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Monomer
Elements
Carbohydrate
Monosaccharides
C, H, O
Lipid
C, H, O
Protein
Amino acid
C, H, O, N, S
Nucleic acid
Nucleotide
C, H, O, N, P
Tetravalence of Carbon
Covalent compatibility (valence e-)
Hydrogen
Oxygen
Nitrogen
Carbon
(valence = 1)
(valence = 2)
(valence = 3)
(valence = 4)
Figure 4.4
Organic Chemistry
Prefix indicates # C
Meth- = 1
Eth- = 2
Pro- = 3
But- = 4
Pent- = 5
Hex- = 6
Hydrocarbons
Found in many of a cells organic molecules
Fat droplets (stained red)
Triglyceride
100 m
Figure 4.6 A, B
Isomers
structural, geometric and
enantiomers
Isomers
Molecules with same
molecular formula but
different structures
different chemical
properties
Structure ~
function
H
H
(a) Structural isomers
X
C
Copyright
ure 4.7
A-C 2005 Pearson Education, Inc. publishing as Benjamin Cummings
H
H
H
C
CO2H
CO2H
NH2
CH3
X
C
(c) Enantiomers
NH2
CH3
Structural isomers
Molecules differ in structural arrangement of
atoms
Structural Isomers
Glucose and Fructose
The Result?
The result is a mixture that consists of 55%
fructose and 45% glucose
Consistency is gel-like and easy to dissolve
when cooking
Leptin
Produced by fat cells (adipose)
Ghrelin
Produced in stomach
Travels to brain
(hypothalamus) to turn
off the satiety cell
Before a meal
After a meal
Stimulates insulin
secretion so that the
sugar can be transported
into cells where it can be
used for cell. resp
Increases production of
leptin that regulates
appetite and fat storage
Suppresses production
of ghrelin hormone which
regulates food intake
Low gherlin = low
hunger
Fructose
In fruit, fructose is
coupled with fiber and is
processed differently
HFCS Effects
Interferes
with bodys
satiety
hormones
Makes you
feel hungry
faster, less
satisfying.
Back to isomers
Geometric isomers
Molecules differ in arrangement around C=C
double bond
same covalent partnerships
Cis
Trans
Enantiomers
Are important in the pharmaceutical industry
Figure 4.8
L-Dopa
D-Dopa
(effective against
Parkinsons disease)
(biologically
inactive)
Amino
Carboxyl
Sulfhydryl
Carbonyl
Phosphate
Affect reactivity
hydrophilic
increase solubility in water
Copyright 2005 Pearson Education, Inc. publishing as Benjamin Cummings
Functional Groups
Give organic molecules distinctive chemical
properties. Affects reactivity.
Estradiol
OH
CH3
Identical Carbonskeleton
HO
Female lion
OH
CH3
CH3
O
Figure 4.9
Male lion
Testosterone
Different
functional group
Hydroxyl
OH
organic compounds with OH = alcohols
Carbonyl
C=O
O double bonded to C
Carboxyl
COOH
C double bonded to O & single bonded to OH
group
compounds with COOH = acids
fatty acids, amino acids
Amino
-NH2
compounds with NH2 = amines
amino acids
Sulfhydryl
SH
S bonded to H
Phosphate
PO4