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2
Features
Large growth in use since 1950 (6 times)
Abundant metal - 8% of earth’s crust
Light weight SG = 2.7
Moderate to high strength (depending on alloy)
Conductivity high (pure metal & low alloys)
Corrosion resistant (Al2O3 coating)
Reflectivity high
Non-magnetic
Fabrication
Ductile metal easily fabricated by rolling
and extrusion
– Commercially pure metal can undertake a cold
reduction of 80 - 90% without annealing
– Anneal at 350˚C
Machineability is good, but limited by the
tendency to gall.
4
Aluminium products
Cast alloys
Wrought products
– Sheet, plate, foil
– Rod, bar, wire, tube
– Standard and special extruded shapes
– Forgings, impacts (combined extrusion and
forging)
Powder metallurgy (dispersion strengthened) products
5
Structural applications
Static building structures AS1664 series
6
Thermal and electrical
Electrical
– Pure Al(68%) has 200% of the conductivity of
copper weight for weight
– Conductors, heat sinks, capacitors, wave
guides, antennas
Reflectors
– Mirrors, search lights, loft insulation
7
Limits of use
Temperature range of -240˚C to +200˚C
for normal alloys
Up to 350˚C for special alloys
Up to 480˚C for short periods for special
alloys
Low modulus of elasticity, requires
stiffening
Inferior wear, creep, & fatigue properties
to steel
8
Wrought alloy designations
Alloy Group Designation
Pure aluminium (99.00% min) 1xxx
Al-Cu 2xxx
Al-Mn 3xxx
Al-Si 4xxx
Al-Mg 5xxx
Al-Mg-Si 6xxx
Al-Zn 7xxx
Al + other element 8xxx
9
Alloy types and properties
10
Strain hardened alloy tempers
Code Description
-O Annealed
-F As fabricated (no mechanical
property limits)
-H1x Strain hardened
-H2x Strain hardened and partially
annealed
-H3x Strain hardened and stabilised
11
Temper designations
T1 Hot work, then naturally age
T2 Hot work, cold work, then naturally
age
T3 Solution treat, cold work, then
naturally age
T4 Solution treat, then naturally age
T5 Hot work, then artificially age
12
1000 Series alloys
Pure Al, can be work hardened
Corrosion performance excellent
Electrical and thermal conductivity excellent
– eg 1060: 99.6%Al min. 62 IACS
Yield strength up to 145 MPa (1050-H18)
Food, chemical, heat exchangers, electrical
wiring, capacitor foil
Weldable
13
2000 Series alloys
Up to 6.3% Cu
Eg 2014: 4.4Cu-0.8Si-0.8Mn-0.5Mg
Precipitation hardened
– 130 to 230˚C aging temperature - T6
– RP0.2 410 MPa typical
Aircraft structure and mechanical components,
vehicle body panels
Weldability poor to fair depending on alloy
14
3000 Series
Up to 1.2Mn + Fe in some alloys
– Eg 3004: 1.2Mn-1.0Mg
Strength from fine particles (Mn,Fe)Al6 which
pin grain boundaries
Excellent formability and weldability, very high
corrosion resistance
Work hardened up to 250 MPa yield typical
– 3004-H38
Cans, chemical vessels, industrial roofing,
culvert pipe
15
4000 Series
Up to 13Si (few wrought alloys)
Eg 4032: 12Si-1Mg-0.9Cu-0.9Ni
High temperature parts, pistons
Can be precipitation hardened if Cu is
present
– Aging168-174˚C 8 to 12 h
Inferior corrosion resistance
16
5000 Series alloys
Mg up to 5.1% in solution increases work
