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Micro Electro Mechanical Systems

Prof. S.A. Gangal


ISRO Chair Professor
Department of Electronic Science
University of Pune

21-08-2012

Lecture at DIAT

What are MEMS

Micro Electro Mechanical Systems or MEMS is a


term coined around 1989 by Prof. R. Howe and
others to describe an emerging research field,
where mechanical elements, like cantilevers or
membranes, had been manufactured at a scale
more akin to microelectronics circuit than to
lathe machining.

But MEMS is not the only term used to describe


this field. From its multicultural origin it is also
known as Micromachines.

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Techniques used for fabrication

Bulk Micromachining

Surface Micromachining

LIGA

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MEMS Basic Structures


Nozzles

Diaphragm
Cantilever

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Hinge

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Groove

Rack and pinion drive, gear


reduction system.

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Pop-up mirror with ground and


joint hinges.

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Advantages offered by MEMS Technology

Miniaturization of existing devices,


e.g. gyroscope existing devices weighting several kg
and with a volume of 1000 cm3. Silicon based
devices reduced to a chip of a few grams contained in a
0.5 cm3 package.

Development of new devices based on principles that do


not work at larger scale.
e.g. A biochips where electrical field is used to pump the
reactant around the chip. This electro-osmotic effect
based on the existence of a drag force in the fluid works
only in channels with dimension of a fraction of one mm,
that is, at micro-scale.

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Lecture at DIAT

Contd.

Development of new tools to interact with the micro-world.

e.g. development of micromachined sharp micro-tips


with radius below 50 nm for scanning tunnelling
microscope.
This work heralded the development of a new class of
microscopes (atomic force microscope, scanning nearfield optical microscope...).
This micro-tool was used to position atoms in complex
arrangement, writing Chinese character or helping verify
some prediction of quantum mechanics.

Another example of this class of MEMS devices at a


slightly larger scale would be the development of microgrippers to handle cells for analysis.

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Diverse products

Product category: Pressure sensor, Manifold pressure


(MAP), tire pressure, blood pressure..

Inertia sensor: Accelerometer, gyroscope, crash sensor...

Microuidics /bioMEMS: Inkjet printer nozzle, micro-bioanalysis systems, DNA chips...

Optical MEMS / MOEMS: Micro-mirror array for projection


(DLP), micro-grating array for projection (GLV), optical
fiber switch, adaptive optics...

RF MEMS: High Q-inductor, switches, antenna, filter..

Others: Relays, microphone, data storage, toys...

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Lecture at DIAT

The MEMS materials


The choice of a good material for MEMS application is
based more on mechanical aspect:
o small or controllable internal stress,
low processing temperature,
compatibility with other materials,
possibility to obtain thick layer,
patterning possibilities...
additional properties depending on the field of
application,

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RF MEMS: small loss tangent (for example high


resistivity silicon),
optical MEMS may need a transparent substrate,
BioMEMS will need bio-compatibility,
sensor application will need a material showing
piezoresistance or piezoelectricity, etc.
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Relevant Material Properties

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Electrical (semiconductor, metals, insulators)


Mechanical (elasticity, fatigue, Creep etc.)
Thermal (heat conductivity)
Chemical, electro-chemical
Biological (bio-compatibility)
Optical (roughness)
Processing

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Materials used

Silicon (Si) Monocrystalline, Polycrystalline,


amorphous

Si compounds SiO2, Si3N4, SiC

Metals Ag, Au, Al, Cr, Ti etc.

Polymers SU-8, polymides etc.

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Silicon Classification According to


crystallization

MonoCrystalline:
Wafers (2 to 12 )

Polysilicon: thin film


deposition

Amorphous : thin film


deposition at low
temperature

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Facts about Silicon

Eighth most common element in the universe by mass


Second most abundant material in the earth crust
Silicon is the material used to create most integrated
circuits used in consumer electronics in the modern world
Silicon is widely used in semiconductors because it
remains a semiconductor at higher temperatures than the
semiconductor germanium

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The economies of scale, ready availability of cheap


high-quality materials and ability to incorporate
electronic functionality make silicon attractive for a wide
variety of MEMS applications

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Contd..

One of very few materials that can be economically


manufactured in single crystal substrates. Czocharlski
technique is used for this purpose.

