1 years. I f 1 g of
90
Sr was absorbed in bones
of a new born baby, how much of it will remain aft er 20 years, if not lost
met abolically?
b) For a react ion,
2
2A B A B, - rat e const ant is mol
1 1
0.5 Ls

Rat e Law is Rat e = k[ A]
2
, Calculat e t he rat e when :
( i) mol mol
1 1
A 0.60 L , [B] 0.05 L

= = (

( ii) Concent rat ion of A and B are reduced t o
1
4
. ( 5)
SOLUTI ONS TO SAMPLE PAPER- 4
1. Brownian movement ( 1)
2. ( a) Et hyl 4 chlorobenzoat e (
1
2
)
( b) 3- Chloropropanoic acid (
1
2
)
3. Hexaamminecobalt ( I I I ) chloride
( 1)
4. 2, 4, 6- Trinit rophenol is more acidic t han phenol because of elect ron
wit hdrawing or I effect of t hree
2
NO
groups. Thus, it gives a salt wit h
Na
2
CO
3
which is a weak base. So, t his makes 2, 4, 6- t rinit rophenol
soluble in aqueous Na
2
CO
3
.
( 1)
5. Elast omers are t he polymers in which polymer chains are held t oget her
by weak int ermolecular forces & hence are st ret chable. F ibres are t he
polymers wit h st rong int ermolecular forces like hydrogen bonding &
hence possess high t ensile st rengt h.
( 1)
6. Chloroxylenol Ant isept ic
1
( )
2
Phenol ( 0. 2%) Ant isept ic
1
( )
2
7. Due t o + I effect of alkyl groups, aliphat ic amines are st ronger bases
t han NH
3
. So, aliphat ic amines have a higher K
b
value and hence a lower
pk
b
value t han ammonia. ( 1)
8. Anomers are t he carbohydrat es which differ in configurat ion at t he
glycosidic carbon ( i. e. C
1
in aldoses and C
2
in ket oses) . Example: o- D-
glucose and |- D- glucose. ( 1)
9. ( a) P is a pent avalent element . When Si is doped wit h P, it occupies
some of posit ions of Si. Since it can form 4 covalent bonds wit h ot her Si
at oms, t he 5
t h
elect ron being not involved in bonding can delocalize.
This increases t he conduct ivit y of doped Si. ( 1)
( b) Glass is an amorphous solid. Over a period of t ime, it st art s get t ing
cryst alline and t herefore appears milky. ( 1)
10. Henrys Law st at es t hat solubilit y of a gas in a liquid at a given
t emperat ure is direct ly proport ional t o t he pressure of a gas. I f we use
mole fract ion of a gas in t he solut ion as a measure of it s solubilit y, t hen
it can be said t hat t he mole fract ion of a gas in t he solut ion is
proport ional t o t he part ial pressure of gas over t he solut ion.
p = K
H
. x ( 1)
Applicat ion: Soft drinks cont ain dissolved carbon dioxide. I n t he
preparat ion of t hese beverages, carbon dioxide is passed at high
pressure t o increase it s solubilit y. ( 1)
11. ( a) Out ermost conf igurat ion of is
10 2
Zn 3d 4s . Since all elect rons in Zn
are paired, met allic bond is weak, t hus ent halpy of at omizat ion is
lowest . ( 1)
b) Compounds of t ransit ion element s are coloured because t hey have
unpaired elect rons which on absorpt ion of light undergo d - d t ransit ions
and emit light in t he visible region. ( 1)
OR
a) The variable oxidat ion st at es of t ransit ion element s are due t o t he
part icipat ion of bot h ns and
, )
n 1 d elect rons in bonding. ( 1)
b) Due t o low charge densit y, Cu
+
has low ent halpy of hydrat ion. Cu
+
in
aqueous solut ion undergoes disproport ionat ion.
2 Cu
+
( aq) Cu
2+
( aq) + Cu ( s)
The E