hardening rate
– 5083: 4.4Mg-0.7Mn-0.15Cr
Work hardened up to 260 MPa yield
– 5083-H116: RP0.2 228 MPa typical
Excellent weldability, moderate strength,
Good corrosion resistance
17
5000 series alloy applications
Very popular alloys
Marine, auto and aircraft applications
Pressure vessels, cryogenics
Communication towers
Armour plate
Some alloys prone to exfoliation or stress
corrosion if Al8Mg5 forms in grain boundaries
– Avoid high Mg over 65˚C
18
6000 series
Combination of Mg and Si allows precipitation
hardening with Mg2Si precipitates
6061: 1Mg-0.6Si-0.3Cu-0.2Cr
– 6061-T6: RP0.2 276 MPa typical
Easily workable alloy with excellent strength,
corrosion resistance
Limited to excellent weldability (alloy
dependant)
Available as sheet, plate, extrusions
Applications as 5000 series
19
7000 Series
Up to 7.6% Zn
Includes some modern high strength alloys
7178: 6.8Zn-2.7Mg-2.0Cu-0.3Cr
– 7178-T6: RP0.2 540 MPa typical
Used where stress corrosion or exfoliation
corrosion are a problem
Aircraft
Alloys with Cu can be precipitation hardened
Unweldable to excellent weldability depending
on alloy and process
20
Alclad
Many multiphase alloys have inferior
corrosion resistance
These alloys are available as Alclad sheet
or plate
This material has a thin layer of pure
aluminium roll bonded to one or both
surfaces to provide corrosion resistance
Fabrication must be undertaken so as to
maintain the integrity of this coating
21
Casting alloys
System shown is from the Aluminum
Association
The number after the decimal point
indicates the form supplied (eg ingot or
casting)
22
Casting alloy designations
Al >99.00% 1xx.x
Al-Cu 2xx.x
Al-Si, with Cu and/or Mg 3xx.x
Al-Si 4xx.x
Al-Mg 5xx.x
Al-Zn 7xx.x
Al-Sn 8xx.x
23
Casting processes
Die casting
Permanent mould casting
Sand mould casting
Investment casting
– Lost wax
Centrifugal
24
Mechanical properties
Depend on
– Casting process
– Composition
Alloy modification with sodium finer grain
– Heat treatment
Up 435 MPa Yield strength possible
Ductility up to 20%, but mostly <5%
25
200 series alloys
Heat treatable up to 435 MPa
– Eg 201.0:
4.6Cu-0.7Ag-0.35Mn-0.35Mg-0.2Ti
Sand, investment and die castings
Structural members, aircraft, car cylinder
heads, pistons, etc
Low weldability, lower corrosion resistance
26
300 series alloys
Up to 12Si with up to 4Cu or up to 0.6Mg
Excellent castability, especially die castings
336.0: 12Si-2.5Ni-1Mg-1Cu
Pistons, general and ornamental castings,
aircraft piston engines
Most widely used series
Limited weldability
27
400 series alloys
Up to 12Si
413.0: 12Si
Excellent castability
Thin walled and intricate castings
Cooking utensils, marine fittings
Die and sand castings
Excellent weldability
28
500 series castings
Up to 10% Mg
518.0: 8Mg
Corrosion resistance and machineability
excellent
Castability can be low (hot short)
Weldability limited to excellent
Dairy, food, sewage, chemical, marine fittings,
ornamental, aircraft fittings
29
700 series alloys
Zn up to 7.5%
Eg 713.0: 7.5Zn-0.7Cu-0.35Mg
High strength without heat treatment ages
at room temperature (21 days). Corrosion
resistant. Polishes to high lustre.
