Professional Documents
Culture Documents
Atomic Theory
Atoms, Molecules, and Ions
Science as an early form of investigation, with occult philosophical and spiritual traditions.
Zn, Cu, Fe Au or Ag
the creation of a "panacea," or the elixir of life, a remedy that supposedly Atoms, would cure all diseases and prolong Molecules, life indefinitely. and Ions
(s)
(l)
(g)
27 g
25 g + 2 g
Atoms, Molecules, and Ions
{HgOMovie}
#2
#3
34.0 g
25.5 g
2.0 g
1.5 g
32.0
24.0 g
(17541826)
When two elements form two different compounds, the mass ratio of the elements in one compound is related to the mass ratio in the other compound by a small whole number.
C + O2 (high oxy.conc.) CO2
The Electron
Excess of electrons
Rubber band rubs Movie} metals inside
{Electroscope
Electrically charged particles can be rubbed-out of many substances such as glass rods, hair, shoes, rubber tires and shoes. {Electroscope Movie*}
Lack of electrons
Rubber band
Electric motor
The Electron
Batteries (chemicals)
Electron Rays
cathode ray tubes produce negatively charged particles (electrons) from chemicals in batteries. J. J. Thompson is credited with their discovery (1897). Movie 1 Movie 2 Movie 3
Plum pudding model, put forward by J. J. Thompson. Positive sphere of matter with negative electrons imbedded in it.
Atoms, Molecules, and Ions
He
Since some particles were deflected at large angles, J. J. Thompsons model could not be correct.
{*Rutherfords Experiment}
Atoms, Molecules, and Ions
According to Rutherford
He postulated a very small, dense nucleus with the electrons around the outside of the atom.
Protons and neutrons have essentially the same mass. Atoms, The mass of an electron is so small we ignore it.
Elements
Pure substances that cannot be broken down into more elemental particles by ordinary chemical means. IA
IIA VIIIA
IIIA
IVA
VA
VIA
VIIA
Mass number (A) = (#p+) + (#no) A = Z + N of the same element (same at. #), having Isotopes Atoms different number of neutrons. Atomic mass or weigh (a.m.u. or grams)
The average mass of the isotopes of an element, considering their natural % abundance.
Atoms, Molecules, and Ions
Isotopes
Atoms of the same element with different masses (mass number) Isotopes have different numbers of neutrons.
Atomic mass or weigh?
*
(atomic number =1) 99.985% 0.015% 0% Natural Abundance
Natural Abundance:
11 C 6
negligible
12 C 6
98.89%
13 C 6
1.11%
14 C 6
Atoms, Molecules, and Ions
negligible
Isotopes of Hydrogen
1H 2H 3H
Isotopes of Carbon
12C 13C 14C
Natural
Abundance
98.89%
1.11%
negligible
South pole (-) of magnet attracts lighter isotope more easily than heavier isotope.
Ionizing chamber
Mass Spectrometer
Mass Spectrum of Germanium (Ge)
Atomic Mass (Weight): the average mass of isotopes of an element, considering their natural abundance
Isotope % Abund. f.Abund. X Mass # =
3He 4He
0.01 99.99
(0.0001 x
3) = 0.0003
(0.9999 x 4) = +3.9996
4.000
35Cl 37Cl
75.77 24.23
200?
2007 (B)#2
More exact
Representative Elements
Transition Metals
Representative Elements
Alonsos Rule of 7 + 1:
At2
These seven + one elements occur naturally as molecules containing two atoms (diatomic).
In compounds they may combine in other ratios. NaCl, BaCl2, AlCl3,CCl4.
Atoms, Molecules, and Ions
Compounds
Pure substances (cannot be separated by physical means). Compounds can be broken down (decomposed) into more elemental particles (elements) by ordinary chemical means.
