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SULIT 454113 MOZ@C

454113
Kimia
Kertas3
Sept.
2008

No. Kad Pengenalan: .. Angka Giliran: .

..... /

Nama: Tingkatan: ..

PERSIDANGAN KEBANGSAAN PENGETUA-PENGETUA

SEKOLAH MENENGAH
NEGERI KEDAH DARUL AMAN

PEPERIKSAAN PERCUBAAN SPM 2008

CHEMISTRY

Paper 3

One hour and thirty minutes

JANGAN BUKA KERTAS SOALAN INI SEHINGGA DffiERITAHU

1. Kertas soalan ini adalah da/am
dwibahasa.

2. Soalan dalam Bahasa Inggeris Untuk Keguriaan Pemeriksa

meildahuIui soalan yang sepadan
da/am Bahasa Me/ayu. Markah Markah'
Soalan
penuh diperoleh
3. Calon dibenarkan menjawab
leese/uruhan atau sebahagiansoalan 1 33
sama ada da/am Bahasa Inggeris atau
Bahasa Me/ayu. 2 17

4. Calon dileehendald membaca JUMLAH

maklumatdi halaman belakangkertas
soa/an ini.

Kertas soalan ini mengandungi 10 halaman bercetak

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INFORMATION FOR CANDIDATES

1. This question paper consists oftwo questions. Answer all the questions.

2. Write your answers for Question J and Question 2 in the spaces provided in the
question paper.

3. You may use equations, diagrams, tables, graphs and other suitalJle methods to
. explain your answer.

4. If you wish to cancel any answer, neatly cross out the answer. Then write down
the new answer.

5. Show your working. It may help you to get marks.

6. The diagrams in the questions are not drawn to scale unless stated

7. Marks allocatedfor each question or part ofthe question are shown in brackets.

8. The time suggested for answering Question 1 is 45 minutes and Question 2 is 45

minutes.

9. You may use a non-programmable scientific calculator.

10. Hand in all your answer sheets at the end ofthe examination.

Marks awarded:

Mark Description
3 Excellent: The best response
2 Satisfactory : An average response
1 Weak: An inaccurate response
0 No response or wrong response

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Answer all the questions.

Jawab SenllUl soalan.

The timesuggested for answering Question 1 is 45 minutes.

Masayang dicadangkan untulc menjawab Soalan 1 ialah 45 minit.

1 A student carried out an experiment to construct the electrochemleal series by

measuring the voltage of copper and metal T in a simple voltaic cell as shown in
Diagram 1.1. The experiment is repeated by replacing metal T with metals P, Q, R and
S.
Seorang pelajar telah menjalankan suatu elrperimen untuk membina siri elektrokimta

dengan mengukur voltan antara logam kuprum dan logam T dalam sebuah sel

. ring/cas seperti yang ditunjulclran dalam Rajah 1.1. Ekperimen itu diulang beberapa

/rali dengan menggantikan logam T dengan logam P, g, R dan S.

Copper(II) sulphate
solution
Larutan kuprum(ll)
sulfat
DIAGRAM 1.1
RAJAH 1.1

The voltmeter readings for each pair of metals are shown in Diagram 1.2
Bacaan voltmeter bagi setiap pasangan logam ditunjulckan dalam Rajah 1.2

Cu and P Cu andQ

Cu and S Cuand T

DIAGRAM 1.2

RAJAH 1.2

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(a) Based on Diagram 1.2, record the voltmeter readings for each pair of metals in
Table 1.1.
Berdasarkan Rajah 1.2. rekodkan bacaan voltmeter bag; setiap pasangan logam
dalam Jadual 1.1.

Pair of metals Negative terminal Voltage/V

Pasangan logam Terminal negatif Voltanl V
Cuand P P
Cuand Q Q
Cu and R Cu
Cu and S S
Cuand T Cu

TABLE 1.1
JADUAL 1.1
[3 mara]

(b) Based on the voltmeter readings, arrange the metals Cu, P, Q, R, Sand Tin
descending order ofelectropositivity.
Berdasarkan bacaan voltmeter, susun logam-logam cu. P, Q, R, S dan T dalam
tertib keelektropositifan logam secara menurun.