Cast furniture, very large castings
Excellent weldability
30
Fabrication
Machineability better than steel
Cold and hot workability excellent
Complex extrusion forms common
Joined by fusion and non-fusion welding,
brazing, soldering, adhesive bonding and
mechanical methods
31
Copper and its alloys
32
Properties of Cu and its alloys
33
Extraction of Cu
34
Cu Alloys Designation
CDA (Copper Development Association) designation
system
– Three digits, eg 110 = Electrolytic tough pitch Cu
– See AS 2738 parts 1, 2 & 3
UNS designations (more than 340 alloys)
– C + 3 CDA digits + 00 eg C11000
145 different temper or mill treatments
Cast alloys are to AS1565
Wrought alloys to AS1566, AS1567, AS1568, AS1569,
AS1571, AS1572, AS1573, AS1574
180 ASTM specifications (e.g. Grade B 36, 148, 176)
35
CDA wrought alloy designations
37
Grades of coppers – 80% of all alloys
High conductivity copper (electrolytic tough pitch
copper, C11000)
– Remelting of cathode copper, contains oxygen (0.04%)
Electrolytic oxygen-free copper (C10100)
– Produced as above, but melted and cast in a controlled
atmosphere (O<10ppm)
Cadmium copper 0.1Cd (C14300)
Silver bearing copper 0.085Ag (C10700)
Tellurium and sulphur bearing coppers (C14500,
C14700)
Fire refined tough pitch copper (C12500)
Phosphorus deoxidised copper (C12200)
38
Application of coppers
Electrical conductivity high - up to 102% IACS
– International annealed copper standard
Electrical/thermal applications (~50%)
– Electrical wiring and components
– Thermal conductors
General uses
– Architectural, automotive, cooking vessels,
pressure vessels, printing rolls, plumbing
– Sculptural
39
Metalworking of coppers
Pure copper is extremely ductile, only 3.9 MPa
shear stress to cause slip on {111} crystal planes
Limitless cold reduction without annealing being
necessary (single phase FCC)
– 90% rolling reduction in one pass
Alloying increases work hardening rate
Joined by mechanical methods, soldering,
brazing & welding
– GTAW, GMAW (argon/helium, ERCu wire), MMAW (ECu
wire), electron beam, friction and cold welding
Oxygen causes embrittlement during heating in
furnaces, welding and brazing
40
Problems in welding of coppers
41
High-copper alloys
Be, Cr, Cd, Co, Ni, Zr, Te added in small
amounts (<4%)
High thermal and electrical conductivity retained
Strengthening by solid solution
Age hardening
– Cu-Be, up to 1380 MPa yield strength (highest
strength of all Cu alloys)
– Cu-Co and Cu-Cr alloys
42
Metalworking of High-Cu alloys
Application: Non-sparking hand tools, electrical
contact springs, cavities in plastic injection molds
Good formability
– Forming done in the annealed condition, before aging
Machinability lower than brass (diamond tools)
Welding
– GMAW, GTAW and MMAW
– Welding gives overaged HAZ, brazing
overages whole component
– Weld only in solution annealed condition
– Beryllium fume from casting or welding Cu-Be
is toxic
43
Brasses
Wide range of alloys of Cu with Zn
– Zn deoxidises and strengthens copper
– Other elements: Pb, Fe, Sn, Ni, As
Single phase alloys a up to 38% Zn have
excellent ductility
– Gilding metal, red brass, cartridge brass
Duplex a plus b at higher Zn levels(40%)
– Muntz metal
– Lower ductility
– Higher strength
44
Metalworking of Brasses
Excellent formability
– Stress relief of cold-worked brass is required
Excellent machinability - Pb added
Soldered and brazed
Weldability low - volatility of Zn
– GMAW, GTAW, MMAW and OFW with ERCuSn or
ERCuAl-2 filler
Wide variety of uses from decorative to marine
– Jewellery, plumbing fittings, door furniture,
cartridge cases, light globe caps, ship’s
propellers
45
Tin Bronzes
Sn is less soluble and has greater hardening
effect than Zn (delta phase)
Types:
– phosphorus bronze (Cu-5Sn-0.2P)
– zinc bronze (Gun metal, Cu-10Sn-2Zn)
– lead bronze (free lead, Cu-10Sn-10Pb)
