You are on page 1of 5

Ways on Determining Specific Gravity Digital density meters Hydrostatic Pressure-based Instruments: This technology relies upon Pascal's

Principle which states that the pressure difference between two points within a vertical column of fluid is dependent upon the vertical distance between the two points, the density of the fluid and the gravitational force. This technology is often used for tank gaging applications as a convenient means of liquid level and density measure. Vibrating Element Transducers: This type of instrument requires a vibrating element to be placed in contact with the fluid of interest. The resonant frequency of the element is measured and is related to the density of the fluid by a characterization that is dependent upon the design of the element. In modern laboratories precise measurements of specific gravity are made using oscillating U-tube meters. These are capable of measurement to 5 to 6 places beyond the decimal point and are used in the brewing, distilling, pharmaceutical, petroleum and other industries. The instruments measure the actual mass of fluid contained in a fixed volume at temperatures between 0 and 80 C but as they are microprocessor based can calculate apparent or true specific gravity and contain tables relating these to the strengths of common acids, sugar solutions, etc. The vibrating fork immersion probe is another good example of this technology. This technology also includes many coriolis-type mass flow meters which are widely used in chemical and petroleum industry for high accuracy mass flow measurement and can be configured to also output density information based on the resonant frequency of the vibrating flow tubes. Ultrasonic Transducer: Ultrasonic waves are passed from a source, through the fluid of interest, and into a detector which measures the acoustic spectroscopy of the waves. Fluid properties such as density and viscosity can be inferred from the spectrum. Radiation-based Gauge: Radiation is passed from a source, through the fluid of interest, and into a scintillation detector, or counter. As the fluid density increases, the detected radiation "counts" will decrease. The source is typically the radioactive isotope cesium-137, with a half-life of about 30 years. A key advantage for this technology is that the instrument is not required to be in contact with the fluid typically the source and detector are mounted on the outside of tanks or piping. .[6] Buoyant Force Transducer: the buoyancy force produced by a float in a homogeneous liquid is equal to the weight of the liquid that is displaced by the float. Since buoyancy force is linear with respect to the density of the liquid within which the float is submerged, the measure of the buoyancy force yields a measure of the density of the liquid. One commercially available unit claims the instrument is capable of measuring specific gravity with an accuracy of +/- 0.005 SG units. The submersible probe head contains a mathematically characterized spring-float system. When the head is immersed vertically in the liquid, the float moves vertically and the position of the float controls the position of a permanent magnet whose displacement is sensed by a concentric array of Hall-effect linear displacement sensors. The output signals of the sensors are mixed in a dedicated electronics module that provides an output voltage whose magnitude is a direct linear measure of the quantity to be measured.[7]

Specific Gravity of Solids The density of a substance is its mass per unit volume, i.e., its

The Specific Gravity of a substance is the ratio of the weight of nay volume of the substance to the weight of an equal volume of water at 4C. The specific gravity of a substance is really a relative density, i.e. its relative density to that of water at 4C In C.G.S. system, the mass of 1 c.c. of water at 4C is one gram, its density is, therefore, 1 gm. per c.c. In M.K.S. it is 1 kg. per liter In F.P.S. system, the mass of 1 c.ft. of water is 62.5 lbs. or the density is 62.5 lb. per c.ft. Hence in C.G.S. system, the density of a substance is numerically equal to its specific gravity. On the other hand, the density of a substance in F.P.S. unit is numerically equal to 62.5 X specific gravity of the substance.

Determination of Specific Gravity a) By Archimedes' Principle: 1) To find the Sp. Gravity of solid heavier than water. To take the weight of the body in water, it is suspended by means of a fine thread from the hook of the left pan and made to sink completely in water contained in a beaker. The beaker is placed on a small wooden bridge, which is put across the pan in such a way that the bridge or the beaker does not touch any part of the pan of the balance. 2) Solid Lighter than Water

3) Solid Soluble in Water The specific gravity of a solid soluble in water can be found by immersing the solid in a liquid of known specific gravity in which the solid is insoluble.

Determine the specific gravity of the solid relative to the liquid. Then the actual specific gravity of the solid will be obtained by multiplying this value with the specific gravity of the liquid.

Specific gravity of solid b) By the Specific Gravity Bottle. It is a small glass bottle usually of 25 or 50 c.c. capacity with a slight conical neck. It is fitted with a ground glass stopper which has a fine bore along the whole length. When the bottle is completely filled with any liquid and the stopper is fitted to the mouth, the excess of the liquid flows out through the hole in the stopper. Thus, the inside volume of the bottle is always kept constant. This bottle is used to find out the specific gravity of a solid in the form of powder or small fragments, and of liquid also.

