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Water
The Common Solvent
Water as a Solvent
Bent (V-shaped) molecule
Water as a Solvent
Partial charges () form on
Polar Water Molecules Interact with the Positive and Negative Ions of a Salt Assisting in the Dissolving Process
Solubility
Solubility of ionic substances in water varies
greatly.
Solubility
Water will dissolve non-ionic substances
structure, the molecule can be subject to being water soluble. polar solvents and nonpolar substances dissolve in nonpolar solvents.
An Ethanol Molecule Contains a Polar OH Bond Similar to Those in the Water Molecule
The Polar Water Molecule Interacts Strongly with the Polar-O-H bond in Ethanol
dissolved in water; the substance is the solute and the solvent is the water. electrical conductivity. Its ability to conduct an electric current.
efficiently.
current.
flow.
Svante Arrhenius
1859-1927 Studied the nature of solutions and
theorized that conductivity of solutions arose from the presence of ions. conductivity is directly related to the number of ions present in solution.
Strong Electrolytes
Strong electrolytes are substances
that are completely ionized when they are dissolved in water. Soluble salts Strong acids Strong bases
NaCl Dissolves
Acids
Arrhenius discovered in his studies of
solutions that when acids were dissolved in water they behaved as strong electrolytes. This result was directly related to an acids ability to ionize in water. H+ ions when it is dissolved in water.
Acids
HCl H
HNO3 H
H 2 SO4 H
H O 2 u u u u u x
H O 2 u u u u u x
( aq )
Cl
( aq )
3( aq )
4( aq )
H O 2 u u u u u x
( aq )
( aq )
NO
HSO
Acids
HCl H
HNO3 H
H 2 SO4 H
H O 2 u u u u u x
H O 2 u u u u u x
( aq )
Cl
( aq )
3( aq )
4( aq )
H O 2 u u u u u x
( aq )
( aq )
NO
HSO
In conductivity studies, virtually every molecule ionizes. Therefore, strong electrolytes are strong acids.
Strong Acids
Sulfuric acid, nitric acid and hydrochloric
acid are aqueous solutions and should be written in chemical equations as such.
dissociates into its ions. In aqueous solutions, the HCl molecule does not exist. molecule. Only the first H+ ion completely dissociates. The anion HSO4- remains partially intact.
Strong Bases
Bases are soluble ionic compounds
containing the hydroxide ion (OH-). and these compounds ionize completely in water.
Strong Bases
NaOH ( s ) Na KOH ( s ) K
H2O
H2O
( aq )
OH
( aq )
( aq )
OH
( aq )
Weak Electrolytes
Weak electrolytes are substances that
exhibit a small degree of ionization in water. They produce relatively few ions when dissolved in water Most common weak electrolytes are weak acids and weak bases.
Weak Acids
HC2 H 3O2( aq ) H 2 O(l ) H O C H O 3 (aq ) 2 3 2( aq )
the acidic hydrogen atom or atoms (the hydrogen atoms that will produce H+ ions in solution) listed first. If any nonacidic hydrogens are present they are written later in the formula.
Weak Acids
HC2 H 3O2( aq ) H 2 O(l ) H O C H O 3 (aq ) 2 3 2( aq )
ionize.
reaction can occur in either direction. therefore a weak acid because it dissociates (ionizes) only to a slight extent in aqueous solutions.
Weak Bases
The most common weak base is NH3.
In an aqueous solution, ammonia results
in a basic solution.
Nonelectrolytes
Nonelectrolytes are substances that
Concentration:
Solutions
Most chemical reactions take place in the
environment of solutions. In order to perform stoichiometric calculations in solutions, one must know two things. The nature of the reaction; which depends on the exact forms the chemicals take when dissolved. The amounts of the chemicals present in the solutions, usually expressed as concentrations.
Concentration
Molarity (M) is moles of solute
Example
Calculate the molarity of a solution
prepared by dissolving 11.5g of solid NaOH in enough water to make 1.50L of solution.