Few single phase alloys
46
Metalworking of Tin Bronzes
Many casting alloys
– Some casting alloys have low ductility
Cold working of wrought alloys inferior to brass
Machinability increased by Pb
Weldability is good if Pb, Zn are not present
– Keep arc energy low because to avoid
cracking
– Gun metals are not welded
Wear resistant parts: bearings, worm gears,
pump parts
47
Aluminium Bronzes
Aluminium is the main alloy element
– Mn, Ni, Fe and Si may also be added
4-8% Al alloys are single phase (a)
Alloys with >8% Al, or with Ni and Fe
(Al>10.5%) are multi-phase, with properties
which are often influenced by processing
High strength UTS 415 to 1000 MPa
High corrosion, corrosion-abrasion and wear
resistance
Good creep strength up to 400 C
48
Metalworking of Al Bronzes
Wrought and cast alloys
– Excellent ductility for a alloys
Welding
– Alloys with <8% Al suffer cracking in HAZ
– Single phase alloys with Al >8% and 2 phase alloys are
considered weldable with low arc energy
– Preheat often not required
Applications
– Propellers, pumps, gears, valve guides, seals for
seawater and sour mine water, safety tools (non
sparking), equipment for handling explosives;
Architectural (bells, statuary, art castings)
49
Silicon Bronzes
1 to 5% silicon added
– Single phase alloys
Silicon has a powerful effect on:
– Strength (UTS 380 to 900 MPa)
– Corrosion resistance (marine applications)
– Castability
Good weldability
– Low thermal conductivity, preheat
unnecessary
– Solidification cracking possible, but less likely
than other copper alloys
50
Copper-Nickel alloys
Complete solid solubility of Ni in Cu
90/10 and 70/30 alloys widely used in marine
applications
– Seawater piping, cladding of offshore
platforms
“Cunife” and “Cunico” are permanent magnet
alloys containing Fe and Co
“Silver” coinage is 75Cu-25Ni
Constantan (65Cu-45Ni) is an electrical
resistance alloy
51
Metalworking of Cu-Nickel alloys
Wrought and cast alloys
Hot and cold formability are good
– Strengthening by cold work
Machinability is fair
Readily welded
– GTAW, GMAW, MMAW, OFW, and SAW
– Autogenous welds are likely to be porous
– Preheat not necessary (thermal conductivity is
similar to carbon steel)
– Surfaces must be clean and free of oxide and
sulphur
52
Introduction to Steel
Production
Commercial Forms
Strengthening Mechanisms
Applications
Corrosion
Iron Production
Blast Furnace
– Reduces iron ore
to metal
– Separates metal
from impurities
Molten Iron
Slag
Ferrous Metals
Pig Iron
– Iron ore is combined with coke, and limestone
(fluxing agent). Blasts of hot air are forced
through the material to ignite the coke and
melt the iron ore. The impurities in the iron
are absorbed by the limestone and forms
blast furnace slag.
Forms of Ferrous Alloys
Cast Iron
– cast iron is pig iron is any other shape.
Remelted and cast into desired shape.
Malleable Cast Iron
– annealed (heating then slow cooling to
encourage refined grains and soften
mechanical properties, removes internal
stresses, removes gases) cast iron that has
been made more ductile and formable.
Forms of Ferrous Alloys
Wrought Iron
– a form of iron that contains slag, and virtually
no carbon. making it workable when it is hot
but hardens very rapidly when cooled rapidly.
Ingot Iron
– low carbon steel or iron cast from a molten
state.
Forms of Ferrous Alloys
Steel
– Iron - Carbon alloy which is cast from a
molten mass in a form which is malleable.
Carbon steel is steel with less than 1.7%
carbon. Alloy steel is steel which has
properties controlled by elements other than
carbon.
Historical Use of Structural Steel
Cast Iron first used in bridges
– England – 100 ft. arch bridges (1777)
– Truss and ached trusses (1780-1820)
Wrought Iron replaced cast iron
– Wales – Multi span 230’-460’-460’-230’ built
up tubular girder bridge (1845)
1stRolled shapes in 1870s.
