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BALANCES ON NONREACTIVE
PROCESSES
Introduction
Non-reactive processes
Processes that undergo without chemical
reaction.
Depends on the physical/environmental
factors like temperature, volume, pressure,
boiling and melting, as well as vaporization.
Normally in chemical process unit, W s=0;
OPEN SYSTEM
(molar flow rate)
U (internal energy)
(rate of enthalpy)
(specific internal
energy)
(specific enthalpy)
Introduction (contd)
For this chapter, we will learn the
Introduction (contd)
To evaluate changes in enthalpy or internal energy,
we can make up any process path we want to simplify
the calculations. They can often be evaluated for:
1. changes in P at constant T
2. changes in T at constant P
3. changes in T at constant V
4. changes in phase at constant T and P (e.g., heats of
vaporization)
5. mixing at constant T and P (heats of mixing)
6. chemical reactions at constant T and P (heats of
reaction)Chapter 9
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properties species
When a species passes from one state to another state, both
Class Discussion
EXAMPLE 8.1-1: Energy Balance on a
Condenser
The flowchart
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Solution
STEP 1: Perform required material balance
calculations.
-None are required in this example because
there are no
material balance involved in this process.
STEP 2: Write and simplify the energy
balance.
For open steady-state system:
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of
STEP 6: Calculate
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Changes in P at Constant T
(no phase change or reactions)
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Ideal gases:
Independent of pressure ( unless undergo
very large pressure
changes)
Real gases:
must evaluate from:
1. enthalpy departure charts
2. an equation of state
3. tabulated data
Liquids and solids:
Nearly independent of pressure
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Changes in T at Constant V
(no phase change or reactions)
Here, we use the heat capacity at
constant volume,
defined by:
Ideal gases:
Liquids and solids:
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Heat capacity, Cp
Estimation of heat capacities, Cp
Kopps rule- simple empirical method for
estimating Cp of
solid or liquid at or near 20C based on the
summation of atomic heat capacities (Table B.10)
of the molecular compound.
(Cp)Ca(OH)2 = (Cpa)Ca + 2(Cpa)O + 2(Cpa)H
= 26 + (2x17) + (2x9.6)
= 79 J/mol.C
Polynomial expressions for Cp in Table B.2
based on the experimental data for the listed
compound.
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Where
= heat capacity of the
mixture
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Class Discussion
EXAMPLE 8.3-1
EXAMPLE 8.3-2
EXAMPLE 8.3-3
EXAMPLE 8.3-4
EXAMPLE 8.3-5
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Estimation of Heat of
Vaporization
1. Troutons rule accuracy between 30%
versus 1/T
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Chaperon equation
known v
at T1
.Estimation of Heat of Fusion
Class Discussion
EXAMPLE 8.4-1
EXAMPLE 8.4-2
EXAMPLE 8.4-3
EXAMPLE 8.4-4
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Psychrometric Charts
PSYCHROMETRIC chart (or HUMIDITY Chart)
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Psychrometric Charts
(contd)
To use Psychrometric Chart, you need to
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IMPORTANT TERM:
Dry-bulb temperature, T This is the air
temperature as measured by thermometer,
thermocouple, or other conventional
temperature measuring device.
Absolute humidity, ha [kg H2O(v)/kg DA]
Called moisture content placed on the
ordinate of the chart.
Psychrometric Charts
(contd)
Relative humidity, hr
Class Discussion
EXAMPLE 8.4-5
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THANK
YOU.
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