Descending order of electropositivity of metal,

Susunan keelektropositifan logam secara menurun.
[3 mara]

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(c) Complete Table 1.2 for the experiment.

Leng1cap1can Jadual 1.2 bag!experiment inf.

Variables Action to be taken

Pembolehubah Tindakan .,anl! Derlu diambU
(i) Manipulated variable: (i) The way to manipulate variable:
Pembolehubah dimanipulasi: Cara pembolehubah dimanjpulasi1can:

.(ii) Responding variable:
Pembolehubah bergerakbalas:
..................................................................
..................................................................
(ii) What to observe in the responding
variable:
Apa yang diperhatiJran poda
pembolehubah bergerakbalas:

(iii) Controlled variable: (iii) The way to maintain the controlled

Pembolehubah dimalarkan: variable:
Cara untuk menetapkan pembolehubah
yang dimalarkan:

TABLE 1.2 [6marh]

JADUAL 1.2

(d) State a hypothesis for this experiment.

Nyatakan satu hipotesis untuk eksperimen ini.

[3 maries]

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(e) State three observations and corresponding inferences that can be obtained from
the cell in Diagram 1.1(Cu and metal T).
Nyatakan tiga pemerhatian dan inferens yang sepadan yang boleh diperoleh.
dartpada sel dalam Rajah 1.1(eu dan logam T).

Observation Inference
Pemerhatian Interens

I " " " " " " """"" " "" " " " " " . "" "" """ "" " " "" " "" """" "" .. ] "" . "" "" . """" ,," " ...... "" " .... " "" .......... " . " .... "" . ":,, ..
•..........................•.•••.....••.••.•.. ..•...•..•.......••..•..•.••••.•.•••••........
..
"" " " "" " " "" ...... " " " .... " " .. " ..... "" .. " " . " "" " " . " . " . " ...... ..•.......•....................•..••.•••••.•..
2 •...................•..•.........••.......•. 2 •...•..............•...•..•......•.....•....

""" " . " " "" . "" " "" .... " "" " . " ........ " """" " " .... "" " . "" " .... " ...............•.......••..........•••........

"" .... "" " "" " . "" " ................................ ..............••••......•............•......••

3 .•...•.....••••...•......•.•..•.......•..•.. 3 ............................................

.................. ...•....•.••.....••..••••..
~ .•••.•....•.•....•....•.•..•....•.••.•.••.....
.••.••..•.••...••.••...••..•...•..••••......•. .•.•.......••....•..•.•.•....•••...•.••..••.•.
[6 mara]

(1) Predict the voltage ofthe cells which contain the following pair of metals.
Ramalkan voltan sel yang memJJ!lnyai pasanganlogam yang beriku:

Pair of metals Voltagel V

PtlSangan logam VoltanIV
PandS

PandT

QandR

[3 mara]

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(g) Classify metals P, Q, R, S and T into more electropositive than copper and less
electropositive than copper. Write your answers in the table provided.
Kelaskan logam-logam P. Q. R, S dan T kepada yang lebih eleksropositif
daripada kuprum dan kurang elekiropostttfdaripada kuprum. Tuliskan jawapan
anda dalam jadual yang disediakan.

[3 marks]

(h) Explain why the voltage of cell consist of copper and metal S is larger than the
cell consist of copper and metal P.
Terangkan mengapa nilai voltan sel yang mengandungi kuprum dan logam S
lebih besar daripada selyang mengandungi kuprum dan logam P.

..... . . .. ..,. " .

[3 marks] .
. .
(i) Another example of a chemical cell is Daniell Cell. Draw the apparatus set-up of
a Daniell Cell consisting copper and metal T.
Contoh lain bagi satu sel kimia ialah Sel Daniell. Lukiskan susunan radas bag;
satu Sel Daniell yang mengandungi kuprum dan logam T.

[3 marh]

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2.
Lithium. sodium and potassium are three elements in Group I of the Periodic
Table. These three elements show different reactivity in their reactions with water.
Litium, natrium dan kalium adalah tiga unsur Kumpulan J dalam Jadual Berkala.
Tiga unsur int menunjukan kereaktifan berbezadalam tindak balas dengan air.