In the monocrystalline form is used in the semiconductor


device fabrications

Its strength and flexibility

Its native oxide is easily grown in a furnace and forms a


better semiconductor/dielectric interface than any other
material

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Silicon Crystal Structure & planes

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The width of the rectangular or square cavity bottom plane,


W0, aligned with the 110 directions is defined completely by
the etch depth z the mask opening Wm and the abovecalculated sidewall slope
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Properties of Silicon

Youngs Modulus [ 190 GPa] as high as steel [210 Gpa]


Yield Strength [7 GPa] Steel [4.2 GPa]
Silicon shows no plasticity below 800 oC
It shows no fatigue failure under all conceivable circumstances
Density [2.3 g/cm3] Aluminum [2.7 g/cm3]
Melting point 1673 K
Low thermal expansion coefficient
It is mechanically stable and can be integrated into electronics
on the same substrate
Treatment and fabrication process for silicon substrates are
well establish

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Polysilicon

Surface micromachined MEMS devices utilize


polycrystalline Si (polysilicon) as the primary structural
material,
SiO2 as the sacrificial material, and
Si3N4 for electrical isolation of device structures.
For surface micromachined structures, polysilicon is an
attractive material because
it has mechanical properties comparable to singlecrystal Si,
the required processing technology has been developed
for IC applications, and
it is resistant to SiO2 etchants.

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polysilicon thin films are commonly deposited by lowpressure chemical vapor deposition (LPCVD) technique.

The typical polysilicon LPCVD reactor (or furnace) is


based on a hot-wall resistance-heated horizontal fusedsilica tube design. The temperature of the wafers in the
furnace is maintained by heating the tube using resistive
heating elements. The furnaces are equipped with quartz
boats that have closely spaced vertically oriented slots that
hold the wafers.

The most commonly used source gas is silane (SiH4),


which readily decomposes into Si on substrates heated to
these temperatures.

Typical deposition conditions utilize temperatures from 580


to 650C and pressures ranging from 100 to 400 mtorr.
The polysilicon deposition rate is about 100 /min.

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The microstructure and physical properties of the


deposited polysilicon are a function of the deposition
temperature.

TEM micrograph of an amorphous Si


film deposited at 570C.

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TEM micrograph of a
polysilicon film deposited at
620C.

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During the fabrication of micromechanical devices,


polysilicon films typically undergo one or more hightemperature processing steps
doping,
thermal oxidation,
annealing

These steps can cause recrystallization of the


polysilicon grains leading to a reorientation of the film
and a significant increase in average grain size.

the polysilicon surface roughness increases with the


increase in grain size. This is undesirable outcome
from a fabrication point of view because surface
roughness limits pattern resolution.

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Thin films are generally under a state of stress commonly


referred to as residual stress.

In polysilicon micromechanical structures, the residual


stress in the films can greatly affect the performance of
the device.

as-deposited polysilicon films have compressive residual


stresses. It depends on microstructure,

The highest compressive stresses are found in polysilicon


films with a strong columnar (110) texture.

For films with fine grained microstructures, the stress


tends to be tensile.

For the same deposition conditions, thick polysilicon films


tend to have lower residual stress values than thin films;

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Annealing can be used to reduce the compressive


stress in as-deposited polysilicon films.

For polysilicon films deposited at 650C, the


compressive residual stress is typically on the order of
5 x 109 to 10 x 109 dyne/cm2.

After annealing it is reduced to less than 108 dyne/cm2

RTA is a fast and effective method of stress reduction


in polysilicon films.

For polysilicon films deposited at 620C with


compressive stresses of about 340MPa, a 10 sec
anneal at 1100C was sufficient to completely relieve
the stress

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For single-crystal silicon the youngs modulus in different directions can vary
from 125 to 180GPa.
Randomly oriented polycrystalline silicon should have a Youngs modulus
between 163 and 166GPa.
The fracture strength depends on the flaws in the material.
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Silicon Dioxide (SiO2)

SiO2 can be grown thermally on Si substrates as well as


deposited using a variety of processes to satisfy a wide
range of different requirements.

In polysilicon surface micromachining, SiO 2 is used as a


sacrificial material, as it can be dissolved easily using
etchants that do not attack polysilicon.