.192 M NaOH
Example
Calculate the molarity of a solution
prepared by dissolving 1.56g of gaseous HCl in enough water to make 26.8 ml of solution. 1.60M HCl
Example
Give the concentration of each type
Example
Calculate the number of moles of Cl-
Dilution
The process of changing the molarity of a
solution from a more concentrated solution to a lesser concentrated solution. Moles of solute after dilution = moles of solute before dilution. M x V= moles M1V1=M2V2
Example
What volume of 16M sulfuric acid must
9.4 ml solution
Precipitation Reactions
When two solutions are mixed, an
insoluble substance sometimes forms; that is, a solid forms and separates from the solution. The solid that forms is called a precipitate.
2K
( aq )
CrO
2 4( aq )
Ba
2 ( aq )
2 NO
3( aq )
Reactant Solutions
Solution PostReaction
We look at all the possible combinations of the ions to check for compounds that form solids. K2CrO4 KNO3 BaCrO4 Ba(NO3)2
Two of these combinations are the reactants and can be ruled out: K2CrO4 KNO3 BaCrO4 Ba(NO3)2
Solubility
Predicting the identity of a solid product in a
dissolves is not noticeable. The solid appears insoluble to the naked eye. Insoluble and slightly soluble are often used interchangeably.
Two of these combinations are the reactants and can be ruled out: K2CrO4 KNO3 BaCrO4 Ba(NO3)2
Precipitation Reactions
Precipitation reactions move forward
due to the decrease in energy state of the compound. Bonds forming in the compound increase stability and push the reaction forward.
Solutions
Describing Reactions in
Formula Equation
Although the formula equation shows
the reactants and products of the reaction, it does not give a correct picture of what actually occurs in solution.
Gives the overall reaction
stoichiometry but not necessarily the actual forms of the reactants and products.
represents the actual forms of the reactants and products in solution. All substances that are strong electrolytes are represented as ions. Complete ionic equation shows all ions in a reaction, even those that do not participate in the reaction. These ions are called spectator ions.
those solution components that are directly involved in the reaction. Commonly used because it gives the actual forms of the reactants and products and includes only the species that undergo a change. Spectator ions are not included.
Example Problem
For the following reaction, write the formula
equation, the complete ionic equations, and the net ionic equation. Aqueous potassium chloride is added to aqueous silver nitrate to form a silver chloride precipitate plus aqueous potassium nitrate.
KCl(aq) AgNO3(aq ) AgCl( s ) KNO 3(aq )
Cl ( aq ) Ag
( aq )
AgCl( s )
Stoichiometry
of Precipitation Reactions
Solution Stoichiometry
The rules of stoichiometry and limiting
reactant apply to chemical reactions in solutions. But two rules need special emphasis. Always write a balanced equation of the reaction and give special attention to the products that are formed and the true form of the ions in solution. Moles must still be calculated, but molarity and volume must be used in the calculation.
Example Problem
Determine the mass of solid NaCl that must be
added to 1.50L of a 0.100 M AgNO3 solution to precipitate all the Ag+ ions in the form of AgCl.
Ag( aq ) Cl
( aq )
AgCl ( s )
2. Write the balanced net ionic equation for the 3. Calculate the moles of reactants. 4. Determine which reactant is limiting. 5. Calculate the moles of product or products, as
required.
Reactions
Acid-Base
Acids
Arrheniuss concept of acids and bases:
An acid is a substance that produces H+ ions when dissolved in water and a base is a substance that produces OH- ions. Fundamentally correct but doesnt include all bases.
Brnsted-Lowry Acids
Johannes Brnsted (1879-1947) and
Lowry (1874-1936) gives a more general definition of a base that includes substances that do not contain OH-. An acid is a proton donor. A base is a proton acceptor.