value for t his is posit ive and react ion becomes favourable.
( 1)
12. F e + 2H
+
Fe
2+
+ H
2
2
2
0.059 [F e ]
E E log
n [H ]
-
u
-
=
1
( )
2
cat hode anode
E E E
0 ( 0.44V)
1
0.44 V ( )
2
u u u
=
=
=
u
=
=
0.059 0.001 1
E E log ( )
2 1 2
1
0.5285 V ( )
2
13. At omic number of Co = 27
Elect ronic configurat ion of Co = [ Ar] 3d
7
4s
2
Elect ronic configurat ion of Co
3+
= [ Ar] 3d
6
3
NH being a st rong field ligand causes pairing up of elect rons. Hence,
no free elect ron is available. Thus [ Co ( NH
3
)
6
]
3+
is diamagnet ic. ( 1)
F
-
being a weak field ligand cannot cause pairing of elect rons. Thus,
unpaired elect rons are available in [ CoF
6
]
3-
and t herefore it is
paramagnet ic. ( 1)
14. Hexagonal ( 1)
Example: Graphit e ( 1)
15. The compound ( a) react s fast er t han compound ( b) . ( 1)
This is due t o format ion of a more st able
, )
o
3 carbocat ion in compound
( a) in t he rat e det ermining st ep t han
, )
o
2 carbocat ion in compound ( b) .
( 1)
16. ( a) M onomers of Dacron:
Et hylene glycol , )
2 2
HOCH CH OH and Terepht halic acid
( 1)
( b) M onomers of Buna N:
1, 3 But adiene , )
2 2
CH CH CH CH = = and acrylonit rile
, )
2
CH CH CN = ( 1)
17. Saccharin is an art ificial sweet ener. ( 1)
I t adds sweet ness t o t he food wit hout adding calories. I t is useful for
diabet ic pat ient s who need t o cont rol t heir caloric int ake. ( 1)
18. ( a) ( i) Dows process ( 1/ 2)
( ii) F inkelst ein react ion ( 1/ 2)
b) I odobenzene has a higher boiling point t han chlorobenzene. (
1
2
)
Due t o larger size of t he halogen iodine, van der Waals forces are
st ronger in iodobenzene t han chlorobenzene. This making t he boiling
point of iodobenzene higher t han chlorobenzene. (
1
2
)
19. ( a) 4.6 at m n 2 t = =
T = 300 K
c = 0.1 M
i 1.87 = (
1
2
)
-
-
o o o
o - o - o
=
- o
= = - o
= - o
o =
=
NaCl Na Cl
I nit ial 1 0 0
Aft er
dissociat ion 1
1
i (1 / 2)
1
1
1
1
1.87 1
1.87 1
0.87 (1)
20.
(a) At a part icular spot of an obj ect made of iron, oxidat ion t akes place.
Elect rons released at anodic spot move t hrough t he met al and go t o anot her
spot on t he met al and reduce oxygen in presence of H
+
( which is believed t o
be available from H
2
CO
3
formed due t o dissolut ion of carbon dioxide from air
int o wat er. Hydrogen ion in wat er may also be available due t o dissolut ion of
ot her acidic oxides from t he at mosphere) . This spot behaves as cat hode. (1)
At anode: F e( s) Fe
2+
( aq) + 2e
-
(
1
2
)
At cat hode:
1
2
O
2
( g) + 2H
+
( aq) + 2e
-
H
2
O ( l) (
1
2
)
( b)
4 2 2 2 4
2PbSO ( s) 2H O(l) Pb( s) PbO ( s) 2H SO ( aq) - - - ( 1)
21. ( a) I t causes pept izat ion leading t o t he format ion of reddish brown
colloidal solut ion of Fe( OH)
3
. ( 1)
( b) Scat t ering of light by colloidal part icles t akes place and t he pat h of
light becomes illuminat ed. This is called Tyndall effect . ( 1)
( c) Under t he influence of current , t he collodial part icles st art moving