SiO2 is also used as an etch mask for dry etching of thick


polysilicon films because it is chemically resistant to dry
polysilicon etch chemistries.

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The SiO2 growth and deposition processes most widely


used in polysilicon surface micromachining are thermal
oxidation and LPCVD.

Thermal oxidation of Si is performed at high temperatures


(e.g., 900 to 1000C) in the presence of oxygen or steam.

The maximum practical film thickness that can be obtained


is about 2 m, which for many sacrificial applications is
sufficient.

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P is incorporated to form phosphosilicate glass (PSG). PSG is


formed using the same deposition process as LTO, with PH3
added to dope the glass with a P content ranging from 2 to 8
wt%.

PSG has an even higher etch rate in HF than LTO, further


facilitating the release of polysilicon surface-micromachined
components.

PSG flows at high temperatures (e.g., 1000 to 1100C) which


can be exploited to create a smooth surface topography.

Additionally, PSG layers sandwiching a polysilicon film can be


used as a P-doping source, improving the uniformity of
diffusion-based doping.

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The dissolution of the sacrificial SiO2 to release free-standing


structures is a critical step in polysilicon surface
micromachining.

Typically, 49% (by weight) HF is used for the release process.

To pattern oxide films using wet chemistries, etching in buffered


HF (28 ml 49% HF, 170 ml H2O, 113 g NH4F), also known as
buffered oxide etch (BOE), is common for large structures.

A third wet etchant, known as P-etch, is traditionally used to


selectively remove PSG over undoped oxide.

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Other Materials:

Semiconductors like InP have also been


micromachined mainly to take advantage of their
photonics capabilities and serve as tunable laser
source.

Quartz crystal has strong piezoelectric effect that


has been put into use to build resonant sensors
like gyroscope or mass sensors.

Glass is only second to silicon in its use in MEMS


fabrication because it can easily form tight bond
with silicon and also because it can be used to
obtain bio-compatible channels for BioMEMS.

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Contd

Polymers are also often used for BioMEMS fabrication


where they can be tailored to provide bio-degradability
or bio-absorbability. The versatility of polymers makes
them interesting for other MEMS application, and for
example the reflow appearing at moderate temperature
has been used to obtain arrays of spherical microlenses
for optical MEMS. This thermoplastic property also allows
molding, making polymer MEMS a cheap alternative to
silicon based system, particularly for microfluidic
application.

Recently the availability of photosensitive polymers like


SU8 that can be spun to thickness exceeding 100 m
and patterned with vertical sides has further increased
the possibility to build polymer structure.

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How MEMS are made

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Micro-fabrication is the set of technologies used to


manufacture structures with micrometric features.
As MEMS devices have about the same feature size
as integrated circuits, MEMS fabrication technology
quickly took inspiration from microelectronics.
Techniques like photolithography, thin film
deposition by chemical vapor deposition (CVD) or
physical vapor deposition (PVD), thin film growth
by oxidation and epitaxy, doping by ion
implantation or diffusion, wet etching, dry etching,
etc have all been adopted by the MEMS
technologists
Plus some unique techniques suitable bulk
micromachining, surface micromachining, LIGA, etc
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Process Classification

It starts with a wafer (silicon, polymer, glass...) that may play


an active role in the final device (bulk micromachining) or
may only be a substrate on which the MEMS is built (surface
micromachining).

This wafer is processed with a succession of processes that


add, modify or remove materials along precise patterns.

Additive process
Evaporation
Sputtering
CVD
Spin-coating

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Modifying process
Oxidation
Doping
Annealing
UV exposure

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Substractive process
Wet etching
Dry etching
Sacrificial etching
Development

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MEMS production process

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Common Sensing Methods

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Piezoresistivity
piezoelectricity

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Piezoresistivity

Piezoresistivity is the phenomenon by which an


electrical resistance changes in response to
mechanical stress.
Most of the resistance change in metals is due to
dimensional changes: under stress, the resistor gets
longer, narrower, and thinner

Thin foil metal strain


gauge

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The piezoresistive effect in silicon and germanium was


much greater (by roughly two orders of magnitude)
than in metals.
Impurity-doped silicon exhibits a piezoresistive
behavior that lies at the core of many pressure and
acceleration sensor Techniques for Sensing and
Actuation

11 12 parallel and perpendicular Piezoelectric coeffs

11

12

parallel and perpendicular stress components

Polysilicon and amorphous silicon also exhibit a strong


piezoresistive effect
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Piezoelectricity

Certain classes of crystals exhibit the peculiar property of


producing an electric field when subjected to an external force.
Conversely, they expand or contract in response to an externally
applied voltage.