1890 Steel replaced wrought iron
Microstructure
Phases of Steel
– Ferrite, a (BCC)
– Austenite, (FCC)
– Cementite (Orthorhombic)
Grain Size
BCC FCC
(ferrite) (austenite)
Strengthening Mechanisms
Alloying
Heat Treating
Cold Working
Alloying
Coarse
Pearlite
Fine Pearlite
Bainite
Martinsite
Cold Working
Plastic deformation
Done below recrystallization temperature
Engineering Properties of Steel
Yield Strength
– Prior to 1960, Fy=33 ksi
– Currently 36-100 ksi structural steel
– 150-270 ksi for steel cable and wire
Modulus of Elasticity
– E~29,000 ksi
Poison’s Ratio
– ~0.30
Engineering Properties of Steel
Ductility
– Mild Steel: ~ 0.20/0.002=100
– Alloy Steel: ~ 0.08/0.005= 16
Fracture Toughness
– CVN from 15-35 ft-lbs
Fatigue Resistance
Carbon and Alloy Steels
Boron: Added to relatively low carbon steels in very small amounts to increase
the hardening capacity of steels meant to be quenched and tempered
Nitrogen Intentionally added only when other elements like vanadium are
present so that vanadium nitrides can improve strength and help refine
the grain size
Atmospheric Cu, Ni
corrosion Resistance
Annealing
Normalizing
Quenching
Tempering
Stress relieving
Flame hardening
Hot shots
Case hardening
Zinc Copper
Global Metal Production - 2001
Metal 106 Tonnes
Zinc 7
Copper 12
Aluminum 21
BLAST FURNACE
heat generation
gas C+O2 CO2
refractory
vessel reduction of iron ore to metal
layers of coke CO2 +C 2CO
and iron ore 3CO+Fe 2O3 2Fe+3CO 2
air purification
slag
Molten iron CaCO 3 CaO+CO 2
CaO + SiO 2 +Al2O3 slag
Metal Alloys
Ferrous Nonferrous
Steels
Steels
<1.4wt%C
<1.4wt%C
Cast Irons
Cast Irons
3-4.5wt%C
3-4.5wt%C
Cu A Mg Ti
Metals
1600
T(°C) microstructure:
ferrite, graphite
Family
d
1400
+L
L
cementite
Tree
(taxonomy
1200 1148°C L+Fe3C
austenite Eutectic:
1000 4.30
a800
ferrite
727°C
Eutectoid:
+Fe3C
Fe3C
cementite
)
600 0.77 a+Fe3C
400
0 1 2 3 4 5 6 6.7
(Fe)
Co, wt% C
Cast iron
Family of ferrous alloys
Cast into desired shape – not worked
3-4.5% C
– Usually with 1-3% Si
Instability of Fe3C (Cementite):
– Cementite → graphite-flakes → graphite-
nodules
Classification of Cast Iron
Type Graphite Ductility Notes
Very
White None Fast Cooling Rates
Little
Very
Gray Flakes Slow Cooling Rates
Little
Anneal:
WhiteIron + Anneal
Malleable Flake → Yes
Heat Treatment
Nodule
Additions Made So that
Nodular Nodular Yes Graphite forms Nodules
and Not Flakes
Cast Iron on Phase
Diagram
Cast Iron: Factors Affecting
Graphitization
Metal Cools Across Eutectic T from “A”
to “B” will Fe3C or GRAPHITE form?