Acid-Base Reactions
An Acid-Base reaction often forms two
things: A salt (sometimes soluble) Water Since water is a nonelectrolyte, large quantities of H+ and OH- cannot coexist in solution. The net ionic equations is:
( aq )
OH
( aq )
H 2O(l )
Acid-Base Reactions
When a strong acid and a strong base
react, we expect both substances to completely ionize. We then check to see what will form that is soluble.
HCl( aq ) NaOH ( aq ) NaCl( aq ) H 2O(l ) H (aq ) Cl(aq ) Na(aq ) Cl(aq ) Na(aq ) Cl(aq ) H 2O(l ) H (aq ) OH (aq ) H 2O(l )
In this case, the salt is soluble and remains as ions. But water, a nonelectrolyte, will form since H+ and OH- have a strong attraction for each other and do not ionize.
Acid-Base Reactions
When a weak acid and a strong base react, the weak acid usually doesnt ionize. However, the hydroxide ion is such a strong base that for the purposes of stoichiometric calculations it can be assumed to react completely with any weak acid.
HC2 H 3O2( aq ) KOH ( aq ) OH (aq ) HC2 H 3O2( aq ) H 2O(l ) C2 H 3O2( aq )
solution before any reaction occurs and decide what reaction will occur. this reaction.
reactions in solution, use the volumes of the original solutions and their molarities.
appropriate.
reactant or product.
required.
Acid-Base Reaction
An acid-base reaction is often called
a neutralization reaction.
react exactly with the acid in a solution, we say the acid has been neutralized.
Na
( aq )
Cl
( aq )
NaCl( s )
Example
What volume of a .100 M HCl solution is
( aq )
OH
( aq )
H 2O(l )
Example
What volume of a .100 M HCl solution is
Example
What volume of a .100 M HCl solution is
How many moles of H+ are needed?
Example
What volume of a .100 M HCl solution is
What volume of HCl is required?
Example
In a certain experiment, 28.0ml of 0.250 M HNO3
and 53.0ml of .320 M KOH are mixed. Calculate the amount of water formed in the resulting reaction. What is the concentration of H+ or OHions in excess after the reaction goes to completion?
Acid-Base Titrations
Volumetric analysis is a technique for
of a measured volume of a solution of known concentration (the titrant) into a solution containing the substance being analyzed (the analyte).
Acid-Base Titrations
The point in the titration where enough
titrant has been added to react exactly with the analyte is called the equivalence point or the stoichiometric point. a substance added at the beginning of the titration that changes color at the equivalence point.
Acid-Base Titrations
The point at which the indicator actually
changes color is called the endpoint of the titration. accurately the concentration of a solution is called standardizing the solution.
Indicators
A common indicator for acid-base
titrations is phenolphthalein, which is colorless in an acidic solution and pink in a basic solution.
Example
A student carries out an experiment to standardize a
sodium hydroxide solution. To do this, the student weighs out a 1.3009g sample of potassium hydrogen phthalate (KHC8H4O4 or KHP). KHP (molar mass 204.22g/mol) has one acidic hydrogen. The student dissolves the KHP is distilled water, add phenolphthalein as an indicator, and titrates the resulting solution with the sodium hydroxide solution to the phenolphthalein endpoint. The difference between the final and initial buret readings indicate that 41.20 ml of the sodium hydroxide solution is required to react exactly with the 1.3009g KHP. Calculate the concentration of the sodium hydroxide solution.
Example
1.3009g KHP, molar mass = 204.22g/mol 41.20 ml NaOH solution to neutralize KHP Calculate concentration of NaOH KHP has 1 acidic hydrogen so it should react in a 1 to 1
ratio:
2 8 4 4(aq )
(aq )
(aq )
.1546 M
Reactions
OxidationReduction
one or more electrons from one species to another. Called Redox reactions. Common and important type of reaction: photosynthesis, energy production and combustion
Oxidation States
Also called oxidation numbers provides a
way to keep track of electrons in oxidationreduction reactions. In a covalent compound when electrons are shared, oxidation numbers are based on the relative electron affinity of the elements involved.