Plan an experiment to compare the reactivity of these three elements when reacting with
water.
Rancang saw eksperimen untuk membandingkan kereaksifan ketiga-tiga unsur tersebut
apabila bertindak balas dengan air.

Your planning must include the following items:

Perancangan anda haruslah mengandungiaspek berikut:

(a) Problem statement

Pernyataanmasaalah

(b) Hypothesis
Hipotesis

(c) All the variables

Semua pembolehubah

(d) Lists of materials and apparatus

Senarai bahan dan alat rodas

(e) Procedure
Prosedur

(t) Tabulation of data

Penjadualan data
[17 marks]

END OF QUESTION PAPER

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PEPERIKSAAN PERCUBAAN SPM 2008

NEGERI KEDAH DARUL AMAN
MARKING SCHEME
CHEMISTRY PAPER 3

Section A

Question Explanation Maximum

score
[Able to record all the five readings accurately]:
1 (a)
Suggested answer:

Pairs of electrodes Voltage/V 3

Cu and P 1.5

Cu and Q 1.8

Cu and R 0.6

Cu and S 2.3

Cu and T 1.2

[Able to record any 4 readings accurately] 2

[Able to record any 3 readings accurately] 1
[No response given or wrong response] 0

Question Explanation Maximum

score
[Able to arrange the position of all metals in descending order of
1 (b) 3
electropositivity correctly]
Suggested answer: S, Q, P, Cu, R, T
[Able to arrange the position of at least four metals in descending order
of electroposivity correctly] 2
[Able to arrange the position of at least two metals in descending order of
electroposivity correctly] 1
[No response given or wrong response] 0

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Question Explanation Maximum

score
[Able to state three variables and the way to control them correctly]
1 (c)
Suggested answer:
Manipulated variable: Substituting the electrode T with
different metals
Pair of metals
Responding variable: Reading of the voltmeter//
6
voltage
Voltmeter reading

Controlled variable:
Electrolyte//copper(II) sulphate Use the same concentration of
solution//concentration and electrolyte/CuSO4 //use the same
volume of electrolyte//same voltmeter//use copper electrode in
voltmeter//copper electrode all experiments.
[Able to state any 5 of the above information correctly] 5
[Able to state any 4 of the above information correctly ] 4
[Able to state any 3 of the above information correctly] 3
[Able to state any 2 of the above information correctly ] 2
[Able to state any 1 of the above information correctly ] 1
[No response given or wrong response] 0

Question Explanation Maximum

score
[Able to state the relationship between the manipulated variable and the
1 (d)
responding variable and the direction correctly]
Suggested answer:The further the distance of the pair of metals in the 3
electrochemical series the higher is the voltage / the voltmeter reading

[Able to state the relationship between the manipulated variable and the
responding variable in general]
Suggested answer: 2
The position of the metal in the electrochemical series affects the reading
of the voltmeter// the higher the position of the metal in the
electrochemical series, the bigger/ higher is the voltage/ the voltmeter
reading.

[Able to state an idea of hypothesis]

Suggested answer:
1
The electrochemical series is determined by the voltage value//Different
metals give different voltage values.

[No response given or wrong response] 0

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Question Explanation Maximum

score
1(e)
[Able to state three observations and three inferences correctly]

Observation
1. copper strip/rod/metal
dissolves/ becomes thinner
2. Brown solid is deposited at
metal T
3. The intensity of blue coloured
solution remains unchanged
Inference
Copper is oxidised/ loses electron 6
to form copper(II) ion
Copper is formed
The concentration of Cu2+ in the
solution remain unchanged

5
[Able to state any five of the above information correctly]
4
[Able to state any four of the above information correctly]
3
[Able to state any three of the above information correctly]
2
[Able to state any two of the above information correctly]
1
[Able to state any one of the above information correctly]
[No response given or wrong response] 0

Question Explanation Maximum

score
1(f)
[Able to predict the voltage of the three cells accurately]
Suggested answer:
Pair of metals Voltage/ V
3
P and S 0.8