They are attractive for MEMS because they can be used as


sensors as well as actuators, and they can be deposited as thin
films over standard silicon substrates.
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A crystal with a center of symmetry, such as a cubic crystal, e.g.


Silicon, is not piezoelectric because the net electric dipole within
the primitive unit is always vanishing, even in the presence of an
externally applied stress and further, the atoms are held together
by covalent (not ionic) bonding.

Piezoelectric materials:
Quartz: but there are no available methods to deposit crystalline
quartz as a thin film over silicon substrates.
Piezoelectric ceramics: Lithium niobate (LiNbO3) and barium titanate
(BaTiO3) but they are also difficult to deposit as thin films.
lead zirconate titanate (PZT)a ceramic based on solid solutions of
lead zirconate (PbZrO3) and lead titanate (PbTiO3)can be
deposited as thin film with.
Zinc oxide is typically sputtered and PZT can be either sputtered or
deposited in a sol-gel process
PVDF is a polymer that can be spun on.
These deposited films must be poled (i.e., polarized by heating above
the Curie temperature, then cooling with a large electric field across
them) in order to exhibit piezoelectric behavior.
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Merits and Demerits

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Common Actuation Methods

There are five schemes

The choice of actuation depends on

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electrostatic,
piezoelectric,
thermal,
magnetic, and
phase recovery using shape-memory alloys.
nature of the application,
ease of integration with the fabrication process,
the specifics of the system around it and
economic justification.
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Electrostatic actuation

It relies on the attractive force between two conductive


plates or elements carrying opposite charges. An applied
voltage, regardless of its polarity, always results in an
attractive electrostatic force.
If C is the capacitance between two parallel plates, x is the
spacing between them, and V is an externally applied
voltage, the electrostatic force is then CV2/x (the square
term ensures that the force is always positive and
attractive).

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Piezoelectric Actuation

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Piezoelectric actuation can provide significantly


large forces, especially if thick piezoelectric films
are used.
Commercially available piezoceramic cylinders
can provide up to a few newtons of force with
applied potentials on the order of a few hundred
volts.
However, thin-film (<5 m) piezoelectric actuators
can only provide a few millinewtons.
Both piezoelectric and electrostatic methods offer
the advantage of low power consumption as the
electric current is very small

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Design Methodology

Start with a list of specifications for the MEM device or system

Identification of the general operating principles and overall


structural elements,

Analysis and Simulation,

Outlining of the individual steps in the fabrication process.

This is often an iterative process involving continuous


adjustments to the shape, structure, and fabrication steps.

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Contd--

The layout of the lithographic masks is completed


using specialized CAD tools to define the twodimensional patterns.

Process is interdisciplinary: includes considerations


from mechanics, optics, fluid dynamics, materials
science, electronics, chemistry, and even biological
sciences.

Determining a particular approach may rely on


economic considerations or ease of manufacture
rather than performance.

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Modern accelerometers
based on simplest MEMS
design

Mass-damper-spring

Air bag deployment


system rapid negative
acceleration

Si

Electronic stability control

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teth
er
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Disadvantages of conventional
Sensors

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Big in size
Consume large power
Inaccurate due to its mechanism, e.g. shape of
fuel tank
High cost
Low yield

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Four types of Accelerator used in


Manufacturing

Piezoresistive Bulk Micromachined


Accelerometer

Capacitive Bulk Micromachined Accelerometer

Capacitive Surface Micromachined


Accelerometer
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Capacitive Deep-Etched
Micromachined Accelerometer
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Piezo resistive analysis of accelerometer

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Modal behavior of structure

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Acceleration Sensor:Structure

considered for fabrication

Flexture

Proof
mass

Piezo resistive type

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Typical resistor structure

contact
Resistive layer

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Accelerometer specifications

A single axis piezoresistive inertial sensor


(accelerometer) in the range of 50g to 100g is
designed & simulated using Coventorware
software.

