Professional Documents
Culture Documents
Risk Management
Risk Assessment
Hazard identification
Hazard assessment(qualitative
& probabilistic)
Quantification of hazards or
consequence analysis
Risk estimation
Hazard Identification
Hazard Assessment
Qualitative
HAZOP
Probabilistic
Fault tree
Event tree
Consequence Analysis
Risk Estimation
Risk Estimation
Representation
FN curves
Frequency of occurrence v.s.
Number of fatality
Risk contours
Risk circles are plotted over the site.
Risk Matrix
Definition
Definition
Evaluate the
Physical effects of the release
of hazardous substances
Or energy
Following the accidental event
Structure
1-Scenario development
Most credible scenarios
Credibility:damage & probability
Damage:FEDI & TDI
Probability : FTA
Scenario Development
Failure mechanism
Volume of material in system
Chemical composition
Process conditions
Mechanical features
Safety systems
Structure
2- source term characterization
Depends on typology of accidental
event
Allows to identify the
characteristics of release
e.g.
Structure
Structure
3- Identification& study of
physical phenomena
Based on source term characteristics
and external conditions:
Meteorological conditions
Presence and type of ignition,etc.
Structure
Consequence Modeling
Source Models
Rate of release of hazardous material
Degree of flashing
Rate of evaporation
Consequence Modeling
Consequence Modeling
Dispersion
Common Models
ARCHIE
ADAM
DEGADIS
OB/DG
SLAB
INPUFF
HGSYSTEM
OOMS
SPILLS
RVD
Bitter &
McQuaid
OME
AFTOX
Proprietary Models
SuperChem
PHAST
CHARM
GASTAR
FOCUS
TRACE
Structure
4- Damage assessment
Determine damage from
Thermal radiation
Overpressure effects
Toxic material
On the population and property
Structure
Consequences are quantified in terms
of:
Damage radii: Radius of area in which
the damage would readily occur
Damage to property:Shattering of
window panes, Caving of buildings
Toxic effects: Chronic/acute toxicity,
mortality
Case Study # 1
Ethylene Oxide & Azinphos
Methyl
Storage in Ikonio/Piraeus
harbor, Greece
Material
Ethylene Oxide
Highly Flammable
Toxic
Azinophose Methyl
Pesticide
Produces toxic
gaseous products
when burning
Wind
1-Southeast Wind
Emission Rate
Hole diameter = 5
cm
EXPERT model
Result
Value
Emission rate
15.586 Kg/s
Exit velocity
9.37 m/s
Used release
duration
64.16 s
Vapor fraction
5.860 E-2
Exit pressure
115 Kpa
Concentration Profile
EXPERT Model
Results
SLAB Model
Definitions
IDLH: Immediately Dangerous to
Life & Health concentration limit.
Concentrations which one could
escape within 30 min without any
escape impairing symptoms &
irreversible health effects
Definitions
Toxic end point:
The threshold concentration value
for serious injury from exposure to
a toxic substance in the air
Definitions
Toxic Dos(toxic.D)
Lowest dose by which a degree of
toxic effect is still possible
LD50
A dose by which 50% of exposed
population will be fatally injured.
IDLH=1460 mg/m3
LFL=54017 mg/m3
TD is calculated via:
TD
Cdt
to
1530
TD3
1530
1300
Results
IDLH=1460 mg/m
LFL=54017 mg/m3
Results
Scenario 2: Ethylene
Oxide Fireball
Scenario
BLEVE
Radiation levels
Thermal doses
Diameter of
fireball=58 m
Duration of
fireball=4.5 s
11 Kw/m2
50 Kw/m2
Results
Results
At block no.5:
6% probability for third degree burns
20% for second degree burns
74% for first degree burns.
At the school area:
2% for third degree
5% for second degree
93% for first degree.
Thermal radiation will be perceptible over 1
km away from point of accident.
Scenario 3 : Ethylene
Oxide Vapor Cloud
Explosion (VCE)
Simulation
51 Kpa:High Risk
Results
Avenue no.6
15% probability of fatal collision of
victim with a stable surface
50% probability of eardrum rupture
Passing cars will turn over
Results
Block no.5 & school no.3
Similar effects as before
50-75% of all outer walls will lightly to
heavily damaged
Most of the houses in the area are old
so the damage will not be repairable
Results
Results
Scenario
Southeast Wind
215 ppm
500 ppm
50 ppm
South Wind
215 ppm
500 ppm
50 ppm
Results
Southeast Wind
South Wind
CA Results
CA Results
Fireball event:
Emits high amounts of thermal
radiation
Would cause burns to humans at
distance less than 132m
Pupils of school and inhabitants would
be endangered
CA Results
Recommendations
Case Study # 2
Sulfolane manufacturing
plant , India
(Khan & Abbasi,2001)
Final Notes
Further Reading