Professional Documents
Culture Documents
Presentation outline
Introduction
Experimental
Results and discussion
Conclusion
Acknowledgement
Introduction
Adsorption: A surface phenomenon effectively used for
adsorbent
To investigate effect of pH, contact time and initial
kinetics
4
Experimental: Preparation of
Adsorbent
Washed
&
grinded
Conc.
H2SO4
Saccharum
officinarum
Charring
Grinded
Modified material
Batch pH study
Different sets of constant Cr(VI) & Al(III) solution with
10
Raw
bagasse
Modified
bagasse
Modified
Bagasse
Modified
bagasse
12
Absorbance
0.1
max =540nm
0.08
0.06
0.04
0.02
0
450 470 490 510 530 550 570 590 610
Wavelength
13
Absorbance
max =530nm
0.3
0.2
0.1
0
450 470 490 510 530 550 570 590
Wavelength
14
% adsorption
100
80
60
40
RSCB
MSCB
20
0
0
pH3
15
% adsorption
RSCB
MSCB
20
0
0
3
pH
7
16
(mg/g
)
qe
qe
(mg/g)
140
120
100
80
60
40
20
0
0
RSCB
MSCB
18
ce /qe (g/L)
RSCB
10
5
0
0
log qe
(mg/g)
1.5
MSC
B
RSC
B
RSCB
0.5
0
0
0.5
1
logce
(mg/L)
1.5
2.5
20
ce /qe (g/L)
f(x) =
R = 0
2.5
2
1.5
RSCB
Linear (RSCB)
MSCB
Linear (MSCB)
1
0.5
0
0
50
100
150
ce (mg/L)
200
250
300
21
log qe
(m g/g)
f(x) =
R = 0
MSCB
f(x) = 0.51x + 1
R = 0.86
RSCB
Linear (RSCB)
RSCB
MSCB
Linear (MSCB)
0.5
1.5
logce
(mg/L)
2.5
22
40
t/qt
(min/mg/g)
30
RSCB
20
10
0
0
RS
CB
t/qt
(min/mg/g)
40
30
20
10
0
0
RSCB
50
RSCB
Linear (RSCB)
MSCB
MSCB
Linear (MSCB)
24
Conclusion
% removal of Cr(VI) & Al(III) depend upon pH, contact
25
Conclusion(contd.)
Contact time for Al(III) was found to be 2 hours
Langmuir isotherm found to be best fitted
Pseudo-second order kinetics model gave the
Acknowledgement
Department Of Chemistry
Tri-Chandra Multiple Campus
Dr. Deba Bahadur Khadka
Central Department Of Chemistry
Tribhuvan University
Nepal Academy of Science &Technology (NAST)
Khumaltar, Lalitpur
27
Thank You
For Your Kind
Attention
28