Following are the optimized dimensions of


accelerometer.
Flexure: L: 100/200 m, W: 50 m, t: 12 m
Proof mass L: 2000 m, W: 1000 (400) m, t:
200 m

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1Starting wafer:

N type, (100), Double Side Polished, 225 m


thick, 76 mm diameter, 7 Ohm cm, Silicon
wafers.

Diamond Unit Cell

{100} planes

{110} planes

{111} planes

Si substrate

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Silicon Crystal Structure & planes

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2 Cleaning of wafers

Wafer surfaces have four types of contaminants


such as Particulates, Organic residues, Inorganic
residues and unwanted oxide layers.

It is essential to have clean wafers at all stages


of fabrication process and specifically before
performing any high temperature operations.

The wafers are cleaned using the standard wet


cleaning processes such as RCA1 (SC1) and
RCA2 (SC2)

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3 Thermal Oxidation

The oxidation layer is used as a mask against implant or diffusion or


selective metallization.
Silicon surface has a affinity for oxygen. An oxide layer is rapidly
formed when Si is exposed to oxidising ambient. Chemical reaction
describing thermal oxidation in oxygen or water vapour is
Si (Solid) + O2 = SiO2 (Solid)
Si (Solid) + 2H2O = SiO2 (Solid) + 2H2

The typical temperature used for this process is bet. 900 1100C
Thickness required 0.5 m
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4Negative PR Coat & Patterning on


front side:

P+ diffused layer is required to be created to provide


electrical inter-connects between resistors. Therefore, this
oxide layer is patterned for deposition of diborane.

Standard lithography technique is used for patterning P+.


In order to avoid etching of oxide from backside, negative
photo-resist is manually coated on backside and baked.

The SiO2 layer is then etched out from the patterned P+


windows using buffered HF.

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Opaque

Transparent

Metallization
Substrate

Mask made up of
Glass or lith film

(a)

Substrate
Exposure

+ve Resist
Metallization
on
(b)

Substrate
Exposure

Mask
+ve Resist
Metallization
Substrate

-ve Resist
Metallization

-ve Resist
Metallization
Substrate

(c)

+ve Resist
Metallization
Substrate

-ve Resist
Metallization
Substrate

(d)

+ve Resist
Metallization
Substrate

-ve Resist
Metallization
Substrate

(e)

Metallization
Substrate

Metallization
Substrate

(f)

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: Lithography process for pattern transfer

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5 Diborane Deposition by APCVD &


diffusion

Diborane (B2H6) is deposited on front side of the wafer


using APCVD system and diffused at elevated
temperature

This creates P+ layer on the etched windows in oxide.

In the process of diffusion, borosilicate glass (BSG) gets


formed as a by-product on the front surface. This BSG
layer is softened by means of high temp heating (900C),
and HF based dip etch process is used to remove the
BSG after its softening.

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CVD Schematic Diagram

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CVD System

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6 Thermal Oxidation:

For the formation of piezoresistors the


process wafers are again oxidized from
both sides using steam oxidation

Thickness required 0.5 m

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7 Negative PR Coat & Patterning on


front side:

patterned on the front side using Resistor


mask employing standard lithography
process

Resistor Mask

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8 Resistor implantation, Annealing and


oxidation

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After creating desired window in oxide on the


front side, boron impurities are implanted in
Silicon using ion-implantation process.
Dopants atoms are vaporised, accelerated and
directed at a silicon substrate. The process is
carried out in vacuum.
The atoms enter the crystal lattice, collide with
silicon atoms and gradually loose energy, finally
coming to rest at some depth in silicon lattice.
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Contd
The average dose can be controlled
by monitoring the ion current during
implantation.
Ion implantation energies : 1KeV 1
MeV
Average depths : 100 10 m
Ion Dose range : 1012 ions /cm2 1018
ions /cm2
The side effect is disruption of the
silicon lattice. The wafers are
annealed to diffuse the impurities and
re-crystallization purpose.
The wafer is again oxidised to close
the opened windows for resistors

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9 Si3N4 Deposition

Si3N4 layer is deposited on the both sides to serve as a


mask for Bulk Micro-Machining
Silicon nitride is chemically deposited by reacting
silane and ammonia at atmospheric pressure at
temperatures between 700 and 900oC or by reacting
dichlorosilane and ammonia at reduced pressure.
The chemical reactions are
3SiH4 + 4NH3 = Si3N4 + 12H2
3SiCl2H2 + 4 NH3 = Si3N4 + 6HCl+ 6H2

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10 Negative PR Coat & Patterning on


Back side (BMM)BMM

Deposited layer is then patterned using BMM


(Bulk Micro Machining) mask to open window on
backside for Proof mass formation.