t owards t he opposit ely charged elect rode. This is called
elect rophoresis. ( 1)
22. ( a) M isch M et all (
1
2
)
Composit ion: 95% Lant hanoid met al, 5% Fe and t races of
(
1
2
)
( b)
, )
3
La OH is more basic t han
, )
3
Lu OH . (
1
2
)
Due t o lant hanoid cont ract ion, La is bigger in size t han Lu. Larger t he M -
OH bond weaker is t he M - OH bond. This makes La( OH)
3
more basic.
(
1
2
)
( c) This is due t o Lant hanoid cont ract ion because of poor screening
effect of f elect rons. As a consequence of t his, element s of t he second &
t hird t ransit ion series have similar size. Therefore Zr and Hf have similar
at omic radii. ( 1)
23.
( a) The acidic charact er of alcohols is due t o t he polar nat ure of OH bond.
An elect ron- releasing group increases elect ron densit y on oxygen t ending t o
decrease t he polarit y of O- H bond. This decreases t he acid st rengt h. Hence
alcohols act as weak acids. ( 1)
( b) Due t o elect ron wit hdrawing induct ive effect of phenyl group, t he C- O
bond in phenol is less polar, whereas, due t o elect ron releasing induct ive
effect of alkyl group t he C- O bond in alcohols is more polar. Hence, phenol
has a smaller dipole moment t han alcohols. ( 1)
( c) Alcohols react wit h sodium met al leading t o evolut ion of
2
H gas while
et hers do not react wit h sodium met al.
, ) No reaction
- -
-
2 5 2 5 2
2 5
2
1
C H OH Na C H ONa H
2
C H O Na
( 1)
24.
( a) Sn + 2PCl
5
SnCl
4
+ 2 PCl
3
( 1)
( c) M nO
2
+ 4 HCl M nCl
2
+ Cl
2
+ 2 H
2
O ( 1)
25. a. Gabriel pht halimide synt hesis: Gabriel synt hesis is used for t he
preparat ion of primary amines. Pht halimide on t reat ment wit h et hanolic
pot assium hydroxide forms pot assium salt of pht halimide which on heat ing
wit h alkyl halide followed by alkaline hydrolysis produces t he corresponding
primary amine. ( 1/ 2)
( 1)
b. Hoffmann bromamide degradat ion met hod: Hoffmann developed a met hod
for preparat ion of primary amines by t reat ing an amide wit h bromine in an
aqueous or et hanolic solut ion of sodium hydroxide. ( 1/ 2)
( 1)
26. a) When D glucose is made t o react wit h
2
Br wat er, gluconic acid is
formed. (
1
2
)
(
1
2
)
b) Carbohydrat es generally opt ically act ive because t hey have one or
more chiral carbon at oms.
( 1)
c) Vit amin C is wat er soluble. I t is excret ed along wit h urine, hence
cant be st ored in t he body.
( 1)
OR
( a) I nsulin: I t is a globular prot ein in which polypept ide chains fold & coil
t o give spherical shape.
M yosin: I t is a fibrous prot ein in which polypept ide chains run parallel,
held by H bonds or disulphide bonds. ( 1)
( b) I n DNA, adenine pairs wit h t hymine and cyt osine pairs wit h guanine.
The sequence of bases in one base aut omat ically det ermines t hat of t he
ot her. Thus t he t wo st rands are complement ary. ( 1)
( c) Sucrose is dext ro rot at ory. But on hydrolysis, it gives fruct ose
( o = - 92.4

