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CATALYTIC REACTION
AND
MASS TRANSFER
Catalyst
Subtopic covered in Chapter
1
Catalytic Reactions and Reactors
Surface and Enzyme Reaction Rates
Introduction of Porous Catalyst
Transport and Reaction
External Mass Transfer
Pore Diffusion
Catalytic Wall Reaction
Langmuir-Hinshelwood Kinetic Mechanism
Temperature Dependence of Catalytic Reaction
Rates
Application of Reaction Engineering in
Microelectronic Fabrication
Catalyst Deactivation
Catalyst Deactivation
So far, we have assumed that the
activity of the catalyst remains
constant throughout the catalysts
C = total
t
concentration
life. of active
sites
Unfortunately,
this is not the
case in most
industrially dCt / dt =
significant
catalytic 0
reactions!!
Catalyst
Deactivation
Catalyst deactivation
Defined as the loss of catalytic activity that occurs
as the reaction takes place on the catalyst.
Major problem faced by most industries when
conducting catalytic reactions.
Known to strongly affect the conversion, hence as a
result, affect the performance of the reactor itself.
Catalysts have only a limited lifetime. Some lose
their activity after a few minutes, others last for
more than ten years.
The maintenance of catalyst activity for as long as
possible is of major economic importance in
indu$try.
In catalyst deactivation, the most
important quantity that need to be
described is the activity of the catalyst,
a(t):
?
Naturally, the activity of catalyst is going to
change (decrease) with time. , a typical
curve of the activity as a function of time is:
/
Sinte
ring / Fouling
Aging Coking
Poisoning
Deactivation by Sintering
(Aging)
Loss of catalytic activity due to a loss of active surface
area (due to prolonged exposure to high gas-phase
temperatures).
The active surface area may be lost by:
Crystal agglomeration and growth of the metals
deposited on the support.
Fogler (4th Ed.)-Elements of Chemical Reaction Engineering, Copyright 2006 www. Chemical Engineering Guy .com
Deactivation by Coking or
Fouling
This mechanism of decay is common
to reactions involving hydrocarbon.
It results from a carbonaceous (coke)
material from fluid phase being
deposited on the surface of a catalyst,
causing activity loss due to blocking of
sites and/or pores.
Fogler (4th Ed.)-Elements of Chemical Reaction Engineering, Copyright 2006 www. Chemical Engineering Guy .c
Deactivation by Coking or
Fouling
When the catalyst is already Fouled
or coked, the material is normally
called spent catalyst
Fresh Spent
catalysts Catalysts
b) Nonseparable kinetics:
PFR
Design
Equatio PF
n R
For cylindrical
tube,
=- = - (4 /d) k CA
(area/volume) r
Schmidt, L.D. (1998). The Engineering of Chemical Reactions, New York: Oxford
The Catalytic Wall Reactor
(cont.)
For reaction limiting process:
Schmidt, L.D. (1998). The Engineering of Chemical Reactions, New York: Oxford
Problem 7-12:
Answer: 14.7 cm
Schmidt, L.D. (1998). The Engineering of Chemical Reactions, New York: Oxford University