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Journal of Catalysis Volume 243, Issue 1, 1 October 2006, Pages 82-92

doi:10.1016/j.jcat.2006.07.007 | How to Cite or Link Using DOI Copyright 2006 Elsevier Inc. All rights reserved.

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Ceramic foams directly-coated with flame-made V2O5/TiO2 for synthesis of phthalic anhydride
Bjoern Schimmoellera, Heiko Schulza, Sotiris E. Pratsinisa, Anika Bareissb, Andreas Reitzmannb and Bettina KraushaarCzarnetzkib
a ,

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Particle Technology Laboratory, Institute of Process Engineering, Department of Mechanical and Process Engineering, ETH Zurich, CH-8092 Zurich, Switzerland
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Institute of Chemical Process Engineering, Department of Chemical Engineering and Process

Engineering, University of Karlsruhe (TH), D-76128 Karlsruhe, Germany Received 4 July 2006; accepted 9 July 2006. Available online 22 August 2006.

Tenure Track position in Photocatalytic Systems Research of PhotocatalysisNetherlands

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Abstract
Flame-made airborne V2O5/TiO2 nanoparticles were deposited directly onto mullite foam supports to create ready-to-use catalysts for the o-xylene conversion to phthalic anhydride. These particles containing 10% (w/w) V2O5 were created by combustion of liquid precursor sprays and characterized by transmission electron microscopy, nitrogen adsorption, X-ray diffraction (XRD), temperatureprogrammed reduction (TPR), and Raman spectroscopy. The specific surface area, anatase content, and dominantly monomeric vanadia species on titania were thermally stable up to 450 C. Catalyst structure was controlled in situ during deposition by the particle-laden gas flow rate through the foam, resulting in homogeneous to patchy V2O5/TiO2 coatings. The catalytic activity and selectivity were affected by both coating texture and particle morphology. These flame-coated foams showed superior catalytic activity and selectivity at high conversions than classic, wet-made V2O5/TiO2 catalysts. Keywords: Flame-spray pyrolysis; Direct deposition; Ceramic; Foam; Sponge; Partial oxidation; oXylene; Vanadia/titania; Raman spectroscopy

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Article Outline
1. Introduction 2. Experimental 2.1. Catalyst preparation 2.2. Catalyst characterization 2.3. Catalytic testing 3. Results 3.1. Characterization of V2O5/TiO2 3.2. Direct deposition of catalyst onto mullite foam 3.3. Catalytic performance 4. Discussion 4.1. Particle characterization and deposition 4.2. Catalytic testing 5. Conclusion Acknowledgements

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Journal of Catalysis Volume 243, Issue 1, 1 October 2006, Pages 82-92

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