P and T 2.7

Q and R 2.4
[Able to predict the voltage of any two cells accurately] 2
[Able to predict the voltage of any one cell accurately] 1
[No response given or wrong response] 0

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Question Explanation Maximum

score
1(g) [Able to classify all the metals correctly]
Suggested answer:

More electropositive Less electropositive 3

P, Q, S R, T

2
[Able to classify three metals correctly]
[Able to classify two metals correctly] 1
[No response given or wrong response] 0

Question Explanation Maximum

score
1(h)
[Able to explain the difference in the voltage of the cell]
Suggested answer: 3
The distance between Cu and metal S is further than the distance between
Cu and metal P in Electrochemical Series.
The distance between Cu and metal S is further than the distance between 2
Cu and metal P..
S is more electropositive than P 1
[No response given or wrong response] 0

Question Explanation Maximum

score
1(i) [Able to draw the labeled apparatus set-up completely]
Suggested answer:

Copper Metal T
3

Copper(II) T nitrate
sulphate solution
solution

Salt bridge
[Able to draw the labeled apparatus set-up incompletely] 2
[Able to draw the apparatus completely without label] 1
[No response given or wrong response] 0

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Question Explanation Maximum

score
2(a) [Able to write the problem statement of the experiment accurately.]

Sample answer: 3
How do lithium, sodium and potassium differ in reactivity with water?

[Able to write the problem statement of the experiment correctly.]

Sample answer: 2
How do lithium, sodium and potassium differ in reactivity?

[Able to write a relevant idea about the problem statement of the

experiment//Able to write aim of experiment accurately.]

Sample answer: 1
How do lithium, sodium and potassium differ?//To compare the reactivity
of lithium, sodium and potassium when react with water.

[No response given or wrong response] 0

Question Explanation Maximum

score
2(b) [Able to state the hypothesis accurately]
Suggested answers:
The reactivity of lithium, sodium and potassium towards water increases
down the group
// The reactivity of lithium, sodium and potassium towards water 3
increases down the group
// The reactivity of lithium, sodium and potassium towards water in
increasing order is :
Lithium, sodium and potassium

[Able to the hypothesis of the experiment]

The reactivity of lithium, sodium and potassium are different.

2
// The reactivity of lithium, sodium and potassium towards oxygen/
halogen increases down the group

[Able to state that there is a reaction between lithium / sodium /

1
potassium and water ]

[No response given or wrong response] 0

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Question Explanation Maximum

score
2(c) [Able to state the three variables correctly.]

Sample answer:
Manipulated variable : Type of metal
3
Responding variables : Reactivity of metal

Fixed variables : Size of metal, volume of water

[Able to state any two variables correctly.] 2

[Able to state only one variables correctly.] 1
[No response given or wrong response] 0

Question Explanation Maximum

score
2(d) [Able to state complete materials and apparatus.]

Sample answer:
3
Materials: Lithium, sodium, potassium, water
Apparatus: Basin/beaker, filter paper, pen knife/blade, forcep/tongs

[Able to state any six materials and apparatus correctly.] 2

[Able to state any three materials and apparatus correctly.] 1
[No response given or wrong response] 0

Question Explanation Maximum

score
2(e) [Able to write the complete procedure of the experiment correctly]
Suggested answer:
1. A small piece of lithium is cut using a knife and a pair of forceps
2. The surface of lithium is dried with filter paper
3
3. The piece of lithium is placed on the surface of water in a trough
4. The movement of lithium and any sound/flame given out is observed
and recorded
5 Repeat the experiment using a small piece of sodium and potassium.
[Able to write the necessary steps of the expeimental procedure]
2
Steps 1, 3, 4 and 5
[Able to write the minimum experimental procedure]
1
Steps 3 and 5
[No response given or wrong response] 0

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Question Explanation Maximum

score
2(f) [Able to construct a labeled tabulation of data ]

Sample answer:
Metal Observation 3
Lithium
Sodium
Potassium
[Able to construct a tabulation of data ]

Sample answer:
Metal Observation
2

[Able to construct a table consisting of two rows and two columns.]

[No response given or wrong response] 0

END OF MARKING SCHEME

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