E ARR

CLL
E A C
NUUC ETTI I
C
N GNNE C
EE
AG A NC
M SOONAN
M A N
REES ) T ERR
R MRR) MEET E
((
N NM T ROOM
E
C C
T R
SS
P P
E
--DARPAN BHANUSHALI
-TYBTECH OILS
2
 BASIC:

For mapping It is
molecular recognized as
Nuclear
structures & one of the
Magnetic
learning how most
Resonance
molecules powerful
spectroscopy
function & techniques
is a NDT.
relate to each for chemical
other. analysis.
 The study of
absorption of
radiofrequency
radiation by nuclei in
a magnetic field is
called Nuclear
Magnetic
Resonance.
 UTILITIES&&IMPORTANCE
UTILITIES IMPORTANCE

The importance of this The utility of this is for

technique is reflected in structural characterization
the efforts that have been arises because different
made to extent its atoms in a molecule
applicability to smaller & experience slightly
smaller sample sizes. different magnetic fields.
 PRINCIPLES

Elementary particles such as electrons or a

The Nuclear Spin
angular momentum associated with the
nucleus are known to behave as if they rotate
spin of the particle would be an integral or a
about an axis & thus have the property of
half-integral multiple of h/2pi.
spin.
Nuclear Energy
Levels
 RELAXATION PROCESS

When nuclei in the higher However, the emission is

energy state return to the
lower state, emission of
radiation takes place.
There are two major R.P-
1.Spin-lattice(longitudinal)
2.Spin-Spin(transverse)
insignificant because the
probability of re-emission
of photons varies with the
cube of the frequency. At
radio-frequencies, re-
emission is negligible.
CONSTRUCTIONAL DETAILS
 Computer
workstati
on
A non-magnetic
sample holder
A display device,
The signal amplifier & detector,
Radio-frequency transmitting system,
A magnet which produces a magneitc field in
the range 10,000-25,000 gauss,
The key parts of the system are:-
 INSTRUMENTATION OF
NMR

` 1
 COMPONENTS OF THE
SPECTROPHOTOMETER
Basically NMR instrumentation involves the following units.

1. A magnet to separate the nuclear spin energy state.

2. Two RF channels, one for the field/frequency stabilization and one to

supply RF irradiating energy.

3. A sample probe containing coils for coupling the sample with the RF
field;
it consists of Sample holder, RF oscillator, Sweep generator and RF
receiver.

4. A detector to process the NMR signals.

5. A recorder to display the spectrum.

1
 M.M.C.P.
77
3/12/17

15
 FOR YOUR
THANKS PATIENCE..
!!!