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(RM-1420)
LECTURE X
Crystal Structures of Iron Fe Fe3C Phase Diagram Steels Cast Iron
Dosen: Fahmi Mubarok, ST., MSc. Metallurgy Laboratory Mechanical Engineering ITS- Surabaya 2008
http://www.its.ac.id/personal/material.php?id=fahmi
Fahmi Mubarok
Illustration of phases and solubility: (a) The three forms of water gas, liquid, and solid are each a phase. (b) Water and alcohol have unlimited solubility. (c) Salt and water have limited solubility. (d) Oil and water have virtually no solubility.
2003 Brooks/Cole, a division of Thomson Learning, Inc. Thomson Learning is a trademark used herein under license.
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Pure Iron Steel Cast Isron < 0.008% wt C 0.008 < % wt C < 2.14 2.14 < %wt C < 6.70
Phases:
-Ferrite () Austenite () -Ferrite () Cemenite (Fe3C)
Critical temperature:
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-Ferrite ()
Solid solution of a carbon in -Iron BCC structure Carbon only slightly soluble in matrix
Maximum solubility of 0.022 % wt C at 727oC to about 0.008 wt% C in room temperature
Austenite ()
Solid solution of a carbon in -Iron FCC structure can accomodate more carbon than ferrite
Maximum solubility of 2.14 % wt C at 1147oC, then decreased to 0.8 wt% C at 727oC. The difference in C solid solubility between and is the basis of hardening in many steel.
Metallurgy Lab. Mech. Eng. Dept. ITS Surabaya X 6
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-Ferrite ()
Solid solution of a carbon in -Iron BCC structure NO technological importance cause only stable at high temperature.
Maximum solubility of ferrite being 0.09 % wt C at 1493oC
Cementite (Fe3C)
Intermetallic Fe-C compound Fe3C : 6.7 wt% C + 93.3 wt% Fe Forms when solubility limit of carbon in -ferrite is exceeded below 727oC Orthorombic crystal structure : very hard and brittle.
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Microstructure: pearlite - Lamellar eutectoid product alternates plates of + Fe3C - Two phases grow simultaneously
Lever rule
Formation of Pearlite
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Hypoeutectoid steel
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3. T = 730oC
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Hypereutectoid steel
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Exercise 10a. Determine the following composition of 1.4 wt%C at a temperature near eutectoid line : a. The fraction of pealite and proeutectoid cementite b. The fraction of total ferrite and cementite phases c. The fraction of eutectoid cementite
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Satisfactory where strength and other requirement are not too severe Used successfully at room temperatures and in atmospheres that are not highly corrosive Can be produced in a great range of strengths at a relatively low cost
Limitation 1. Cannot be strengthened beyond about 100.000 psi without significant loss in toughness (impact resistance) and ductility 2. Large section cannot be made with a martensitic structure throughout 3. Rapid quench rates are necessary for full hardening in medium-carbon plain carbon steels to produce a martensitic structure. This rapid quenching leads to shape distortion and cracking of heat-treated steel 4. Show a marked softening with increasing tempering temperature 5. Poor impact resistance at low temperatures 6. Poor corrosion resistance for many engineering environments 7. Oxidezed readily at elevated temperatures
Metallurgy Lab. Mech. Eng. Dept. ITS Surabaya X 17
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1. Sulfur (<0.05 %) Sulfur combines with iron to form iron sulfide (FeS), which usually occurs as a grain boundary precipitation FeS is hard and has a low melting point, it can cause cracking during hot working of steel (hot-short) 2. Manganese (0.03 % -1.0 %) The fuction of manganese in counteracting the negative effects of sulfur Manganese combines with the sulfur persent in the steels to produce manganese sulfide (MnS), thus no FeS will form. 3. Phosphorus (< 0.04 %) This small quantity tends to dissolve in ferrite, increasing the strength and hardness slightly In large quantities, phosphorus reduces ductility, thereby increasing the tendency of the steel to crack when cold worked (cold-short) 4. Silicon (from 0.05%-0.30%) Silicon dissolves in ferrite, increasing the strength of the steel without greatly decreasing the ductility Silicon is used as a deoxidizer, and forms SiO2 or silicate inclusions
Metallurgy Lab. Mech. Eng. Dept. ITS Surabaya X 18
Alloying Steels
Plain Carbon Steels Plain-carbon steels properties are not always adequate for all engineering applications of steel
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1. 2. 3. 4.
Alloy Steels Alloy steels have been developed which, although they cost more, are more economical for many uses In some applications, alloy steels are the only materials that are able to meet engineering requirements The principal element that are added to make alloy steels are nickel, chromium, molybdenum, manganese, silicon, and vanadium Other elements sometimes added are cobalt, cooper, and lead
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Cast Iron
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Chemical composition: Carbon 1.8-3.6 % Silicon 0.5-1.9 % Manganese 0.25-0.80 % Sulfur 0.06-0.20 % Phosphorus 0.06-0.18 % Solidification rate fast enough Carbon combined with iron cementite (hard, brittle) Microstructure pearlite in a white interdendritic network of cementite Shows a white crystalline fractured surface
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High compressive strength and excellent wear resistance but extremely brittle and difficult to machine Used where:
resistance to wear is most important The service does not require ductility
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Summary
Make sure you understand language and concepts:
! Pearlite ! Peritectic reaction ! Phase ! Phase diagram ! Phase equilibrium ! Primary phase ! Proeutectoid cementite ! Proeutectoid ferrite ! Solidus line ! Solubility limit ! Solvus line ! System ! Terminal solid solution ! Tie line ! Liquidus line ! Metastable
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! Austenite ! Cementite ! Component ! Congruent transformation ! Equilibrium ! Eutectic phase ! Eutectic reaction ! Eutectic structure ! Eutectoid reaction ! Ferrite ! Hypereutectoid alloy ! Hypoeutectoid alloy ! Intermediate solid solution ! Intermetallic compound ! Invariant point ! Isomorphous ! Lever rule
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METALLURGY I
(RM-1420)
MINGGU XI-XIII
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