– + Eutectic-Liquid at “A”
Fast cooling → + Fe3C (white cast iron)
Slow cooling → + GRAPHITE (gray cast iron)
– + Graphite (gray cast iron) at point “B”
a + Fe3C – pearlitic gray cast iron
a + GRAPHITE – ferritic gray cast iron
Gray vs. Nodular Cast Iron
About
250X
White Cast Iron
Fe3C + Pearlite
Hard, Brittle
Excellent Wear
Resistance
Withstands
High Compressive Stress
Shows a “White” Crystalline Fractured
Surface
Malleable Cast Iron
White cast iron + Graphite Nodule
annealing
treatment
During annealing
treatment
graphite nucleates
and grows from
the Fe3C to form
Pearlitic Malleable Cast Iron
Graphite Nodules
Gray Cast Iron
During slow Graphite Flakes
solidification
carbon in Fe
separates or
GRAPHITIZES
to form separate
graphite
FLAKES
Pearlitic Malleable Cast Iron
Ductile/Nodular CastFerrite
Iron
Mg added to
Graphite
molten iron
Helps to
Spherodize
graphite
Low levels of
minor elements
such as S and P
Nodular Cast Iron
General Characteristics,
Advantages of Gray Cast Iron
Cheap Excellent Vibration
Low melting point Damping Properties
Fluid – easy to cast Excellent wear
– especially resistance (hi C)
advantageous into Can be heat treated
large complex (surface hardened
shapes etc.)
Excellent Can be alloyed etc.
machinability
Excellent bearing
properties
STEELS
Low Alloy High Alloy
low carbon med carbon high carbon
<0.25wt%C 0.25-0.6wt%C 0.6-1.4wt%C
heat austentitic
Name plain HSLA plain plain tool
treatable stainless
Cr,V Cr, Ni Cr, V,
Additions none none none Cr, Ni, Mo
Ni, Mo Mo Mo, W
Example 1010 4310 1040 4340 1095 4190 304
Hardenability 0 + + ++ ++ +++ 0
TS - 0 + ++ + ++ 0
EL + + 0 - - -- ++
Uses auto bridges crank pistons wear drills high T
struc. towers shafts gears applic. saws applic.
sheet press. bolts wear dies turbines
vessels hammers applic. furnaces
blades V. corros.
resistant
increasing strength, cost, decreasing ductility
StainLess Steels
If metallurgist Harry Brearly,
the man credited with the
development of stainless steel,
had his way we would know
this family of alloys as rustless
steel. However, even in 1913,
the Cutlery Manager of the
Sheffield (England) steel plant
where the new alloy was
devised, one Earnest Stuart,
decided that the name rustless
was no great marketing tool.
His test for utensils made from
this new product was to dip
knife blades in vinegar and he
noted they STAINED LESS than
other metals.
What is Stainless Steel?
Must Contain: >10.5% Cr, <1% C
The Cr Alloying Creates as Cr2O3 surface
Layer that resists oxidation and makes the
material "passive" or corrosion resistant
(i.e. "stainless").
Three MAIN Branches
– Ferritic → Cr Only, BCC (e.g. 430)
– Austenitic → Ni Added, FCC (e.g. 304)
– Martensitic → Hard & Brittle (e.g. 410)
StainLess Steels Compared
Mechanical Properties
(Annealed condition)
Tensile Strength Yield Strength Elongation Hardness
G10400 = G 1 0 40 0
carbon and alloy
steels
Future
Plain Steel Use
SOLID ROUND ROD ALL THREAD ROD FLAT BAR PLATE &
SHEET
Appendix
StainLess Steels
Martensitic StainLess Steels
12 to 18% – Fasteners
chromium – Shafts
Basic Characteristics – Springs
– Are magnetic Grades/Forms
– Can be hardened by – Metallurgical
"heat treatment" structure -
– Have "poor" welding Martensitic
characteristics – Grade: 410 (most
used), 420 (cutlery),
Common Uses 440C (for very high
