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ACID AND BASES

ACID AND BASES


THE STRENGTH OF ACIDS AND ALKALIS
CONCENTRATION OF ACIDS AND
ALKALIS
NEUTRALISATION
ACID AND BASES
ACIDS
i. Examples: (Chemical formulae of the
acids ) HCl, HNO3, H2SO4, CH3COOH

ii. When acids are dissolved in water,


hydrogen atom are released as hydrogen
ions, H+
DEFINITION OF AN ACID
An acid is a chemical substance which
ionises in water to produce hydrogen ions,
H+

Hydrogen chloride molecule, HCl dissolves in water


and ionises to produce a hydrogen ion, H+
HCl H+ + Cl-
The hydrogen ion combines with a water molecule,
to form a hydroxonium ion, H3O+
H+ + H2O H3O+
Classification of acid
based on its basicity
1. Monoprotic acid : HCl and HNO3
2. Diprotic acid : H2SO4

Basicity of an acid :
The maximum number of hydrogen ions that
is produced when one molecule of the acid
ionises in water
Bases and alkalis

A base is a substance that reacts with


an acid to form a salt and water

Examples of bases :
All metal oxides and metal hydroxide
CuO, MgO, Na2O
- Cu(OH)2, Mg(OH)2, NaOH
Definition of a base
A base is a chemical substance which ionises
in water to produce hydroxide ion, OH-

A base that dissolves in water is called an


Alkali : NaOH, KOH, Na2O, K2O, Ca(OH)2
Ammonia solution, NH3(aq)
NaOH dissolves in water and
releases its hydroxide ion,OH-

NaOH Na+ + OH-


Ammonia molecule, NH3 dissolves in
water to produce a hydroxide ion,
OH-

NH3 + H2O NH4+ + OH-


Uses of acids, bases and alkali
Laboratary reagents
Manufacture and preserve food-benzoic
acid, carbonic acid, ethanoic acid, ascorbic
acid
Making medicines-magnesium
hydroxide(toothpaste) and Aluminium
hydroxide (gastric pills)
Producing detergents, soaps and shampoo
( sulphuric acid, hyrochloric acid, sodium
hydroxide),
Role of water and the
properties of acids
An acid only shows its acidic
properties when dissolved in water,
- Without water : acid exists as
molecules , no H+ ions present,
- In water : acid ionises to produce
hydrogen ions, H+
Role of water and the
properties of alkalis
An alkali only shows its alkaline
properties when dissolved in water,
- Without water : no free mobile OH-
ions present,
- In water : alkali ionises to produce
hydroxide ions, OH-
The role of water in showing
the properties of acids and
alkalis
Hydrogen ions ,H+ are responsible for the
acidic properties.
Hydroxide ions, OH- are responsible for
the alkaline properties.

Water is essential for an acid to ionise to


produce hydrogen ions, H+
Water helps a base to ionise to produce
hydroxide ion, OH-
CHEMICAL PROPERTIES
OF ACIDS
1. Acids react with bases/alkali to
form salts and water.
2. Acids react with reactive metals to
produce salts and hydrogen gas, H2.
3. Acids react with carbonates to
produce salt, water and carbon
dioxide, CO2
Reaction of an acid with
bases
Sulphuric acid + copper(II) oxide
copper(II) sulphate + water

H2SO4 + CuO CuSO4 + H2O


Reaction of acid with
reactive metal
Hydrochloric acid + zinc zinc
chloride + hydrogen

2HCl + Zn ZnCl2 + H2
Reaction of an acid with
metal carbonates
Nitric acid + calcium carbonate
calcium nitrate + water +
carbon dioxide

HNO3 + CaCO3 Ca(NO3)2 + H2O


+ CO2
Experiment today

Reaction of acids investigate the


chemical properties.

Get the salt ( solid/crystal)


CHEMICAL PROPERTIES
OF ALKALIS
1. Alkalis react with acids to form salts and
water.
2. A mixture of an alkali and an ammonium
salt is heated ammonia gas, NH3
produced.
3. Adding and alkali ( OH- ion) to most
cation solutions (metal ions solutions) will
give a precipitate of metal hydroxide

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