Oxidation States
In a covalent compound: If the bond is between two identical
atoms, the electrons are divided equally. If the bond is between different atoms, the electrons are divided based on electron attraction.
maintains a -. Therefore O is assumed to have taken both electrons, one from each of the Hydrogens. H has an oxidation state of +1 (each) O has an oxidation state of -2
Oxidation States
The sum of the oxidation states must
equal the charge of the ion. Ion charges are written as n+ or n-, while oxidation numbers are written +n or -n
Examples
CO2
SF6 NO3-
C +4, O -2
S +6, F -1 N +5, O -2
is assumed to have the same charge within the compound. But the compound actually contains two Fe3+ ions and one Fe2+ ion.
Redox Reactions
Characterized by a transfer of electrons
Redox Reactions
CH 4( g ) 2O2( g ) CO2( g ) 2 H 2O(l )
C -4
C +4 Carbon loses 8 electrons Increase in oxidation state is Oxidation O -2 Oxygen gains 8 electrons: 4 (-2) = -8 Decrease in oxidation state is Reduction
O 0
Redox Reactions
CH 4( g ) 2O2( g ) CO2( g ) 2 H 2O(l )
C -4
C +4 Carbon is Oxidized Oxygen gas is the oxidizing agent O -2 Oxygen is Reduced Methane is the reducing agent.
O 0
Example
Metallurgy, the process of producing a metal from its
ore, always involves oxidation-reduction reactions. In the metallurgy of galena (PbS), the principal leadcontaining ore, the first step is the conversion of lead sulfide to its oxide (a process called roasting):
Example
2PbS( s ) 3O2( g) 2PbO( s ) 2SO2( g )
Pb +2 S -2 O 0 Pb +2 S +4 O -2
Sulfur is oxidized and oxygen is reduced. Oxygen gas is the oxidizing agent and lead sulfide is the reducing agent.
Example
PbO( s ) CO( g ) Pb( s ) CO2( g )
Pb +2 O -2
Pb 0 O -2
C +2
C +4
Lead is reduced and carbon is oxidized. PbO is the oxidizing agent, and CO is the reducing agent.
Balancing
Oxidation-Reduction Equations
must ultimately have equal numbers of electrons gained and lost, and we can use this principle to balance redox equations.
Example
2 H(aq) Cl(aq) Sn( s ) NO3( SnCl aq ) 6( aq ) NO2( g ) H 2O(l )
+1
-1
+5 -2
+4 -1
+4 -2
+1 -2
Note that hydrogen, chlorine, and oxygen do not change oxidation states and are not involved in electron exchange.
2 Sn( s ) NO3( SnCl aq ) 6( aq ) NO2( g )
+5 -2
+4 -1
+4 -2
Example
Sn( s ) NO
0
3( aq )
SnCl
2 6( aq )
NO2( g )
+4 -2
+5 -2
+4 -1
Tin lost 4 electrons and each Nitrogen gained 1 electron. Therefore each nitrogen must have a coefficient of 4.
END
The
Figure 4.11a-b Measurin g Pipets and Volumetri c Pipets Measure Liquid Volume
Figure 4.12a-c A Measuring Pipet is Used to Add Acetic Solution to a Volumetric Flask
Figure 4.17 Molecular-Level Representations Illustrating the Reaction of KCl (aq) with AgNO3 (aq) to Form AgCl (s)
Neutralizati on Titration
Figure 4.19 The Reaction of Solid Sodium and Gaseous Chlorine to Form Solid Sodium Chloride
Lead Sulfate
Figure 4.19 The Reaction of Solid Sodium and Gaseous Chlorine to Form Solid Sodium Chloride
Magnetite
Chocolate
When Potassium Dichromate Reacts with Ethanol, the Solution Contains Cr3+.
The End