– Knife blades hardness)
– Surgical instruments – UNS: S41000,
S42000, S44004
Ferritic StainLess Steel
12 to 18% Cr; – Automotive exhaust
<0.2% C and fuel lines
– Architectural trim
Basic Character
– Cooking utensils
– Are magnetic
– Bank vaults
– CANNOT be
hardened by "heat Grades/Forms
treatment" – Metallurgical
always used in the structure - Ferritic
annealed or softened
condition – Grade: 409 (high
temperature), 430
– Poor Weldabiliy (most used)
Common Uses – UNS: S40900,
S43000
Austenitic StainLess Steel
Nickel added and – Have the "BEST"
the Cr level corrosion resistance
increased – Can be easily welded
– Structure Stays FCC – Have excellent
to Room Temp cleanability and
hygiene
Basic Character characteristics
– Are NOT magnetic – Have exceptional
– CANNOT be resistance to both
hardened by "heat high and low
treatment" BUT CAN temperature
be hardened by cold
working
Austenitic StainLess Steel cont.1
Common Uses – Ovens/Furnaces
– Kitchen sinks – Heat exchangers
– Architectural Grades/Forms
applications such as – Metallurgical
roofs and gutters, structure - Austenitic
doors and windows,
– Grade: 304 (most
tubular frames
used), 310 (for high
– Food processing temperature), 316
equipment (for better corrosion
– Restaurant food resistance), 317 (for
preparation areas best corrosion
– Chemical Vessels resistance)
Other StainLess Steels
Austenitic Grades Cr = 18 to 26%
Ni = 4-7%
Forms (cont)
Mo = 2-3%
– UNS: S30400,
– Common Uses
S31000, S31600,
Sea water
S31700 applications
Duplex StainLess Heat exchangers
– MicroStructure is Desalination plants
Combination of Food pickling plants
Ferritic and
Austenitic
– Typical Compostion
Applications
Structural Members
Bolts, Connectors
Concrete Reinforcement
Cold Formed Steel Studs
Standard Rolled Shapes
Mild Steel Grades
A36 Carbon Steel
– <0.26% Carbon
– Structural Shapes, weld & bolt, Buildings
– d8”=20%
– Fu=58-80 ksi
– <.40 Si, 0.85-1.35% Mn,
– <0.04% P, <0.05% S
A325 and A490 Bolts
A325
– High Strength Bolts A490
– <0.30 C – Heat Treated High
– Quenched & Tempered Strength Bolts
– Fy= 81-92 ksi – <0.53 C
– Fu= 105-120 ksi – Quenched & Tempered
– Fy= 115-130 ksi
– Up to 1½” diameter
– Fu= 170 ksi
– Up to 2½” diameter
High Strength Bolts
A 572 “High-Strength Low-Alloy
Columbium-Vanadium Steel”
– Grade 42 (0.21C, Fu=60 ksi, d8”= 20%)
– Grade 50 (0.23C, Fu=65 ksi, d8”= 18%)
– Grade 60 (0.26C, Fu=75 ksi, d8”= 16%)
– Grade 65 (0.26C, Fu=80 ksi, d8”= 15%)
– 0.80-1.35 Mn, 0.40% Si,
– < 0.04%P, < 0.05%S,
– <0.15% V, 0.05% Nb, <0.15% (V+Nb)
– Structural Plate, Sections, Bolts and Rivets
A 572 High-Strength Low-Alloy
Columbium-Vanadium Steel
A 615 Billet Reinforcing Steel
Grade 60
low alloy, high ductility steel
reinforcing bars
d8”=9%, bend around a pin 3.5-9 bar
Fu=90 ksi
A709 Bridge Steel
standard W option
High-strength low-
alloy steel C <0.26 <0.19
Transition Zone
Charpy (CVN) Specifications
Test temperature is LAST/F Test Temp.
dependent y
– lowest anticipated 0F Non-Critical Critical
service temperature <65 ksi
70 ksi
70
40
70
40
(LAST) 100 ksi 10 -10
Fe Fe 2 2e
Al Al 3 3e
2 Fe O2 2 H2 O 2 Fe ( OH ) 2
Fe 2 2e Fe -0.440 V
Zn 2 2e Zn -0.763 V
Control Methods
– Protective Coatings
– Galvanic Protection
– Cathodic Protection
– Corrosion-resistant Steels
Corrosion Prevention