) and glucose
, )
o
52.5 = - .Hence t he result ing solut ion is
laevorot at ory. Thus due t o t he inversion of configurat ion, it is called
invert sugar. ( 1)
27. ( a) This reduct ion react ion is feasible only at a high t emperat ure, t hus it
is not economically & pract ically viable. ( 1)
( b) This is done t o remove basic impurit ies by format ion of slag.
Example:
2 3
FeO Si O Fe Si O - ( 1)
( Slag)
c) I n elect romet allurgy of Al, graphit e rods act as anode and get burnt
away as CO and CO
2
during t he process of elect rolysis. ( 1)
28.
( 1)
( 1)
( 1)
c) Carbonyl compounds react wit h
3
NaHSO t o give a cryst alline
bisulphit e addit ion product which on hydrolysis wit h dilut e acid gives
original carbonyl compound. ( 1)
( 1)
OR
( a)
( 1)
( 1)
( 1)
( 1)
( 1)
29. ( a) HClO
4
is a st ronger acid t han
2 4
H SO due t o higher elect ronegat ivit y
of Cl t han S making t he O- H bond in HClO
4
more polar. ( 1)
( b) Noble gases cont ain fully filled p - subshell. This leads t o
int erelect ronic repulsions leading t o an increase in size. Therefore, noble
gases are bigger in size t han t he corresponding halogens. ( 1)
( c) I n solid st at e, PCl
5
exist s as [ PCl
4
]
+
[ PCl
6
]
-
t hus exhibit ing ionic
Charact er. ( 1)
( d) Due t o very small size of O, addit ion of elect ron leads t o
int erelect ronic repulsions, hence lowering t he value of elect ron gain
ent halpy. ( 1)
( e) Due t o N N t riple bond, N
2
is chemically inert . F lushing packaged
foods wit h high purit y nit rogen ret ards oxidat ive det eriorat ion by
t ypically reducing t he oxygen level in packaged foods hence it is used in
food packaging. ( 1)
OR
a) Aqua regia is t hree part s of conc. HCl & one part of conc.
3
. HNO This
is used t o dissolve noble met als. ( 1)
1
( )
2
b)
( 1)
Hybridizat ion is sp
3
1
( )
2
c) No, PCl
5
cant act as bot h oxidizing & reducing agent . ( 1)
Oxidat ion st at e of P in PCl
5
is + 5, which is maximum for P.
5
P
-
can only
reduce it self hence serving as an oxidizing agent ( 1)
30.
2 moles of gaseous
2 5
N O on complet e decomposit ion gives 5 moles of
gaseous product ( 4 moles of NO
2
and 1 mole of
2
O ) .
I nit ial pressure of N
2
O
5
, p
0
= 584.5
2
5
= 233.8 mm Hg ( 1)
Let t he pressure of N
2
O
5
decrease by x at m
So, aft er 30 minut es, Pressure due t o N
2
O
5
= 233.8 - x
Pressure due t o NO
2
= 2x
Pressure due t o
2
2 O x =
Tot al pressure aft er 30 min = 284. 5 mm Hg
( 1)
Pressure of
2 5
N O aft er 30 min = 233. 8 - 33. 8
= 200 mm Hg
For a 1
st
order react ion,
3 1
5.2 10 min .

= ( 1)
( b)
(
1
2
)
k
2
= 4k
1
( 1)
E
a
= 52.85 kJ/ mol (
1
2
)
OR
( a) For a 1
st
order react ion,
1
1
2
0.693 0.693
0.0247 years
28.1

= = = k
t
( 1)
Aft er 20 years,
2.303
=
o
N
t log
k N
(
1
2
)
- 6
2 . 3 0 3 1 0
2 0 = l o g
0 . 0 2 4 7 N
( 1)
7
6.1 10

= N g (
1
2
)
b) Rat e
j
2
k A =
( i) Rat e
j
2
0.6 k =
0.5 0.6 0.6
0.18
=
=
( 1)
( ii) Since rat e depends only on concent rat ion of A and is independent of B
Therefore, if t he concent rat ion of A is reduced t o one- fourt h, it becomes
0.6
4
And now t he rat e becomes:
Rat e
2
0.6
0.5
4
| |
=
|
\ .
0.5 0.6 0.6
0.011
4 4

= =

( 1)

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