Si3N4 layer is then etched from this exposed


part using HF based solution

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11 Bulk micromachining for 190


micron.

Bulk micromachining is the most important process


in accelerometer fabrication.
In bulk micromachining, the exposed areas of the
silicon substrate are etched off anisotropically
Bulk micromachining can be done either by wet
etching (KOH) or by dry etching (DRIE) process.
For 190m silicon etching wet etching is selected in
the present work.
Process optimization necessary.
Etching with KOH at the etch rate of 40m/h at 80oC
is done.

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Isotropic and Anisotropic Etching

Isotropic etching

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Anisotropic etching

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12Si3N4 Etching and Contact

Si3N4 patterning on front side of wafer.

This opens the window on P+ for metal


deposition.

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13 Metallization GOLD METAL

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For interconnection between resistor and bondpad connection metallization is done using Au.

The gold is having poor adhesion on silicon


surface. Thus very thin chrome layer is used as
adhesive layer in between Gold and silicon.

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Schematic Diagram of Vacuum


Evaporation System

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RF and DC Sputtering System

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14 METAL Pattering

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This layer is patterned using positive


photoresist and the metallization mask

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15 Dicing

Figure 1.1: A Cell containing all six design


variations

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Figure 1.2: Mask Layout for 3


wafer

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16 Structure Release

It is the last process of Piezoresistive


accelerometer fabrication.

In this process, wet etching is done up to the


depth of 30-35m using KOH. It is required that
KOH should etch only Si. On the wafer side
Si3N4, Si and pattern Au layer are present.
Si3N4 and Au are good masking material thus
only exposed Si get etched in KOH.

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Released accelerometer

Fig 1.3:- Released accelerometer

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Capping Wafer
Etching of glass to 200 m depth

Anodic BondingSealing the


device with Glass cap wafers

Capping WaferEtching of glass to


240 m depth

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MEMS Specific fabrication


process
Bulk
micromachining
Surface
micromachining

Deep reactive ion


etching (DRIE)
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Lecture at DIAT

Bulk Vs Surface micromachining

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Lecture at DIAT

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RF Switch fabrication: Surface


micromachining

Standard RF MEMS switch (cross-section view)

Microstripsine
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Lecture at DIAT

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1. RCA clean silicon wafer.


2.Grow oxide layer on the silicon substrate.
Thin SiO2 is required if high resistivity silicon
substrate are not being used

Lecture at DIAT

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Deposition of Gold
Thin film Gold is deposited for microstrip transmission
line and for bottom actuation electrode.

Lecture at DIAT

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Gold is patterned by spinning resist and then exposing


the wafer to UV light through mask.

Lecture at DIAT

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Deposition of Polyimide
Polyimide is spin coated onto the substrate.

Lecture at DIAT

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Deposition of Hard mask and pattering.


Deposition of hard mask material (generally metal like
Al) is carried out on polyimide and then
lithographically an opening is made in the hard mask.

Lecture at DIAT

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Dry etching of Polyimide.


Dry etching of sacrificial layer is carried out in O2
plasma

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Partial etching of sacrificial layer.

Hard mask is patterned for tip, and then sacrificial


layer is partial etched for making gold contact.

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Lecture at DIAT

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Wet etching is used to remove hard mask, as it is of metal the


respective metal etchant is used to remove the mask.

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Gold deposition is carried out using gold sputtering system to


avoid deposition on sidewalls of polyimide.

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Patterning and etching of gold is carried with


lithographic process.

Lecture at DIAT

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Deposition of Si3N4
Deposition of Si3N4 is deposited using Hot-wire CVD
or PECVD (Plasma enhanced chemical vapor
deposition) system.

Lecture at DIAT

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Deposition of top gold electrode and patterning.


Gold is deposited and is patterned lithographically to
get the top electrode.

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Release the structure.


Finally we dry etch the polyimide, by plasma asher in O2 plasma
to release the switch structure.

Lecture at DIAT

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