Molecular Formulas: H2O CO2 H2O2 CO CH4
Classification of Compounds
Covalent (Molecular) Compounds: Non-Metals + Non-Metals. Acids: Hydrogen + Nonmetals (polar covalent) Ionic Compounds Salts: Metal + Non-Metal Bases: Metals + Hydroxide Ion (OH-) Acid Salts: Metal + Acid (Hydrogen + Nonmetal) Organic Compounds: covalent compounds containing
carbon (C) atom chains, with mostly H & O atoms attached Atoms, to the Molecules, chain. and Ions
H2O(s)
Atoms, Molecules, and Ions
H2O(l)
Ionic Compounds
Cations
Anions
132-
Aluminum Nitride Al
3+
Aluminum Oxide Al
3+
Aluminum Bromide Al
3+
N AlN
3-
O Al2O3
2-
Br AlBr3
N Fe3N2
3-
N FeN
3-
IUPAC Nomenclature:
Traditional Names:
Atoms, Name of 1st Element (Roman Numeral) (or ous, -ic) Molecules, and Ions Root of 2nd Element -IDE
Iron (Ferrum): Exceptions 2+ 3+ Fe (Iron II or Ferrous) Fe (Iron III or Ferric) Copper (Cuprum): Cu 1+ (Copper I or Cuprous) Cu 2+ (Copper II or Cupric) Atoms, Molecules, Mercury (Hydragyrum): and Ions 1+ 2+ Hg (Mercury I or Mercurous) Hg (Mercury II or Mercuric)
Na+ NO3 nitrate Na+ PO4 3phosphate Na+AsO4 3Arsenate Na+ClO3 chlorate
BO3 3borate
Oxygen
Pattern in # oxygens:
ClO4 -
Oxygen
Per-(oxyanion)-ate (oxyanion)-ate
SO4 2sulfate
ClO3 chlorate
ClO3 ClO2 -
(oxyanion)- ite
TeO4 2tellurate
IO3 iodate
Every step down the pattern ion has one less oxygen.
Name of 1st Element (Roman Numeral or ous, Atoms, -ic) Name of Polyatomic ion (Per- Hypo ATE ITE)
Molecules, and Ions
CNcyanide
SCNthiocyanate
C2H3O2acetate
MnO4permanganate
Cr2O72dichromate
C2O42oxalate
O22peroxide
Mg2+
OH-
Mg 2+
Mg 2+
O2PO43-
Mg 2+
SO32-
Atoms, If these subscripts are not in the lowest whole-numberMolecules, ratio, and Ions divide them by the greatest common factor.
Zinc Phosphate
Zn2+ PO43Zn3(PO4)2
CuO
Heat ()
- 4H2O
+4 H2O
- 2H2O
+ 2H2O
Anhydrous
PREFIX- HydrateAtoms,
Molecules, and Ions
Acid Nomenclature
Depends on the nomenclature ending of the anion that composes the acid. -ide: hydro-(anion root) ic acid
HCl
Acid of Binary -IDE
Hydrochloric acid
Acid Nomenclature
Exercises: HCl, HClO3, HClO4 HBr, HI, HClO, HClO2
Binary acid ends in -ide, add the prefix hydro- and change the ending to -ic acid HCl: hydrochloric acid HBr: hydrobromic acid HI: hydroiodic acid Acid of polyatomic ion ends in -ate, change ending to -ic acid Per-(oxyanion)-ate HClO3: chloric acid (oxyanion)-ate HClO4: perchloric acid (oxyanion)- ite
Hypo-(oxyanion)-ite
Acid of polyatomic ion ends in -ite, change the ending to -ous acid Atoms, Molecules, HClO2: chlorous acid and Ions HClO: hypochlorous acid
Examples:
Acid
HNO3 H2CO3 H3PO4
Salt
NaNO3 Na2CO3 Na3PO4
Basic Salts: salts of weak polyhydroxy bases. They do not dissolve well in water and thus exists mostly in the undissociated solid salt state instead of the dissolved basic state. They do neutralize acids. Mg(OH) 2(s) Fe(OH)3(s) Cr(OH)
3(s))
Cr
3+
(aq) +
3 OH
(aq)
(Milk of Magnesia)
solid salt
Solubility Rule: All OH- are insoluble except for IA metals, NH4+ & slightly soluble Ca 2+ Ba2+ & Sr2+
Methanol CH3OH
Ethanol CH3CH2OH
Propanol Butanol Pentanol Hexanol Heptanol Octanol
Atoms, Nonanol Molecules, and Ions
Propane
Butane Pentane Hexane Heptane Octane Nonane
3
4 5 6 7 8 9
CH3CH2CH3
CH3CH2CH2CH3 CH3CH2CH2CH2CH3 CH3CH2CH2CH2CH2CH3 CH3CH2CH2CH2CH2CH2CH3 CH3CH2CH2CH2CH2CH2CH2CH3 CH3 CH2 CH2CH2CH2CH2CH2CH2CH3
Decane
10 CH3CH2CH2CH2CH2CH2CH2CH2CH2CH3
Decanol