Physical Properties Absorption, in chemistry, is a physical or chemical phenomenon or a process in whichatoms, molecules, or ions enter some bulk phase - gas, liquid, or solid material. This is a different process from adsorption, since molecules undergoing absorption are taken up by the volume, not by the surface (as in the case for adsorption). A more general term is "sorption", which covers absorption, adsorption, and ion exchange. Absorption is a condition in which something takes in another substance.[1] If absorption is a physical process not accompanied by any other physical or chemical process, it usually follows the Nernst partition law: "the ratio of concentrations of some solute species in two bulk phases in contact is constant for a given solute and bulk phases

The value of constant KN depends on temperature and is called partition coefficient. This equation is valid if concentrations are not too large and if the species "x" does not change its form in any of the two phases "1" or "2". If such molecule undergoes association ordissociation then this equation still describes the equilibrium between "x" in both phases, but only for the same form - concentrations of all remaining forms must be calculated by taking into account all the other equilibria. In the case of gas absorption, one may calculate its concentration by using, e.g., the Ideal gas law, c = p/RT. In alternative fashion, one may use partial pressures instead of concentrations. In many processes important in technology, the chemical absorption is used in place of the physical process, e.g., absorption of carbon dioxide by sodium hydroxide - such acid base processes do not follow the Nernst partition law.

For some examples of this effect, see liquid-liquid extraction. It is possible to extract from one liquid phase to another a solute without a chemical reaction. Examples of such solutes are noble gases and osmium tetroxide. In chemistry, concentration is defined as the abundance of a constituent divided by the total volume of a mixture. Four types can be distinguished: mass concentration, molar concentration, number concentration, and volume concentration.[1] The term concentration can be applied to any kind of chemical mixture, but most frequently it refers to solutes in homogeneous solutions. Solubility is the property of a solid, liquid, or gaseous chemical substance called solute to dissolve in a solid, liquid, or gaseous solvent to form a homogeneous solution of the solute in the solvent. The solubility of a substance fundamentally depends on the used solvent as well as on temperature and pressure. The extent of the solubility of a substance in a specific solvent is measured as the saturation concentration where adding more solute does not increase the concentration of the solution. Most often, the solvent is a liquid, which can be a pure substance or a mixture. One may also speak of solid solution, but rarely of solution in a gas (see vapor-liquid equilibrium instead). The extent of solubility ranges widely, from infinitely soluble (fully miscible ) such as ethanol in water, to poorly soluble, such as silver chloride in water. The term insoluble is often applied to poorly or very poorly soluble compounds. Under certain conditions, the equilibrium solubility can be exceeded to give a socalled supersaturated solution, which is metastable. Solubility is not to be confused with the ability to dissolve or liquefy a substance, because the solution might occur not only because of dissolution but also because of a chemical reaction. For example, zinc is insoluble in hydrochloric acid, but does dissolve in it by chemical reaction into zinc chloride and hydrogen, where zinc chloride is then soluble in hydrochloric acid. Solubility does not also depend on particle size or other kinetic factors; given enough time, even large particles will eventually dissolve.

Viscosity is a measure of the resistance of a fluid which is being deformed by either shearor tensile stress. In everyday terms (and for fluids only), viscosity is "thickness" or "internal friction". Thus, water is "thin", having a lower viscosity, while honey is "thick", having a higher viscosity. Put simply, the less viscous the fluid is, the greater its ease of movement (fluidity). Viscosity describes a fluid's internal resistance to flow and may be thought of as a measure of fluid friction. For example, high-viscosity felsic magma will create a tall, steepstratovolcano, because it cannot flow far before it cools, while low-viscosity mafic lava will create a wide, shallow-sloped shield volcano. All real fluids (except superfluids) have some resistance to stress and therefore are viscous, but a fluid which has no resistance to shear stress is known as an ideal fluid or inviscid fluid.

The mass density or density of a material is defined as its mass per unit volume. The symbol most often used for density is (the Greek letter rho). In some cases (for instance, in the United States oil and gas industry), density is also defined as its weight per unit volume; although, this quantity is more properly called specific weight. Different materials usually have different densities, so density is an important concept regarding buoyancy, purity and packaging. Osmium and iridium are the densest known metal elements at standard conditions for temperature and pressure but not the densest materials. Less dense fluids float on more dense fluids if they do not mix. This concept can be extended, with some care, to less dense solids floating on more dense fluids. If the average density (including any air below the waterline) of an object is less than water (1000 kg/m3) it will float in water and if it is more than water's it will sink in water. In some cases density is expressed as the dimensionless quantities specific gravity (SG) or relative density (RD), in which case it is expressed in multiples of the density of some other standard material, usually water or air/gas. (For example, a specific gravity less than one means that the substance floats in water.) The mass density of a material varies with temperature and pressure. (The variance is typically small for solids and liquids and much greater for gasses.) Increasing the pressure on an object decreases the volume of the object and therefore increase its density. Increasing the temperature of a substance (with some exceptions) decreases its density by increasing the volume of that substance. In most materials, heating the bottom of a fluid results in convection of the heat from bottom to top of the fluid due to the decrease of the density of the heated fluid. This causes it to rise relative to more dense unheated material. The reciprocal of the density of a substance is called its specific volume, a representation commonly used in thermodynamics. Density is anintensive property in that increasing the amount of a substance does not increase its density; rather it increases its mass.

You might also like